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Physical properties of refractory carbides of metals of groups IV and V of the Mendeleev periodic table during rapid heating by an electric current pulse

† , ,
Joint Institute for High Temperatures, Russian Academy of Sciences, ul. Izhorskaya 13/19, Moscow, 127412, Russian Federation

A method for studying the thermophysical properties of refractory carbides under pulsed electric heating for 5—10 microseconds is considered. Results are presented for (ZrC; Zr+C; TaC+HfC; HfC) as a function of the temperature measured from ∼ 2000 K to 5000 K. Data on enthalpy, specific heat Cp, heat of melting, and electrical resistance are given. For all the studied carbides, a sharp increase in the specific heat of the solid phase is observed at ≈ 300 K before melting. This may be due to the formation of paired Frenkel defects under conditions of a short heating time. Comparative data on the results obtained for all carbides are presented, and the choice of carbides for creating thermal protection is discussed.

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Fulltext is also available at DOI: 10.3367/UFNe.2021.06.038990
Keywords: pulse heating, refractory carbides, melting temperature, liquid state, thermophysical properties, electrical resistance
PACS: 64.70.D−, 65.40.−b, 81.05.Je (all)
DOI: 10.3367/UFNe.2021.06.038990
URL: https://ufn.ru/en/articles/2022/6/c/
001100839200002
2-s2.0-85182870598
2022PhyU...65..597S
Citation: Savvatimskiy A I, Onufriev S V, Aristova N M "Physical properties of refractory carbides of metals of groups IV and V of the Mendeleev periodic table during rapid heating by an electric current pulse" Phys. Usp. 65 597–616 (2022)
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Received: 22nd, March 2021, revised: 1st, June 2021, 7th, June 2021

Оригинал: Савватимский А И, Онуфриев С В, Аристова Н М «Исследование физических свойств тугоплавких карбидов металлов IV и V групп периодической таблицы Менделеева при быстром нагреве импульсом электрического тока» УФН 192 642–662 (2022); DOI: 10.3367/UFNr.2021.06.038990

References (109) ↓ Cited by (4) Similar articles (20)

  1. Wuchina E et al Electrochem. Soc. Interface 16 30 (2007)
  2. Mungiguerra S et al 2018 Intern. Energy Conversion Engineering Conf., July 2018 (Session: Thermal System Applications And Unique Environment III) (Reston, VA: American Institute of Aeronautics and Astronautics, 2018), AIAA 2018-4694
  3. Zeng Y et al Nat. Commun. 8 15836 (2017)
  4. Andrievski R A Phys. Usp. 60 276 (2017); Andrievski R A Usp. Fiz. Nauk 187 296 (2017)
  5. Andrievski R A Phys. Usp. 57 945 (2014); Andrievski R A Usp. Fiz. Nauk 184 1017 (2014)
  6. Storms E K The Refractory Carbides (New York: Academic Press, 1967)
  7. Kosolapova T Ya Carbides; Properties, Production, And Applications (New York: Plenum Press, 1971); Translated from Russian, Kosolapova T Ya Karbidy (Moscow: Metallurgiya, 1968)
  8. Toth L E Transition Metal Carbides And Nitrides (New York: Academic Press, 1971)
  9. Samsonov G V, Upadkhaya G Sh, Neshpor V S Fizicheskoe Materialovedenie Karbidov (Physical Materials Science Of Carbides) (Kiev: Naukova Dumka, 1974)
  10. Pierson H O Handbook Of Refractory Carbides And Nitrides: Properties, Characteristics, Processing, And Applications (Park Ridge, NJ: Noyes Publ., 1996)
  11. Krzhizhanovskii R E, Shtern Z Yu Teplofizicheskie Svoistva Nemetallicheskikh Materialov. Karbidy . Spravochnaya Kniga (ThermoPhysical Properties Of Non-Metallic Materials. Carbides. Reference Book) (Leningrad: Energiya, 1977)
  12. Kotel’nikov R B et al Osobo Tugoplavkie Elementy I Soedineniya. Spravochnik (Particularly Refractory Elements And Compounds. Handbook) (Moscow: Metallurgiya, 1969)
  13. Shabalin I L Ultra-High Temperature Materials II. Refractory Carbides I (Ta, Hf, Nb And Zr Carbides) (Dordrecht: Springer, 2019)
  14. Touloukian Y S (Series Ed.) Thermophysical Properties Of Matter (New York: IFI/Plenum, 1970-1979)
  15. Allen P B Phys. Rev. Lett. 59 1460 (1987)
  16. Brorson S D et al Phys. Rev. Lett. 64 2172 (1990)
  17. Onufriev S V, Savvatimskiy A I, Kondratyev A M High Temp. High Press. 43 217 (2014)
  18. Eggert J H et al Nat. Phys. 6 40 (2010)
  19. Lebedev S V, Savvatimskii A I Sov. Phys. Usp. 27 749 (1984); Lebedev S V, Savvatimskii A I Usp. Fiz. Nauk 144 215 (1984)
  20. Savvatimskii A I, Onufriev S V Phys. Usp. 63 1015 (2020); Savvatimskii A I, Onufriev S V Usp. Fiz. Nauk 190 1085 (2020)
  21. Mellan T A, Duff A I, Finnis M W Phys. Rev. B 98 174116 (2018)
  22. Savvatimskiy A I, Korobenko V N Vysokotemperaturnye Svoistva Metallov Atomnoi Energetiki: Tsirkonii, Gafnii I Zhelezo Pri Plavlenii I V Zhidkom Sostoyanii (High-Temperature Properties Of Nuclear Energy Metals: Zirconium, Hafnium And Iron During Melting And In The Liquid State) (Moscow: Izd. Dom MEI, 2012)
  23. Savvatimskiy A I, Onufriev S V Phys. Atom. Nucl. 79 1637 (2016); Savvatimskiy A I, Onufriev S V Yad. Fiz. Inzhiniring 6 622 (2015)
  24. Kondratyev A et al J. Alloys Compd. 631 52 (2015)
  25. Savvatimskiy A I, Onufriev S V, Muboyadzhyan S A J. Mater. Res. 32 1287 (2017)
  26. Savvatimskiy A I et al J. Phys. Conf. Ser. 891 012318 (2017)
  27. Savvatimskiy A I et al Bull. Russ. Acad. Sci. Phys. 82 363 (2018); Savvatimskiy A I et al Izv. Ross. Akad. Nauk Fiz. 82 419 (2018)
  28. Savvatimskiy A I High Temp. 56 678 (2018); Savvatimskiy A I Teplofiz. Vys. Temp. 56 704 (2018)
  29. Savvatimskiy A I, Onufriev S V, Muboyadzhyan S A J. Europ. Ceram. Soc. 39 907 (2019)
  30. Savvatimskiy A I et al J. Mater. Sci. 55 13559 (2020)
  31. Aristova N M, Onufriev S V, Savvatimskiy A I High Temp. 58 681 (2020); Aristova N M, Onufriev S V, Savvatimskiy A I Teplofiz. Vys. Temp. 58 749 (2020)
  32. Buchnev L M et al Sov. Phys. Dokl. 29 837 (1984); Buchnev L M et al Dokl. Akad. Nauk SSSR 278 1109 (1984)
  33. Onufriev S V Bull. Russ. Acad. Sci. Phys. 82 372 (2018); Onufriev S V Izv. Ross. Akad. Nauk Fiz. 82 430 (2018)
  34. Korobenko V N, Rakhel A D Int. J. Thermophys. 20 1257 (1999)
  35. Grigoriev I S, Meilikhov E Z (Eds) Handbook Of Physical Quantities (Boca Raton, FL: CRC Press, 1997); Translated from Russian, Grigoriev I S, Meilikhov E Z (Eds) Fizicheskie Velichiny. Spravochnik (Moscow: Energoatomizdat, 1991)
  36. Varshney D, Shriya S Int. J. Refract. Met. Hard Mater. 41 375 (2013)
  37. Onufriev S V, Savvatimskiy A I, Muboyadzhyan S A Mater. Res. Express 6 125554 (2019)
  38. Polezhaev Yu V, Yurevich F B Teplovaya Zashchita (Thermal Protection, Ed. A V Lykov) (Moscow: Energiya, 1976)
  39. Aristova N M, Belov G V High Temp. (1) (2022); Aristova N M, Belov G V Teplofiz. Vys. Temp. 60 23 (2022)
  40. Neel D S, Pears C D, Oglesby S (Jr.) "The thermal properties of thirteen solid materials to 5000F for their destruction temperatures" Technical Report WADD-TR-60-924 (Birmingham, AL: Southern Research Institute, 1962); http://contrails.iit.edu/reports/AD0275536
  41. Westrum E F (Jr.), Feick G J. Chem. Eng. Data 8 176 (1963)
  42. McClaine L A (Ed.) "Thermodynamic and kinetic studies for a refractory materials program" Technical Report No. ASD-TDR-62-204, Pt. 2 (Cambridge, MA: Arthur D. Little, Inc, 1962); http://contrails.iit.edu/reports/7395
  43. Levinson L S J. Chem. Phys. 42 2891 (1965)
  44. Kantor P B, Fomichev E N High Temp. 5 41 (1967); Kantor P B, Fomichev E N Teplofiz. Vys. Temp. 5 48 (1967)
  45. Bolgar A S, Guseva E A, Fesenko V V Poroshk. Metallurg. (1) 40 (1967)
  46. Turchanin A G, Fesenko V V Poroshk. Metallurg. (1) 88 (1968)
  47. Sheindlin A E, Belevich I S, Kozhevnikov I G High Temp. 11 599 (1973); Sheindlin A E, Belevich I S, Kozhevnikov I G Teplofiz. Vys. Temp. 11 666 (1973)
  48. Mebed M M, Yurchak R P, Korolev L A High Temp. 11 380 (1973); Mebed M M, Yurchak R P, Korolev L A Teplofiz. Vys. Temp. 11 427 (1973)
  49. Korshunov I G et al High Temp. 15 439 (1977); Korshunov I G et al Teplofiz. Vys. Temp. 15 521 (1977)
  50. Petrova I I, Chekhovskoi N Y High Temp. 16 1045 (1978); Petrova I I, Chekhovskoi N Y Teplofiz. Vys. Temp. 16 1226 (1978)
  51. Bolgar A S et al "Termodinamicheskie svoistva karbida tsirkoniya v oblasti gomogennosti (Thermodynamic properties of zirconium carbide in the region of homogeneity, Kiev, 1989)" All-Russian Institute for Scientific and Technical Information, Deposit No. 1162-V89 (1989)
  52. Aristova N M Russ. J. Phys. Chem. A 94 2685 (2020)
  53. Turchanin A G, Fesenko V V Poroshk. Metallurg. (6) 48 (1969)
  54. Storms E K, Wagner P High Temp. Sci. 5 454 (1973)
  55. Storms E K, Griffin J High Temp. Sci. 5 291 (1973)
  56. Tshai V A Zh. Fiz. Khim. 64 689 (1990)
  57. Tshai V A Zh. Fiz. Khim. 64 2354 (1990)
  58. Fernández Guillermet A J. Alloys Compd. 217 69 (1995)
  59. Hugosson H W et al Chem. Phys. Lett. 333 444 (2001)
  60. Jackson H F, Lee W E Comprehensive Nuclear Materials (Ed.-in-Chief R J M Konings) (Amsterdam: Elsevier, 2012) p. 339
  61. Katoh Y et al J. Nucl. Mater. 441 718 (2013)
  62. Xie C et al Phys. Chem. Chem. Phys. 18 12299 (2016)
  63. Jiang M et al Sci. Rep. 7 9344 (2017)
  64. Gasparrini C et al Sci. Rep. 10 6347 (2020)
  65. Schick H L (Ed.) Thermodynamics Of Certain Refractory Compounds Vol. 1, 2 (New York: Academic Press, 1966)
  66. Frenkel J Kinetic Theory Of Liquids (Oxford: The Clarendon Press, 1946); Translated from Russian, Frenkel J Kineticheskaya Teoriya Zhidkostei (Leningrad: Nauka, 1975)
  67. Zapadaeva T E, Petrov V A, Sokolov V V High Temp. 19 228 (1981); Zapadaeva T E, Petrov V A, Sokolov V V Teplofiz. Vys. Temp. 19 313 (1981)
  68. Korobenko V N, Savvatimskiy A I Russ. J. Phys. Chem. 77 1564 (2003)
  69. Korobenko V N, Savvatimskiy A I High Temp. 45 159 (2007); Korobenko V N, Savvatimskiy A I Teplofiz. Vys. Temp. 45 187 (2007)
  70. Korobenko V N, Savvatimskiy A I AIP Conf. Proc. 684 783 (2003)
  71. Savvatimskiy A I Carbon 43 1115 (2005)
  72. Savvatimskiy A I J. Phys. Condens. Matter 20 114112 (2008)
  73. Savvatimskiy A Carbon At High Temperatures (Springer Ser. in Materials Science) Vol. 134 (Cham: Springer, 2015)
  74. Manara D et al J. Eur. Ceramic Soc. 33 1349 (2013)
  75. Onufriev S V, Savvatimskii A I, Yanchuk V I Izmerit. Tekh. (8) 49 (2011)
  76. Korobenko V N "Eksperimental’noe issledovanie svoistv zhidkikh metallov i ugleroda pri vysokikh temperaturakh’’ (``Experimental investigation of the properties of liquid metals and carbon at high temperatures" Ph.D. Thesis (Phys.-Math. Sci.) (Moscow: Joint Institute for High Temperatures of the Russian Academy of Sciences, 2001)
  77. Reithof T, Acchione B D, Branyan E R Temperature, Its Measurement And Control In Science And Industry Vol. 3 (Ed. C M Herzfeld) Pt. 2 Applied Methods And Instruments (Ed. A I Dahl) (New York: Reinhold, 1967) p. 515
  78. Chase M W (Ed.) NIST-JANAF Themochemical Tables (J. Phys. Chem. Ref. Data, Monograph, No. 9) 4th ed. (Woodbury, NY: American Institute of Physics for the National Institute of Standards and Technology, 1998) p. 652
  79. Bolgar A S, Turchanin A G, Fesenko V V Termodinamicheskie Svoistva Karbidov (Thermodynamic Properties Of Carbides) (Kiev: Naukova Dumka, 1973)
  80. Turchanin A G Russ. J. Phys. Chem. A 54 2962 (1980)
  81. Barin I Thermochemical Data Of Pure Substances Vol. 1, 2 3rd ed. (Weinheim: VCH, 1995)
  82. Bgasheva T et al CALPHAD XLIV Intern. Conf. Computer Coupling of Phase Diagrams and Thermochemistry Calphad XLIV, May 31 - June 5, 2015 Loano, Italy
  83. Levinson L S J. Chem. Phys. 40 1437 (1964)
  84. Guseva E A Russ. J. Phys. Chem. A 45 2948 (1971)
  85. Knyazkov A M et al High Temp. High Press. 40 (3 - 4) 349 (2011)
  86. Zapadaeva T E, Petrov V A, Sokolov V V High Temp. 18 68 (1980); Zapadaeva T E, Petrov V A, Sokolov V V Teplofiz. Vys. Temp. 18 76 (1980)
  87. Sheindlin M et al Adv. Appl. Ceram. 48 (2018)
  88. Andrievskii R A et al Sov. Powder Metallurg. Metal Ceram. 6 (1) 65 (1967); Andrievskii R A et al Poroshk. Metallurg. (1) 85 (1967)
  89. Cedillos-Barraza O et al Sci. Rep. 6 37962 (2016)
  90. Klimov D A et al Tr. Mosk. Aviats. Inst. (46) ID 6 (2011); https://trudymai.ru/published.php?ID=26114
  91. Osama Gaballa Gaballa Processing Development of 4TaC-HfC and Related Carbides and Borides for Extreme Environments, Graduate Theses and Dissertations, Iowa State University (2012)
  92. Gusev A I Russ. J. Phys. Chem. 59 336 (1985); Gusev A I Zh. Fiz. Khim. 59 579 (1985)
  93. Arblaster J Anal. Bioanal. Chem. 407 6589 (2015)
  94. Deadmore D L J. Am. Cer. Soc. 48 357 (1965)
  95. Gokcen N A et al High Temp. Sci. 8 81 (1976)
  96. Hong Q-J, van de Walle A Phys. Rev. B 92 020104 (2015)
  97. Buinevich V S et al Ceramics Int. 46 (10) 16068 (2020)
  98. Potschke J et al J. Mater. Sci. 56 11237 (2021)
  99. Savvatimskii A I Onufriev S V High Temp. 58 778 (2020); Savvatimskii A I Onufriev S V Teplofiz. Vys. Temp. 58 865 (2020)
  100. Savvatimskii A I, Onufriev S V High Temp. 57 140 (2019)
  101. Vishnevetskaya I A et al High Temp. 18 414 (1980); Vishnevetskaya I A et al Teplofiz. Vys. Temp. 18 523 (1980)
  102. Simonenko E P "Novye podkhody k sintezu tugoplavkikh nanokristallicheskikh karbidov i oksidov i polucheniyu ul’travysokotemperaturnykh keramicheskikh materialov na osnove diborida gafniya’’ (``New approaches to the synthesis of refractory nanocrystalline carbides and oxides and the production of ultrahigh-temperature ceramic materials based on hafnium diboride)" Abstract of Doctoral Thesis (Chem. Sci.) (Moscow: Kurnakov Inst. of General and Inorganic Chemistry of the RAS, 2016)
  103. Lebedev S V, Khaikin S E Zh. Eksp. Teor. Fiz. 26 723 (1954)
  104. Ushakov S V et al Materials 12 2728 (2019)
  105. Wissner-Gross A D, Freer C E Phys. Rev. Lett. 110 168702 (2013)
  106. Yeh J-W et al Adv. Eng. Mater. 6 299 (2004)
  107. Savchenko A "Entropiinye effekty v real’nykh sistemakh (Entropy effectsreal systems)" Atomnaya Strategiya 110 14 (2015); http://www.proatom.ru/modules.php?name=News&file=print&sid=6440
  108. Savchenko A Energy Nature Of Configurational Entropy. Generation Of Entropy And Anti-entropy Flows (Saarbrucken: LAMBERT, 2015)
  109. Fernandes C M, Senos A M R Int. J. Refract. Met. Hard Mater. 29 405 (2011)
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