A novel view of the nature of formation of metallic glasses, their structural relaxation, and crystallization

N.P. Kobelev^†^a, V.A. Khonik^‡^b
^aOsipyan Institute of Solid State Physics, Russian Academy of Sciences, Akademika Osip'yana str. 2, Chernogolovka, Moscow Region, 142432, Russian Federation
^bVoronezh State Pedagogical University, Lenina st. 86, Voronezh, 394043, Russian Federation

An alternative concept of the formation of the defect structure and properties of metallic glasses — the interstitialcy theory (IT), which has been actively developed recently — is systematically laid out. The premises and basic hypotheses of the IT are presented, and the experimental data pertaining to the assessment of its adequacy are considered. The multifaceted relation between the relaxation of the shear elasticity and heat phenomena upon various types of thermal processing of metallic glasses is analyzed in detail. A simple mathematical IT formalism is shown to provide a good description of experimental data. The most important result of the IT is an adequate description of the excess thermodynamic potentials of metallic glasses. Problems surrounding the IT and approaches to its further development are considered.

Keywords: metallic glasses, structural relaxation, crystallization, defects, interstitialcy theory
PACS: 61.43.−j, 61.72.J−, 81.05.Kf (all)
DOI: 10.3367/UFNe.2022.04.039173
URL: https://ufn.ru/en/articles/2023/7/b/
Web of Science

001097028100002
Scopus

2-s2.0-85179171278
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2023PhyU...66..673K
Citation: Kobelev N P, Khonik V A "A novel view of the nature of formation of metallic glasses, their structural relaxation, and crystallization" Phys. Usp. 66 673–690 (2023)

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Received: 2nd, March 2022, revised: 21st, March 2022, accepted: 7th, April 2022

Оригинал: Кобелев Н П, Хоник В А «Новые представления о природе образования металлических стёкол, их структурной релаксации и кристаллизации» УФН 193 717–736 (2023); DOI: 10.3367/UFNr.2022.04.039173

References (108) Cited by (8) Similar articles (20) ↓

D.S. Sanditov “Nature of Poisson's ratio of amorphous polymers and glasses and its relation to structure-sensitive properties” Phys. Usp. 63 327–341 (2020)
B.A. Klumov “Universal structural properties of three-dimensional and two-dimensional melts” Phys. Usp. 66 288–311 (2023)
A.I. Gusev “Nonstoichiometry and superstructures” Phys. Usp. 57 839–876 (2014)
R.A. Andrievski “Metallic nano/microglasses: new approaches in nanostructured materials science” Phys. Usp. 56 261–268 (2013)
R. Folk, Yu. Holovatch, T. Yavorskii “Critical exponents of a three-dimensional weakly diluted quenched Ising model” Phys. Usp. 46 169–191 (2003)
V.V. Brazhkin, A.G. Lyapin “Universal viscosity growth in metallic melts at megabar pressures: the vitreous state of the Earth’s inner core” Phys. Usp. 43 493–508 (2000)
G.E. Abrosimova, D.V. Matveev, A.S. Aronin “Nanocrystal formation in homogeneous and heterogeneous amorphous phases” Phys. Usp. 65 227–244 (2022)
D.S. Sanditov, M.I. Ojovan “Relaxation aspects of the liquid—glass transition” Phys. Usp. 62 111–130 (2019)
G.V. Kozlov, V.U. Novikov “A cluster model for the polymer amorphous state” Phys. Usp. 44 681–724 (2001)
D.K. Belashchenko “Diffusion mechanisms in disordered systems: computer simulation” Phys. Usp. 42 297–319 (1999)
A.A. Ionin, S.I. Kudryashov, A.A. Samokhin “Material surface ablation produced by ultrashort laser pulses” Phys. Usp. 60 149–160 (2017)
M.N. Sapozhnikov “Fifty years of selective laser spectroscopy of solids: a history, general principles and applications” Phys. Usp. 61 (4) (2018)
V.A. Gritsenko “Structure of silicon/oxide and nitride/oxide interfaces” Phys. Usp. 52 869–877 (2009)
L.V. Spivak “Synergy effects in the deformation response of thermodynamically open metal — hydrogen systems” Phys. Usp. 51 863–885 (2008)
V.A. Gritsenko “Atomic structure of the amorphous nonstoichiometric silicon oxides and nitrides” Phys. Usp. 51 699–708 (2008)
M.M. Sushchinskii “Resonant inelastic light scattering in crystals” Sov. Phys. Usp. 31 181–195 (1988)
A.N. Vasil’ev, Yu.P. Gaidukov “Electromagnetic excitation of sound in metals” Sov. Phys. Usp. 26 952–973 (1983)
T.V. Tropin, Ju.W.P. Schmelzer, V.L. Aksenov “Modern aspects of the kinetic theory of glass transition” Phys. Usp. 59 42–66 (2016)
A.M. Miterev “Theoretical aspects of the formation and evolution of charged particle tracks” Phys. Usp. 45 1019–1050 (2002)
V.A. Shklovskii, V.M. Kuz’menko “Explosive crystallization of amorphous substances” Sov. Phys. Usp. 32 163–180 (1989)

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