RSS feeds
ÐóññêèéEnglish
Issue 4, 2024
Volume year page
Issues Authors PACS Subscription For authors

Issues

 / 

1992

 / 

September

←  →

Reviews of topical problems


Small metal particles


Vereshchagin Institute for High Pressure Physics, Russian Academy of Sciences, Kaluzhskoe shosse 14, Troitsk, Moscow, 108840, Russian Federation

This review article is devoted to results of theoretical and experimental investigations of properties of nanometer metal particles. First, the modern theory of equilibrium structures and shapes of small particles is presented. The next Section deals with the thermodynamics of small particles. It reflects the present state of the theory of surface forces for small particles, including crystalline ones. Validity conditions are pointed out for the standard approach, and an alternative approach is described which is adequate for particles surrounded by their saturated vapor. In it the Laplace pressure is not a real physical force, but a formal quantity that describes the size dependence of the chemical potential. Specific features are described of melting and interphase fluctuations in small particles. In describing the electron properties of the particles emphasis is laid on the smoothed level density and the size dependence of the Fermi energy. Some effects caused by this dependence are presented, in particular the mutual charging of particles of different sizes which manifests itself in an anomalously strong attraction between particles and so on. Magnetic properties of small particles are also described including macroscopic quantum tunneling of magnetization.

Fulltext pdf (1.9 MB)
Fulltext is also available at DOI: 10.1070/PU1992v035n09ABEH002261
PACS: 61.46.Df, 01.30.Vv, 65.80.+n, 64.70.Dv, 73.22.−f, 75.50.Tt (all)
DOI: 10.1070/PU1992v035n09ABEH002261
URL: https://ufn.ru/en/articles/1992/9/b/
Citation: Nagaev E L "Small metal particles" Sov. Phys. Usp. 35 (9) 747–782 (1992)
BibTexBibNote ® (generic)BibNote ® (RIS)MedlineRefWorks

Îðèãèíàë: Íàãàåâ Ý Ë «Ìàëûå ìåòàëëè÷åñêèå ÷àñòèöû» ÓÔÍ 162 (9) 49–124 (1992); DOI: 10.3367/UFNr.0162.199209b.0049

References (282) Cited by (144) ↓ Similar articles (20)

  1. Magomedov M N Phys. Rev. B 109 (3) (2024)
  2. Deviatova V N, Nekrasov A N, Bondarenko G V Geochem. Int. 62 140 (2024)
  3. Andrieieva O L, Tkachenko V I 118 (2023)
  4. Borts B V, Vorobyov I A et al 58 (2023)
  5. Ikim M I, Gerasimov G N et al IJMS 24 1570 (2023)
  6. Trakhtenberg L I, Ikim M I et al Chemosensors 11 320 (2023)
  7. Trakhtenberg L I Russ. J. Phys. Chem. B 17 600 (2023)
  8. Kawano H Progress In Surface Science 97 100583 (2022)
  9. Poletaev G M, Sitnikov A A et al J. Exp. Theor. Phys. 134 183 (2022)
  10. Magomedov M N Phys. Solid State 63 1465 (2021)
  11. Yasnikov I S, Gryzunova N N Jetp Lett. 114 284 (2021)
  12. Fedoseev V B, Shishulin A V Tech. Phys. 66 34 (2021)
  13. Gerasimov G N, Gromov V F et al Russ. J. Phys. Chem. B 15 1072 (2021)
  14. Poletaev G, Sitnikov A, Filimonov V Lett. Mater. 11 204 (2021)
  15. Zhukhovitskii D I, Zhakhovsky V V 152 (22) (2020)
  16. Magomedov M N J. Synch. Investig. 14 1208 (2020)
  17. Korotun A V, Koval’ A A, Reva V I J Appl Spectrosc 86 606 (2019)
  18. Pirozerski A L, Smirnova O I et al Physics Letters A 383 125872 (2019)
  19. Levdansky V V, Šolcová O, Izák P Materials Chemistry And Physics 211 117 (2018)
  20. Gerasimov G N, Gromov V F, Trakhtenberg L I Russ. J. Phys. Chem. 92 1087 (2018)
  21. Kumar P, Koledov V et al 2018 IEEE International Conference on Manipulation, Manufacturing and Measurement on the Nanoscale (3M-NANO), (2018) p. 167
  22. Dragan G S, Kutarov V V IEEE Trans. Plasma Sci. 46 743 (2018)
  23. Aref’eva L P, Shebzukhova I G Phys. Solid State 60 1273 (2018)
  24. Yushchenko O V, Badalyan A Yu 2017 IEEE 7th International Conference Nanomaterials: Application & Properties (NAP), (2017) p. 03NNSA16-1
  25. Hrytsyna O R Mater Sci 53 273 (2017)
  26. Khnykov A Yu, Zav’yalov S A et al Russ. J. Phys. Chem. B 10 23 (2016)
  27. Shirinyan A S Metallofiz. Noveishie Tekhnol. 37 475 (2016)
  28. Kolinko P A, Selishchev D S, Kozlov D V Theor Exp Chem 51 96 (2015)
  29. Il’yushchenkov D S, Kozhevin V M, Gurevich S A Phys. Solid State 57 1710 (2015)
  30. Kuznetsova I A, Lebedev M E, Yushkanov A A Tech. Phys. 60 1261 (2015)
  31. Magomedov M N Nanotechnol Russia 10 89 (2015)
  32. Magomedov M N Nanotechnol Russia 9 293 (2014)
  33. Magomedov M N Tech. Phys. 59 1658 (2014)
  34. Bishchaniuk T M, Grygorchak I I et al Tech. Phys. 59 1085 (2014)
  35. Buranbaev M Zh, Aliev B A et al Lecture Notes In Electrical Engineering Vol. Future Information Communication Technology and ApplicationsRadiation Modification of the Structure of Nanosized Metal Powders235 Chapter 52 (2013) p. 471
  36. Liu Yu, Liu Q et al Carbon 64 132 (2013)
  37. Karasevskii A I Eur. Phys. J. B 86 (4) (2013)
  38. Magomedov M N Tech. Phys. Lett. 39 409 (2013)
  39. Belyaev B A, Drokin N A Phys. Solid State 54 360 (2012)
  40. Parshin P P, Zemlyanov M G et al J. Exp. Theor. Phys. 114 440 (2012)
  41. Magomedov M N J. Synch. Investig. 6 430 (2012)
  42. Karpov S V, Semina P N, Gavrilyuk A P Colloid J 74 305 (2012)
  43. Rekhviashvili S S, Kishtikova E V Prot Met Phys Chem Surf 48 402 (2012)
  44. Morozov P V, Grigor’ev E I et al Phys. Solid State 54 2291 (2012)
  45. Shikov A A, Zemlyanov M G et al Phys. Solid State 54 2345 (2012)
  46. Yasnikov I S Phys. Solid State 53 1917 (2011)
  47. Pirozerskii A L, Charnaya E V et al Acoust. Phys. 57 637 (2011)
  48. Koropov A V J. Synch. Investig. 5 780 (2011)
  49. Nepijko S A, Kutnyakhov D et al J Nanopart Res 13 6263 (2011)
  50. Chandrasekar G, Mougin K et al Applied Surface Science 257 4175 (2011)
  51. Magomedov M N J. Synch. Investig. 5 705 (2011)
  52. Parshin P P, Zemlyanov M G et al J. Exp. Theor. Phys. 111 996 (2010)
  53. Kozhushner M A, Trakhtenberg L I J. Exp. Theor. Phys. 111 1010 (2010)
  54. Gladkikh N T, Kryshtal A P, Bogatyrenko S I Tech. Phys. 55 1657 (2010)
  55. Magomedov M N Phys. Solid State 52 1283 (2010)
  56. Shpak A P, Shevchenko A B et al Usp. Fiz. Met. 11 139 (2010)
  57. Dolgusheva E B, Trubitsin V Yu Phys. Solid State 52 1238 (2010)
  58. Shirinyan A S, Gusak A M Diffusion‐Controlled Solid State Reactions 1 (2010) p. 425
  59. Kozhushner M A, Trakhtenberg L I Russ. J. Phys. Chem. B 4 502 (2010)
  60. Samsonov V M, Kharechkin S S et al Bull. Russ. Acad. Sci. Phys. 74 673 (2010)
  61. Magomedov M N High Temp 47 45 (2009)
  62. Karpov S V, Isaev I L et al Colloid J 71 345 (2009)
  63. Dolgusheva E B, Trubitsin V Yu Phys. Solid State 51 2497 (2009)
  64. Borisov B F, Gartvik A V et al Acoust. Phys. 55 816 (2009)
  65. Shirinyan A S, Bilogorodskyy Y S, Schmelzer J W P Acta Materialia 57 5771 (2009)
  66. Drakon A, Emelianov A, Eremin A Shock Waves Chapter 18 (2009) p. 907
  67. Grytsenko K P Opt. Mem. Neural Networks 18 290 (2009)
  68. Assovskiy Igor G Propellants Explo Pyrotec 33 51 (2008)
  69. Burakov V S, Savastenko N A et al J Appl Spectrosc 75 394 (2008)
  70. Frolov G I, Bachina O I et al Tech. Phys. 53 1059 (2008)
  71. Levdanskii V V, Smolik J, Moravec P J Eng Phys Thermophy 81 985 (2008)
  72. Koropov A V Phys. Solid State 50 2184 (2008)
  73. Styrkas A D Inorg Mater 44 470 (2008)
  74. Rekhviashvili S Sh Phys. Metals Metallogr. 105 421 (2008)
  75. Dresvyannikov A F, Kolpakov M E Prot Met 44 43 (2008)
  76. Yakimovich N O, Ezhevskii A A et al Russ Chem Bull 57 520 (2008)
  77. Gerasimov G N, Trakhtenberg L I Thin Films And Nanostructures Vol. Physico-Chemical Phenomena in Thin Films and at Solid SurfacesChapter 10 Vapor Deposited Composite Films Consisting of Dielectric Matrix with Metal/Semiconductor Nanoparticles34 (2007) p. 523
  78. Magomedov M N Tech. Phys. Lett. 33 212 (2007)
  79. Gurevich S A, Kozhevin V M et al Thin Films And Nanostructures Vol. Physico-Chemical Phenomena in Thin Films and at Solid SurfacesChapter 15 Charge Effects in Catalysis by Nanostructured Metals34 (2007) p. 725
  80. Zav’yalov S A, Schoonman J et al Russ. J. Phys. Chem. B 1 171 (2007)
  81. Chernavskii P A, Peskov N V et al Russ. J. Phys. Chem. B 1 394 (2007)
  82. Batrakov A, Onischenko S et al IEEE Trans. Dielect. Electr. Insul. 14 544 (2007)
  83. Frolov G I Bull. Russ. Acad. Sci. Phys. 71 1629 (2007)
  84. Zemlyanov M G, Panova G Kh et al Phys. Solid State 48 139 (2006)
  85. Borman V D, Borisyuk P V et al J. Exp. Theor. Phys. 102 303 (2006)
  86. Borisov B F, Gartvik A V et al Acoust. Phys. 52 138 (2006)
  87. Shirinyan A, Wautelet M, Belogorodsky Y J. Phys.: Condens. Matter 18 2537 (2006)
  88. Shirinyan A S, Gusak A M, Wautelet M Acta Materialia 53 5025 (2005)
  89. Magomedov M N Tech. Phys. Lett. 31 13 (2005)
  90. Magomedov M N High Temp 43 870 (2005)
  91. Shirinyan A S, Pasichnyy M O Nanotechnology 16 1724 (2005)
  92. Kurbatsky V P, Pogosov V V Vacuum 74 185 (2004)
  93. Kurbatsky V P, Pogosov V V Phys. Solid State 46 543 (2004)
  94. Shirinyan A S, Wautelet M Nanotechnology 15 1720 (2004)
  95. Koropov A V Phys. Solid State 46 1502 (2004)
  96. Shirinyan A S, Gusak ‡ A M Philosophical Magazine 84 579 (2004)
  97. Magomedov M N Phys. Solid State 46 954 (2004)
  98. Charnaya E V, Michel D et al J. Phys.: Condens. Matter 15 5469 (2003)
  99. Magomedov M N Phys. Solid State 45 1213 (2003)
  100. Kasperovich V S, Charnaya E V et al Phys. Solid State 45 1802 (2003)
  101. Éntin M V, Braginsky L S J. Exp. Theor. Phys. 97 174 (2003)
  102. Parfen’eva L S, Smirnov I A et al Phys. Solid State 45 381 (2003)
  103. Trakhtenberg L I, Axelrod E et al Journal Of Non-Crystalline Solids 305 190 (2002)
  104. Borman V D, Lai X Ch et al Jetp Lett. 76 444 (2002)
  105. Trakhtenberg L I, Gerasimov G N et al Radiation Physics And Chemistry 65 479 (2002)
  106. Pogosov V V, Kurbatsky V P J. Exp. Theor. Phys. 92 304 (2001)
  107. Éntin M V, Mahmoodian M M Jetp Lett. 73 149 (2001)
  108. Suzdalev I P, Suzdalev P I Russ. Chem. Rev. 70 177 (2001)
  109. Meshcheryakov V V Phys. Solid State 43 517 (2001)
  110. Faivre C, Bellet D, Dolino G 87 2131 (2000)
  111. Zaitsev S V, Karpov A V Instrum Exp Tech 43 566 (2000)
  112. Dereppe J M, Borisov B F et al Phys. Solid State 42 193 (2000)
  113. Pogosov V V, Pogosov W V, Kotlyarov D P J. Exp. Theor. Phys. 90 908 (2000)
  114. Trakhtenberg L I, Gerasimov G N et al Studies In Surface Science And Catalysis Vol. 12th International Congress on Catalysis, Proceedings of the 12th ICCNanoheterogeneous metal-polymer composites as a new type of effective and selective catalysts130 (2000) p. 941
  115. Postovalova G G, Roginskaya Yu E et al Inorg Mater 36 364 (2000)
  116. Meshcheryakov V V Phys. Solid State 42 1749 (2000)
  117. Meshcheryakov V V, Kuznetsov G D, Yuldashev A A J. Exp. Theor. Phys. 89 86 (1999)
  118. Fomichev S V, Zaretsky D F J. Phys. B: At. Mol. Opt. Phys. 32 5083 (1999)
  119. ZELEVINSKY VLADIMIR Int. J. Mod. Phys. B 13 569 (1999)
  120. Jigatch A N, Leipunsky I O et al Rapid Commun. Mass Spectrom. 13 2109 (1999)
  121. Chang S-S, Shih Ch-W et al Langmuir 15 701 (1999)
  122. Buttard D, Dolino G et al 85 7105 (1999)
  123. Kamilov I K, Murtazaev A K, Aliev Kh K Uspekhi Fizicheskikh Nauk 169 773 (1999)
  124. Baidakova M V, Siklitsky V I, Vul A Ya Chaos, Solitons & Fractals 10 2153 (1999)
  125. Borisov B F, Charnaya E V et al J. Phys.: Condens. Matter 11 10259 (1999)
  126. Latkin A S J Min Sci 34 278 (1998)
  127. Gusev A I Uspekhi Fizicheskikh Nauk 168 55 (1998)
  128. Memmert U, Hodel U, Hartmann U 15 1364 (1997)
  129. Karpov S V, Popov A K, Slabko V V Jetp Lett. 66 106 (1997)
  130. Aleksenskii A E, Baidakova M V et al Phys. Solid State 39 1007 (1997)
  131. Meshcheryakov V V J. Exp. Theor. Phys. 84 1010 (1997)
  132. Borisov B F, Charnaya E V et al J. Phys.: Condens. Matter 9 3377 (1997)
  133. Vieira A, Fiolhais C et al Int. J. Quantum Chem. 60 1537 (1996)
  134. Nagaev E L, Zil’bervarg V E Phys. Rev. B 53 5011 (1996)
  135. Hodel U, Memmert U, Hartmann U Phys. Rev. B 54 17888 (1996)
  136. Nagaev E L, Podel’shchikov A I Journal Of Magnetism And Magnetic Materials 159 227 (1996)
  137. Zelevinsky V Annu. Rev. Nucl. Part. Sci. 46 237 (1996)
  138. Pogosov V V Vacuum 46 455 (1995)
  139. Borisov B F, Charnaya E V et al Solid State Communications 92 531 (1994)
  140. Ageev L A, El-Ashkhab Kh I J Appl Spectrosc 60 124 (1994)
  141. Andrievskii R A Russ. Chem. Rev. 63 411 (1994)
  142. Andrievski R A Journal Of Materials Science 29 614 (1994)
  143. Zelevinsky V G Nuclear Physics A 570 411 (1994)
  144. Ya G M Physica Status Solidi (b) 178 59 (1993)
© 1918–2024 Uspekhi Fizicheskikh Nauk
Email: ufn@ufn.ru Editorial office contacts About the journal Terms and conditions