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Spectroscopy of the interaction of a low-energy electron beam with organic luminescent molecules

  a,   b
a Research Institute for Nuclear Problems Belarusian State University, Bobruiskaya 11, Minsk, 220030, Belarus
b Chuvash State University, Moskovskij pr. 15, Cheboksary, 428015, Russian Federation

We present a brief review of the results of spectroscopic studies of the interaction of a beam of low-energy monokinetic tunable-energy electrons with organic luminescent molecules. Data are presented on elastic scattering, the excitation of vibrational and electronic transitions, luminescence properties, and the formation of positive and negative ions for a number of molecules. It is shown that the passage of electrons through the gaseous and thin-film phases of organic samples is close in nature. For all processes, except the excitation of triplet transitions and the formation of negative ions, the dipole interaction prevails, even in the near-threshold region. The results of the conducted research will be useful for understanding the conversion of electron energy by organic molecules in electronics, where the direct study of elementary processes is very difficult, as well as in biology and plasma chemistry.

Fulltext pdf (841 KB)
Fulltext is also available at DOI: 10.3367/UFNe.2022.05.039197
Keywords: organic molecules, excitation, electrons, luminescence, ionization, energy loss spectra
PACS: 33.15.Ta, 33.50.Dq, 34.50.Bw, 34.50.Gb (all)
DOI: 10.3367/UFNe.2022.05.039197
URL: https://ufn.ru/en/articles/2023/2/c/
001097218300003
2-s2.0-85182911987
2023PhyU...66..173K
Citation: Kukhta A V, Kazakov S M "Spectroscopy of the interaction of a low-energy electron beam with organic luminescent molecules" Phys. Usp. 66 173–181 (2023)
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Received: 28th, March 2022, revised: 19th, April 2022, 28th, May 2022

Оригинал: Кухто А В, Казаков С М «Спектроскопия взаимодействия пучка низкоэнергетических электронов с органическими люминесцирующими молекулами» УФН 193 182–191 (2023); DOI: 10.3367/UFNr.2022.05.039197

References (59) ↓ Similar articles (3)

  1. Kukhta A V J. Appl. Spectrosc. 70 165 (2003); Kukhta A V Zh. Prikl. Spektrosk. 70 151 (2003)
  2. Nalwa H S (Ed.) Handbook Of Organic Electronics And Photonics (Los Angeles, CA: American Scientific Publ., 2006)
  3. Kukhto A V J. Appl. Spectrosc. 65 722 (1998); Kukhto A V Zh. Prikl. Spektrosk. 65 694 (1998)
  4. Kukhta A V Mol. Cryst. Liq. Cryst. 427 71 (2005)
  5. Vilar M R et al J. Phys. Chem. B 112 6957 (2008)
  6. Naaman R, Sanche L Chem. Rev. 107 1553 (2007)
  7. Shao Y et al J. Phys. Chem. C 121 2466 (2017)
  8. Gruzinskii V V, Kukhto A V J. Appl. Spectrosc. 47 895 (1987); Gruzinskii V V, Kukhto A V Zh. Prikl. Spektrosk. 47 409 (1987)
  9. Hasted J B Physics Of Atomic Collisions (Washington: Butterworths, 1964); Translated into Russian, Hasted J B Fizika Atomnykh Stolknovenii (Moscow: Mir, 1965)
  10. Drukarev G F Collisions Of Electrons With Atoms And Molecules (New York: Plenum Press, 1987); Translated from Russian, Drukarev G F Stolknoveniya Elektronov S Atomami I Molekulami (Moscow: Nauka, 1978)
  11. Slovetskii D I Mekhanizmy Khimicheskikh Reaktsii V Neravnovesnoi Plazme (Mechanisms Of Chemical Reactions In Nonequilibrium Plasma) (Moscow: Nauka, 1980)
  12. Moore J H et al Nanofabrication Using Focused Ion And Electron Beams: Principles And Applications (Nanomanufacturing Ser.) Vol. 1 (Eds I Utke, S Moshkalev, P Russell) (Oxford: Oxford Univ. Press, 2012) p. 184
  13. Choong V-E et al Macromol. Symp. 125 83 (1998)
  14. Kukhta A V J. Appl. Spectrosc. 73 879 (2006); Kukhta A V Zh. Prikl. Spektrosk. 73 786 (2006)
  15. Kukhta A V et al J. Chem. Phys. 127 084316 (2007)
  16. Kukhta A V et al Chem. Phys. Lett. 434 11 (2007)
  17. Borisevich N A et al J. Appl. Spectrosc. 71 681 (2004); Borisevich N A et al Zh. Prikl. Spektrosk. 71 626 (2004)
  18. Kukhta A V et al Chem. Phys. Lett. 373 492 (2003)
  19. Doering J P J. Chem. Phys. 51 2866 (1969)
  20. Borisevich N A et al J. Appl. Spectrosc. 68 447 (2001); Borisevich N A et al Zh. Prikl. Spektrosk. 68 343 (2001)
  21. Borisevich N A et al J. Appl. Spectrosc. 69 190 (2002); Borisevich N A et al Zh. Prikl. Spektrosk. 69 166 (2002)
  22. Kazakov S, Kukhta A, Suchkov V J. Fluorescence 10 409 (2000)
  23. Gruzinskii V V et al Spectrosc. Lett. 27 65 (1994)
  24. Andreev V A et al Proc. SPIE 5483 157 (2004)
  25. Borisevich N A et al J. Appl. Spectrosc. 68 871 (2001); Borisevich N A et al Zh. Prikl. Spektrosk. 68 664 (2001)
  26. Borisevich N A et al J. Appl. Spectrosc. 72 503 (2005); Borisevich N A et al Zh. Prikl. Spektrosk. 72 468 (2005)
  27. Borisevich N A et al J. Appl. Spectrosc. 69 487 (2002); Borisevich N A et al Zh. Prikl. Spektrosk. 69 421 (2002)
  28. Kukhto A V et al J. Appl. Spectrosc. 74 760 (2007); Kukhto A V et al Zh. Prikl. Spektrosk. 74 684 (2007)
  29. Kulinich A V et al Chem. Phys. 503 20 (2018)
  30. Chen J, Reed M A Chem. Phys. 281 127 (2002)
  31. Ibach H, Mills D L Electron Energy Loss Spectroscopy And Surface Vibrations (New York: Academic Press, 1982), Ch. 3
  32. Salomon E et al Thin Solid Films 466 259 (2004)
  33. Kukhto A V, Kolesnik E E, Ritchik D V Dokl. Nats. Akad. Nauk Belarusi 47 69 (2003)
  34. Borisevich N A Vozbuzhdennye Sostoyaniya Slozhnykh Molekul V Gazovoi Faze (Excited States Of Complex Molecules In The Gas Phase) (Minsk: Nauka i Tekhnika, 1967)
  35. Kukhta A V et al Proc. SPIE 4747 224 (2002)
  36. Gruzinskii V V, Kukhto A V Izv. Akad. Nauk Belorus. SSR. Ser. Fiz. (3) 64 (1989)
  37. Kukhta A V et al J. Appl. Spectrosc. 88 825 (2021); Kukhta A V et al Zh. Prikl. Spektrosk. 88 647 (2021)
  38. Baranov I Yu et al J. Appl. Spectrosc. 62 342 (1995); Baranov I Yu et al Zh. Prikl. Spektrosk. 62 188 (1995)
  39. Gruzinskii V V, Kukhto A V J. Appl. Spectrosc. 65 152 (1998); Gruzinskii V V, Kukhto A V Zh. Prikl. Spektrosk. 65 146 (1998)
  40. Kukhto A V, Mit’kovets A I, Ritchik D V J. Appl. Spectrosc. 71 512 (2004); Kukhto A V, Mit’kovets A I, Ritchik D V Zh. Prikl. Spektrosk. 71 472 (2004)
  41. Gruzinskii V V et al J. Appl. Spectrosc. 51 1258 (1989); Gruzinskii V V et al Zh. Prikl. Spektrosk. 51 924 (1989)
  42. Borisevich N A et al Opt. Spectrosc. 62 333 (1987); Borisevich N A et al Opt. Spektrosk. 62 558 (1987)
  43. Romanova L G et al J. Appl. Spectrosc. 75 506 (2008); Romanova L G et al Zh. Prikl. Spektrosk. 75 482 (2008)
  44. Romanova L G et al Int. J. Mass Spectrom. 279 10 (2009)
  45. Kukhta A V et al Eur. J. Mass Spectrom. 15 563 (2009)
  46. Wannier G H Phys. Rev. 90 817 (1953)
  47. Kukhta A V et al Int. J. Mass Spectrom. 230 41 (2003)
  48. Pshenichnyuk S A, Asfandiarov N L, Kukhto A V Khim. Fiz. 26 (7) 5 (2007)
  49. Pshenichnyuk S A Tech. Phys. 56 754 (2011); Pshenichnyuk S A Zh. Tekh. Fiz. 81 (6) 8 (2011)
  50. Pshenichnyuk S A et al Russ. J. Phys. Chem. B 4 1014 (2010); Pshenichnyuk S A et al Khim. Fiz. 29 (11) 82 (2010)
  51. Pshenichnyuk S A, Asfandiarov N L, Kukhta A V Phys. Rev. A 86 052710 (2012)
  52. Christophorou L G, Hadjiantonious A, Carter J G J. Chem. Soc. Faraday Trans. 2 69 1713 (1973)
  53. Haneef H F, Zeidell A M, Jurchescu O D J. Mater. Chem. C 8 759 (2020)
  54. Asfandiarov N L et al J. Chem. Phys. 151 134302 (2019)
  55. Pshenichnyuk S A et al J. Chem. Phys. 151 214309 (2019)
  56. Goryunkov A A et al J. Phys. Chem. A 124 690 (2020)
  57. Pshenichnyuk S A et al J. Chem. Phys. 155 184301 (2021)
  58. Pshenichnyuk S A Phys. Usp. 65 163 (2022); Pshenichnyuk S A Usp. Fiz. Nauk 192 177 (2022)
  59. Kukhta A V et al J. Phys. B 41 205701 (2008)

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