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Inductive-resonant mechanism of nonradiative transitions in ions and molecules in condensed phaseS I Vavilov State Optical Institute, Birzhevaya liniya 12, St. Petersburg, 199034, Russian Federation The inductive-resonant mechanism of nonradiative transitions between electronic levels in lanthanide and transition metal ions and complex molecules in the condensed phase is systematically described. A quantum-mechanical justification is presented, and theoretical expectations conforming to the mechanisms and quantitative rate constants of nonradiative transitions are compared with experiment.
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