RSS feeds
РусскийEnglish
Issue 4, 2026
Volume year page
Issues Authors PACS Subscription For authors

Issues

 / 

1973

 / 

June

←  →

Reviews of topical problems


Vibrational relaxation in gases and molecular lasers

, , ,

This article reviews the current status of the theory of vibrational relaxation in gases and its applications to the theory of molecular lasers. We discuss relaxation of the vibrational energy of diatomic and polyatomic molecules as represented by harmonic-oscillator models. The vibrational kinetics in a system of anharmonic oscillators is analyzed in detail. We treat quasi-steady-state population distributions of vibrational levels that arise under substantially non-equilibrium conditions, both in a singlecomponent molecular system and in gas mixtures. We discuss relaxation that proceeds in the presence of sources of vibrationally-excited molecules: infrared resonance radiation, recombination, and dissociation; in particular, we analyze the process of non-equilibrium dissociation at low gas temperatures. We discuss from a unified standpoint based on vibrational kinetics the working mechanisms of lasers using vibrational-rotational transitions in diatomic and polyatomic molecules with various means of excitation (electrical, chemical, and gas-dynamic).

Fulltext pdf (2.9 MB)
Fulltext is also available at DOI: 10.1070/PU1973v015n06ABEH005065
PACS: 33.15.Mt, 33.80.−b, 51.10.+y, 82.30.Lp (all)
DOI: 10.1070/PU1973v015n06ABEH005065
URL: https://ufn.ru/en/articles/1973/6/f/
Citation: Gordiets B F, Osipov A I, Stupochenko E V, Shelepin L A "Vibrational relaxation in gases and molecular lasers" Sov. Phys. Usp. 15 759–785 (1973)
BibTexBibNote ® (generic)BibNote ® (RIS)MedlineRefWorks

Оригинал: Гордиец Б Ф, Осипов А И, Ступоченко Е В, Шелепин Л А «Колебательная релаксация в газах и молекулярные лазеры» УФН 108 655–699 (1972); DOI: 10.3367/UFNr.0108.197212c.0655

Cited by (132) ↓ Similar articles (20)

  1. Khrapov S, Khoperskov A Lecture Notes In Computer Science Vol. SupercomputingComputational Efficiency of Non-Equilibrium Reactive Gas Flows Dynamics Simulations on Multi-GPU Supercomputers: GPUDirect Vs. HostCopy16196 Chapter 5 (2026) p. 64
  2. Khrapov S S Fluid Dyn 60 (6) (2025)
  3. Xin Z, Li X et al Journal Of The Energy Institute 118 101929 (2025)
  4. Khrapov S S, Ivanchenko G S et al Tech. Phys. 69 (6) 1596 (2024)
  5. Khrapov S S Fluid Dyn 59 (4) 899 (2024)
  6. Pietanza L D, Guaitella O et al Eur. Phys. J. D 75 (9) (2021)
  7. Micca L G, Vialetto L et al Molecules 26 (12) 3663 (2021)
  8. Tovey D, Pigeon J J et al Journal of Applied Physics 128 (10) (2020)
  9. Morillo-Candas A S, Guerra V, Guaitella O J. Phys. Chem. C 124 (32) 17459 (2020)
  10. Maas U Entropy 22 (12) 1386 (2020)
  11. Tovey D, Tochitsky S Ya et al Appl. Opt. 58 (21) 5756 (2019)
  12. Oblapenko G P J. Phys. Chem. A 122 (50) 9615 (2018)
  13. Bogaerts A, Snoeckx R et al Plasma Chemistry and Gas Conversion Chapter 2 (2018)
  14. Kashlev Y A Physica B: Condensed Matter 511 20 (2017)
  15. Zhu M, Liu T et al Meas. Sci. Technol. 28 (8) 085008 (2017)
  16. Bogaerts A, De Bie Ch et al Plasma Processes & Polymers 14 (6) (2017)
  17. Bogaerts A, Berthelot A et al Plasma Sources Sci. Technol. 26 (6) 063001 (2017)
  18. Kashlev Yu A Inorg. Mater. Appl. Res. 7 (3) 317 (2016)
  19. Panesi M, Munafò A et al Phys. Rev. E 90 (1) (2014)
  20. Perelomova A Applied Mathematical Modelling 38 (23) 5684 (2014)
  21. Heritier K L, Jaffe R L et al The Journal of Chemical Physics 141 (18) (2014)
  22. Kozák Tomáš, Bogaerts A Plasma Sources Sci. Technol. 23 (4) 045004 (2014)
  23. Perelomova A Can. J. Phys. 92 (5) 401 (2014)
  24. Panesi M, Jaffe R L et al The Journal of Chemical Physics 138 (4) (2013)
  25. Perelomova A Acta Phys. Pol. A 123 (4) 681 (2013)
  26. Strekalov M L J. Stat. Mech. 2013 (11) P11014 (2013)
  27. Strekalov M L J Math Chem 51 (8) 2104 (2013)
  28. Bel’skaya E V, Bokhan P A et al Quantum Electron. 42 (2) 99 (2012)
  29. Perelomova A Archives of Acoustics 37 (1) 89 (2012)
  30. Kashlev Yu A, Kashlev Yu A Teor. Mat. Fiz. 167 (1) 123 (2011) [Kashlev Yu A Theor Math Phys 167 (1) 506 (2011)]
  31. Perelomova A Can. J. Phys. 88 (4) 293 (2010)
  32. Makaryan V G, Molevich N E Plasma Sources Sci. Technol. 16 (1) 124 (2007)
  33. Zavershinskii I P, Kogan E Ya High Temp 44 (1) 144 (2006)
  34. Prasad S S, Zipf E C Physics And Chemistry Of The Earth, Part C: Solar, Terrestrial & Planetary Science 25 (3) 213 (2000)
  35. Vereshchagin K A, Smirnov V V, Shakhatov V A Tech. Phys. 42 (5) 487 (1997)
  36. Mllikh G M Journal Of Atmospheric And Terrestrial Physics 52 (2) 119 (1990)
  37. Valyansky S I, Vereschagin K A et al Chemical Physics 140 (1) 59 (1990)
  38. Bruzzese R, de Lisio C et al Nouv Cim D 11 (12) 1693 (1989)
  39. Dubé P, Reid J The Journal of Chemical Physics 90 (6) 2892 (1989)
  40. Ono S, Teii S J. Phys. D: Appl. Phys. 21 (1) 10 (1988)
  41. De Lisio C, Bruzzese R Optics Communications 68 (5) 352 (1988)
  42. Vedenov A A J Russ Laser Res 8 (1) 1 (1987)
  43. Pan Ch-Zh, Bruzzese R et al J. Opt. Soc. Am. B 4 (4) 452 (1987)
  44. Achasov O V, Bruzzese R et al Optics Communications 64 (3) 234 (1987)
  45. Biberman L M, Vorob’ev V S, Yakubov I T Kinetics of Nonequilibrium Low-Temperature Plasmas Chapter 9 (1987) p. 373
  46. Danagher D J, Reid J The Journal of Chemical Physics 86 (10) 5449 (1987)
  47. Gordiets B F, Panchenko V Ya Uspekhi Fizicheskikh Nauk 149 (07) 551 (1986)
  48. Boeuf J P, Kunhardt E E Journal of Applied Physics 60 (3) 915 (1986)
  49. Pan Ch-Zh, Bruzzese R et al Optics Communications 59 (3) 183 (1986)
  50. Florko A V, Kozitskii S V et al Combust Explos Shock Waves 22 (2) 159 (1986)
  51. Gordiets B F, Zhdanok S Topics In Current Physics Vol. Nonequilibrium Vibrational KineticsAnalytical Theory of Vibrational Kinetics of Anharmonic Oscillators39 Chapter 3 (1986) p. 47
  52. Ono S, Teii S J. Phys. D: Appl. Phys. 18 (3) 441 (1985)
  53. D’Ambrosio C, Bruzzese R et al Optics Communications 55 (3) 159 (1985)
  54. Basov N G, Danilychev V A et al J Russ Laser Res 5 (6) 647 (1985)
  55. Basov N, Glotov E et al IEEE J. Quantum Electron. 21 (4) 342 (1985)
  56. Trakhtenberg L I, Milikh G M, Pshezhetsky S Ya Chemical Physics 89 (3) 403 (1984)
  57. Gershikov A G Theor Exp Chem 20 (2) 202 (1984)
  58. Morrison H, Garside B, Reid J IEEE J. Quantum Electron. 20 (9) 1051 (1984)
  59. Lopantseva G B, Napartovich A P et al Gas Flow and Chemical Lasers Chapter 43 (1984) p. 427
  60. Kuznetsov N M, Samusenko A M Theor Exp Chem 18 (3) 223 (1983)
  61. Ablekov V K, Denisov Yu N, Proshkin V V J Russ Laser Res 4 (4) 287 (1983)
  62. Mamedov Sh S J Russ Laser Res 2 (4) 241 (1982)
  63. Kulagin Yu A J Russ Laser Res 3 (1) 1 (1982)
  64. Rozlovskii A I Combust Explos Shock Waves 18 (1) 6 (1982)
  65. Kashlev Yu A Theor Math Phys 53 (1) 1029 (1982)
  66. Zuev V E Laser Beams in the Atmosphere Chapter 5 (1982) p. 243
  67. Konyukhov V K J Russ Laser Res 3 (2) 93 (1982)
  68. Chesnokov E N, Panfilov V N Theor Exp Chem 17 (5) 547 (1982)
  69. Gordiets B F, Osipov a I, Panchenko V Ya J Russ Laser Res 2 (4) 296 (1982)
  70. Kuznetsov N M, Samusenko A M Chemical Physics 68 (3) 359 (1982)
  71. Borisevich N A, Zalesskaya G A, Shukurov T J Appl Spectrosc 37 (6) 1337 (1982)
  72. Kudryavtsev N N, Novikov S S Rev. Phys. Appl. (Paris) 16 (2) 49 (1981)
  73. Dem’yanov A V, Zhdanok S A et al J Appl Mech Tech Phys 22 (3) 287 (1981)
  74. Ben-Shaul A, Haas Y et al Springer Series In Chemical Physics Vol. Lasers and Chemical ChangeDisequilibrium10 Chapter 2 (1981) p. 45
  75. Borisov V N, Breev V V, Moshin Yu N Fluid Dyn 15 (4) 501 (1980)
  76. Rohlfing E A, Rabitz H et al Chemical Physics 51 (1-2) 121 (1980)
  77. Dudkin V A J Appl Spectrosc 31 (3) 1124 (1979)
  78. Aver’yanov N E, Baloshin Yu A J Appl Spectrosc 30 (1) 35 (1979)
  79. Zatsepin S V, Sazonov V N Theor Math Phys 41 (1) 917 (1979)
  80. Kozlov G I, Ivanov V N, Selezneva I K Combust Explos Shock Waves 15 (4) 493 (1979)
  81. Gianturco F A, Lamanna U T Chemical Physics 38 (1) 97 (1979)
  82. Lipovskii I M, Sverdlov L M, Finkel’ A G J Appl Spectrosc 30 (4) 464 (1979)
  83. Volokhov V M, Safaryan M N, Skrebkov O V Theor Exp Chem 14 (4) 354 (1979)
  84. Gordiets B F, Markov M N, Shelepin L A Planetary And Space Science 26 (10) 933 (1978)
  85. Shelepin L A Coherent Cooperative Phenomena Chapter 1 (1978) p. 1
  86. Capitelli M, Dilonardo M Chemical Physics 30 (1) 95 (1978)
  87. Kudryavtsev N N, Novikov S S, Svetlichnyi I B Journal Of Engineering Physics 35 (4) 1137 (1978)
  88. Jolicard G The Journal of Chemical Physics 68 (8) 3445 (1978)
  89. Likalter A A, Naidis G V Chemical Physics Letters 59 (2) 365 (1978)
  90. Akulin V M, Alimpiev S S et al Coherent Cooperative Phenomena Chapter 7 (1978) p. 139
  91. Leshenyuk N S, Nevdakh V V et al J Appl Spectrosc 28 (6) 664 (1978)
  92. Vasilik N Ya, Vakhnenko V A et al J Appl Mech Tech Phys 19 (5) 587 (1978)
  93. Gudzenko L I, Shelepin L A, Yakovlenko S I Theoretical Problems in the Spectroscopy and Gas Dynamics of Lasers Chapter 4 (1977) p. 103
  94. Akhmanov S A, Gordienko V M, Panchenko V Ya Soviet Physics Journal 20 (11) 1406 (1977)
  95. Shelepin L A Theoretical Problems in the Spectroscopy and Gas Dynamics of Lasers Chapter 1 (1977) p. 1
  96. LEVINE R D, BEN-SHAUL A Chemical and Biochemical Applications of Lasers (1977) p. 145
  97. Kalanov T Z, Osipov A I, Panchenko V Ya J Appl Mech Tech Phys 18 (4) 429 (1977)
  98. Vasil’ev V M, Kulikov S V, Skrebkov O V J Appl Mech Tech Phys 18 (4) 437 (1977)
  99. Reshetnyak S A Theoretical Problems in the Spectroscopy and Gas Dynamics of Lasers Chapter 5 (1977) p. 151
  100. Osipov A I Journal Of Engineering Physics 33 (5) 1379 (1977)
  101. Akulintsev V M, Gorshunov N M, Neshchimenko Yu P J Appl Mech Tech Phys 18 (5) 593 (1977)
  102. Zheleznyak M B, Naidis G V Theor Exp Chem 12 (1) 53 (1977)
  103. Keren E, Gerber R B, Ben-Shaul A Chemical Physics 21 (1) 1 (1977)
  104. Biryukov A S Theoretical Problems in the Spectroscopy and Gas Dynamics of Lasers Chapter 2 (1977) p. 11
  105. Djidjoev M S, Khokhlov R V et al Springer Series In Optical Sciences Vol. Tunable Lasers and ApplicationsLaser Chemistry at Surfaces3 Chapter 10 (1976) p. 100
  106. Verter M R, Rabitz H The Journal of Chemical Physics 64 (7) 2939 (1976)
  107. Ktalkherman M G, Mal’kov V M et al Combust Explos Shock Waves 12 (4) 524 (1976)
  108. Levine R D The New World of Quantum Chemistry Chapter 6 (1976) p. 103
  109. Likal’ter A A J Appl Mech Tech Phys 17 (4) 455 (1976)
  110. Zheleznyak M B, Likal’ter A A, Naidis G V J Appl Mech Tech Phys 17 (6) 754 (1976)
  111. Ben-Shaul A, Kompa K L, Schmailzl U The Journal of Chemical Physics 65 (5) 1711 (1976)
  112. Churakov V V, Trushin S A J Appl Spectrosc 24 (5) 561 (1976)
  113. Levine R D The Journal of Chemical Physics 65 (8) 3302 (1976)
  114. Naidis G V J Appl Mech Tech Phys 17 (2) 145 (1976)
  115. Kalanov T Z J Appl Mech Tech Phys 17 (6) 759 (1976)
  116. Baranov V Yu, Bevov R K et al Appl. Opt. 15 (6) 1373 (1976)
  117. Zheleznyak M B, Naidis G V J Appl Mech Tech Phys 17 (1) 1 (1976)
  118. Akulintsev V M, Bashkin A S et al Combust Explos Shock Waves 12 (5) 662 (1976)
  119. Rabitz H, Zarur G The Journal of Chemical Physics 62 (4) 1425 (1975)
  120. Zheleznyak M B, Mnatsakanyan A Kh J Appl Mech Tech Phys 16 (3) 309 (1975)
  121. Likal’ ter A A J Appl Mech Tech Phys 16 (3) 314 (1975)
  122. Vedernikov G A, Karnyushin V N, Soloukhin R I J Appl Mech Tech Phys 16 (2) 155 (1975)
  123. Reshetnyak S A, Shelepin L A J Appl Spectrosc 23 (1) 897 (1975)
  124. Oraevskii A N, Stepanov A A, Shcheglov V A Sov. J. Quantum Electron. 4 (7) 876 (1975)
  125. Osipov A I, Stupochenko E V Combust Explos Shock Waves 10 (4) 399 (1974)
  126. Gordiets B F, Mamedov Sh S J Appl Mech Tech Phys 15 (3) 297 (1974)
  127. Kudryavtsev N N, Novikov S S, Svetlichnyi I B J Appl Mech Tech Phys 15 (5) 590 (1974)
  128. Zharkov V D, Lapushonok L Yu, Chebikin N N J Appl Mech Tech Phys 15 (5) 585 (1974)
  129. Reshetnyak S A, Shelepin L A J Appl Spectrosc 21 (1) 873 (1974)
  130. Novobrantsev I V, Starostin A N J Appl Mech Tech Phys 15 (2) 283 (1974)
  131. Losev S A Combust Explos Shock Waves 9 (6) 669 (1973)
  132. Kuznetsov N M Combust Explos Shock Waves 9 (5) 595 (1973)
© 1918–2026 Uspekhi Fizicheskikh Nauk
Email: ufn@ufn.ru Editorial office contacts About the journal Terms and conditions