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Эффект Яна — Теллера и магнетизм: соединения переходных металлов

 а,
а Институт теоретической и прикладной электродинамики РАН, Москва, Российская Федерация

СОДЕРЖАНИЕ
1. Введение
2. Ян-теллеровские ионы в кристаллах
3. Эффект Яна-Теллера для изолированных центров и кооперативный эффект Яна-Теллера
а) Эффект Яна-Теллера для изолированного центра. б) Взаимодействие ян-теллеровских ионов в концентрированных системах.
4. Обменное взаимодействие в ян-теллеровских системах
а) Суперобмен и модель Хаббарда. б) Суперобмен при орбитальном вырождении. в) Суперобменное упорядочение орбиталей в конкретных веществах
5. Ионы с трехкратным орбитальным вырождением (t2g-ионы)
6. Структурные фазовые переходы в веществах с орбитальным вырождением
а) Ферродисторсионное упорядочение (кристаллы со структурой шпинели). б) Антиферродисторсионное упорядочение (кристаллы со структурой перовскита). в) Фазы с утроением периода и несоизмеримые структуры.
7. Температурная зависимость магнитных свойств ян-теллеровских систем
а) Изменение орбитальной структуры и обменное взаимодействие. б) Подавление обменного взаимодействия за счет эффекта Яна-Теллера.
8. Влияние магнитного поля на ян-теллеровские системы
9. Методы исследования орбитального упорядочения
10. Некоторые дополнительные теоретические вопросы
11. Заключение
Цитированная литература

Текст pdf (3,3 Мб)
English fulltext is available at DOI: 10.1070/PU1982v025n04ABEH004537
PACS: 71.70.Gm, 71.70.Ej, 75.30.Et (все)
DOI: 10.3367/UFNr.0136.198204c.0621
URL: https://ufn.ru/ru/articles/1982/4/c/
Цитата: Кугель К И, Хомский Д И "Эффект Яна — Теллера и магнетизм: соединения переходных металлов" УФН 136 621–664 (1982)
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English citation: Kugel’ K I, Khomskii D I “The Jahn-Teller effect and magnetism: transition metal compounds” Sov. Phys. Usp. 25 231–256 (1982); DOI: 10.1070/PU1982v025n04ABEH004537

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