RSS feeds
РусскийEnglish
Issue 11, 2024
Volume year page
Issues Authors PACS Subscription For authors

Issues

 / 

2021

 / 

November

←  →

In memory of Vladimir Evgen'evich Fortov. Reviews of topical problems


Supercritical fluid of metal vapor plasmas, rare gases, and excitons

, † 
Joint Institute for High Temperatures, Russian Academy of Sciences, ul. Izhorskaya 13/19, Moscow, 127412, Russian Federation

We discuss vapor—liquid and dielectric—metal transitions and the metallization process via an exponential increase in conductivity under compression in metal vapors. We investigate the `cold ionization' mechanism based on a proposed hypothesis on electron jellium existing as a seed of the conduction band in the gas phase. A number of physical models are proposed that combine methods to describe the interaction of atoms as cohesive and collective, caused by the presence of the electron jellium. The parameters of critical points and binodals are calculated for most metals in the Mendeleev periodic table, as well as for hydrogen and excitons. Useful relations between solid-state characteristics of metals and the parameters of critical points are established. Theoretical calculations are compared with experimental results for the equation of state of metal vapors and the conductivity at the critical points, on the binodal, and on near-critical isotherms, with the cold and thermal ionization processes taken into account. We propose the model of a 'jump-like' metallization of inert gases under compression, similar in nature to the Mott transition. We conclude that, in the vicinity of the critical point, metal vapors exhibit properties of metals due to the presence of the cold ionization process.

Fulltext pdf (845 KB)
Fulltext is also available at DOI: 10.3367/UFNe.2020.08.038825
Keywords: supercritical fluid, vapor—liquid (dielectric—metal) phase transition, cohesion, electron jellium, metallization
PACS: 52.25.Kn, 52.27.Gr, 64.10.+h, 64.60.F−, 64.70.F−, 71.30.+h, 72.15.−v (all)
DOI: 10.3367/UFNe.2020.08.038825
URL: https://ufn.ru/en/articles/2021/11/d/
000765556800003
2-s2.0-85125709947
2021PhyU...64.1125K
Citation: Khomkin A L, Shumikhin A S "Supercritical fluid of metal vapor plasmas, rare gases, and excitons" Phys. Usp. 64 1125–1148 (2021)
BibTexBibNote ® (generic)BibNote ® (RIS)MedlineRefWorks

Received: 28th, May 2020, revised: 5th, July 2020, 21st, August 2020

Оригинал: Хомкин А Л, Шумихин А С «Сверхкритический флюид плазмы паров металлов, инертных газов и экситонов» УФН 191 1187–1211 (2021); DOI: 10.3367/UFNr.2020.08.038825

References (143) ↓ Cited by (5) Similar articles (1)

  1. Zel’dovich Ya B, Landau L D Zh. Eksp. Teor. Fiz. 14 32 (1944); Landau L D, Zeldovich Ya B Acta Physicochim. USSR 18 194 (1943)
  2. Brazhkin V V i dr Usp. Fiz. Nauk 182 1137 (2012); Brazhkin V V et al Phys. Usp. 55 1061 (2012)
  3. Brazhkin V V Usp. Fiz. Nauk 187 1028 (2017); Brazhkin V V Phys. Usp. 60 954 (2017)
  4. Khomkin A L, Shumikhin A S Zh. Eksp. Teor. Fiz. 152 1393 (2017); Khomkin A L, Shumikhin A S J. Exp. Theor. Phys. 125 1189 (2017)
  5. DeSilva A W, Rakhel A D Contrib. Plasma Phys. 45 236 (2005)
  6. Khomkin A L, Shumikhin A S Zh. Eksp. Teor. Fiz. 147 775 (2015); Khomkin A L, Shumikhin A S J. Exp. Theor. Phys. 120 672 (2015)
  7. Khomkin A L, Shumikhin A S Fizika Plazmy 39 958 (2013); Khomkin A L, Shumikhin A S Plasma Phys. Rep. 39 857 (2013)
  8. Fortov V E i dr Zh. Eksp. Teor. Fiz. 124 288 (2003); Fortov V E et al J. Exp. Theor. Phys. 97 259 (2003)
  9. Khomkin A L, Shumikhin A S Zh. Eksp. Teor. Fiz. 155 869 (2019); Khomkin A L, Shumikhin A S J. Exp. Theor. Phys. 128 739 (2019)
  10. Khomkin A L, Shumikhin A S Zh. Eksp. Teor. Fiz. 141 101 (2012); Khomkin A L, Shumikhin A S J. Exp. Theor. Phys. 114 89 (2012)
  11. Khomkin A L, Shumikhin A S Zh. Eksp. Teor. Fiz. 146 518 (2014); Khomkin A L, Shumikhin A S J. Exp. Theor. Phys. 119 453 (2014)
  12. Renkert H, Hensel F, Franck E U Ber. Bunsenges. Phys. Chem. 75 507 (1971)
  13. Jüngst S, Knuth B, Hensel F Phys. Rev. Lett. 55 2160 (1985)
  14. Franz G, Freyland W, Hensel F J. Phys. Colloques 41 (C8) C8-70 (1980)
  15. Pfeifer H P, Freyland W, Hensel F Ber. Bunsenges. Phys. Chem. 83 204 (1979)
  16. Kikoin I K, Senchenkov A P Fiz. Met. Metalloved. 24 843 (1967)
  17. Götzlaff W, Schönherr G, Hensel F Z. Phys. Chem. 156 219 (1988)
  18. Ohse R W (Ed.) Handbook Of Thermodynamic And Transport Properties Of Alkali Metals (New York: Wiley, 1985)
  19. Hensel F, Marceca E, Pilgrim W C J. Phys. Condens. Matter 10 11395 (1998)
  20. Alekseev V A, Vedenov A A Usp. Fiz. Nauk 102 665 (1970); Alekseev V A, Vedenov A A Sov. Phys. Usp. 13 830 (1970)
  21. Likal’ter A A Teplofizika Vysokikh Temperatur 16 1219 (1978)
  22. Khrapak A G Teplofizika Vysokikh Temperatur 17 1147 (1979)
  23. Yakubov I T Dokl. Akad. Nauk SSSR 247 841 (1979)
  24. Zhukhovitskii D I Zhurn. Fizicheskoi Khimii 67 1962 (1993)
  25. Ali (Basu) M et al J. Chem. Phys. 124 024325 (2006)
  26. Khomkin A L, Shumikhin A S Teplofizika Vysokikh Temperatur 51 663 (2013); Khomkin A L, Shumikhin A S High Temp. 51 594 (2013)
  27. Semenov A M, Petkoglo N P, Zakharova O D Teplofizika Vysokikh Temperatur 46 374 (2008); Semenov A M, Petkoglo N P, Zakharova O D High Temp. 46 337 (2008)
  28. Likal’ter A A Usp. Fiz. Nauk 162 (7) 119 (1992); Likal’ter A A Sov. Phys. Usp. 35 591 (1992)
  29. Likal’ter A A Usp. Fiz. Nauk 170 831 (2000); Likal’ter A A Phys. Usp. 43 777 (2000)
  30. Likalter A A, Schneidenbach H Physica A 277 293 (2000)
  31. Lang G Z. Metallkd. 68 213 (1977)
  32. Apfelbaum E M, Vorob’ev V S J. Chem. Phys. 139 046101 (2013)
  33. Apfelbaum E M, Vorob’ev V S J. Phys. Chem. B 119 11825 (2015)
  34. Apfelbaum E M, Vorob’ev V S J. Phys. Chem. B 120 4828 (2016)
  35. Fortov V E, Dremin A N, Leont’ev A A Teplofizika Vysokikh Temperatur 13 1072 (1975)
  36. Young D A, Alder B J Phys. Rev. A 3 364 (1971)
  37. Likal’ter A A Teplofizika Vysokikh Temperatur 23 465 (1985)
  38. Bushman A V, Fortov V E Usp. Fiz. Nauk 140 177 (1983); Bushman A V, Fortov V E Sov. Phys. Usp. 26 465 (1983)
  39. Fortov V E et al Nucl. Instrum. Meth. Phys. Res. A 415 604 (1998)
  40. Bardeen J J. Chem. Phys. 6 367 (1938)
  41. Kuhn T S Phys. Rev. 79 515 (1950)
  42. Kuhn T S, Van Fleck J H Phys. Rev. 79 382 (1950)
  43. Wigner E, Hangtington H J. Chem. Phys. 3 764 (1935)
  44. Kratzer A Z. Phys. 3 289 (1920)
  45. Daw M S, Baskes M I Phys. Rev. B 29 6443 (1984)
  46. Slater J C, Koster G F Phys. Rev. 94 1498 (1954)
  47. Banerjia A, Smith J R Phys. Rev. B 37 6632 (1988)
  48. Rose J H et al Phys. Rev. B 29 2963 (1984)
  49. DeSilva A W, Kunze H-J Phys. Rev. E 49 4448 (1994)
  50. DeSilva A W, Katsouros J D Phys. Rev. E 57 5945 (1998)
  51. Krisch I, Kunze H-J Phys. Rev. E 58 6557 (1998)
  52. DeSilva A W, Katsouros J D J. Physique IV 10 209 (2000)
  53. Clérouin J et al Phys. Rev. B 78 224203 (2008)
  54. Clérouin J et al Phys. Plasmas 19 082702 (2012)
  55. Korobenko V N, Rakhel’ A D Zh. Eksp. Teor. Fiz. 139 746 (2011); Korobenko V N, Rakhel A D J. Exp. Theor. Phys. 112 649 (2011)
  56. Korobenko V N, Rakhel A D Phys. Rev. B 88 134203 (2013)
  57. Kondrat’ev A M, Korobenko V N, Rakhel’ A D Zh. Eksp. Teor. Fiz. 154 1168 (2018); Kondrat’ev A M, Korobenko V N, Rakhel A D J. Exp. Theor. Phys. 127 1074 (2018)
  58. Ternovoi V Ya, Fortov V E, Kvitov S V, Nikolaev D N AIP Conf. Proc. 370 81 (1996)
  59. Emelyanov A N, Nikolaev D N, Ternovoi V Ya High Temp. High Press. 37 279 (2008)
  60. Desjarlais M P, Kress J D, Collins L A Phys. Rev. E 66 025401 (2002)
  61. Mazevet S et al Phys. Rev. E 71 016409 (2005)
  62. French M, Mattsson T R Phys. Rev. B 90 165113 (2014)
  63. Miljacic L et al Calphad 51 133 (2015)
  64. Knyazev D V, Levashov P R Phys. Plasmas 21 073302 (2014)
  65. Minakov D V, Paramonov M A, Levashov P R Phys. Rev. B 97 024205 (2018)
  66. Minakov D V, Paramonov M A, Levashov P R AIP Adv. 8 125012 (2018)
  67. Li D et al Sci. Rep. 4 5898 (2014)
  68. Ding Y H, Hu S X Phys. Plasmas 24 062702 (2017)
  69. Migdal K P et al Appl. Surf. Sci. 478 818 (2019)
  70. Zhang S et al J. Chem. Phys. 146 074505 (2017)
  71. Driver K P et al High Energy Density Phys. 23 81 (2017)
  72. Ovechkin A A, Loboda P A, Falkov A L High Energy Density Phys. 20 38 (2016)
  73. Hou Y et al High Energy Density Phys. 22 21 (2017)
  74. Redmer R Phys. Rev. E 59 1073 (1999)
  75. Kuhlbrodt S, Holst B, Redmer R Contrib. Plasma Phys. 45 73 (2005)
  76. Apfelbaum E M Czech. J. Phys. 56 B618 (2006)
  77. Apfelbaum E M Contrib. Plasma Phys. 56 176 (2016)
  78. Apfelbaum E M Contrib. Plasma Phys. 57 479 (2017)
  79. Fu Z J et al Phys. Scr. 85 045502 (2012)
  80. Norman G E, Starostin A N Teplofizika Vysokikh Temperatur 8 413 (1970); Norman G E, Starostin A N High Temp. 8 381 (1970)
  81. Ebeling W, Norman G E J. Stat. Phys. 110 861 (2003)
  82. Filinov V S et al Contrib. Plasma Phys. 44 388 (2004)
  83. Filinov V S et al Contrib. Plasma Phys. 43 290 (2003)
  84. Mintsev V B, Fortov V E Pis’ma ZhETF 30 401 (1979); Mintsev V B, Fortov V E JETP Lett. 30 375 (1979)
  85. Gatilov L A i dr Prikladnaya Mekhanika Tekhnicheskaya Fizika (1) 99 (1985); Gatilov L A et al J. Appl. Mech. Tech. Phys. 26 88 (1985)
  86. Urlin V D, Mochalov M A, Mikhailova O L High Press. Res. 8 595 (1992)
  87. Glukhodedov V D i dr Zh. Eksp. Teor. Fiz. 116 551 (1999); Glukhodedov V D et al J. Exp. Theor. Phys. 89 292 (1999)
  88. Fortov V E i dr Zh. Eksp. Teor. Fiz. 71 225 (1976); Fortov V E et al Sov. Phys. JETP 44 116 (1976)
  89. Mintsev V B, Fortov V E, Gryaznov V K Zh. Eksp. Teor. Fiz. 79 116 (1980); Mintsev V B, Fortov V E, Gryaznov V K Sov. Phys. JETP 52 59 (1980)
  90. Preising M et al Phys. Plasmas 25 012706 (2018)
  91. Li Z-G et al Phys. Plasmas 23 052701 (2016)
  92. Sun H et al J. Chem. Phys. 144 124503 (2016)
  93. Wang Z-Q et al Phys. Rev. E 100 033214 (2019)
  94. Adams J R et al Phys. Rev. E 76 036405 (2007)
  95. Rosmej S, Reinholz H, Röpke G Phys. Rev. E 95 063208 (2017)
  96. Fu Z J, Chen Q F, Chen X R Contrib. Plasma Phys. 52 251 (2012)
  97. Apfelbaum E M Contrib. Plasma Phys. 51 395 (2011)
  98. Da Silva L B et al Phys. Rev. Lett. 78 483 (1997)
  99. Knudson M D et al Phys. Rev. Lett. 87 225501 (2001)
  100. Holmes N C, Ross M, Nellis W J Phys. Rev. B 52 15835 (1995)
  101. Belov S I i dr Pis’ma ZhETF 76 508 (2002); Belov S I et al JETP Lett. 76 433 (2002)
  102. Weir S T, Mitchell A C, Nellis W J Phys. Rev. Lett. 76 1860 (2002)
  103. Fortov V E, Khrapak A G, Yakubov I T Fizika Neideal’noi Plazmy (M.: Fizmatlit, 2010)
  104. Fortov V E et al Phys. Rev. Lett. 99 185001 (2007)
  105. Redmer R et al J. Phys. Condens. Matter 4 1659 (1992)
  106. Apfelbaum E M Phys. Chem. Liq. 48 534 (2010)
  107. Clementi E, Roetti C Atom. Data Nucl. Data Tabl. 14 177 (1974)
  108. Khomkin A L, Shumikhin A S Zh. Eksp. Teor. Fiz. 150 1020 (2016); Khomkin A L, Shumikhin A S J. Exp. Theor. Fiz. 123 891 (2016)
  109. Puska M J, Nieminen R M Phys. Rev. B 43 12221 (1991)
  110. Yxklinten U, Hartford J, Holmquist T Phys. Scr. 55 499 (1997)
  111. Belashchenko D K Usp. Fiz. Nauk 183 1281 (2013); Belashchenko D K Phys. Usp. 56 1176 (2013)
  112. Regel A R, Ioffe A F Prog. Semicond. 4 237 (1960)
  113. Khomkin A L, Shumikhin A S Zh. Eksp. Teor. Fiz. 151 82 (2017); Khomkin A L, Shumikhin A S J. Exp. Theor. Fiz. 124 70 (2017)
  114. Khomkin A L, Shumikhin A S Zh. Eksp. Teor. Fiz. 145 84 (2014); Khomkin A L, Shumikhin A S J. Exp. Theor. Fiz. 118 72 (2014)
  115. Stishov S M Phys. Rev. B 47 12260 (1993)
  116. Khomkin A L, Shumikhin A S Zh. Eksp. Teor. Fiz. 148 597 (2015); Khomkin A L, Shumikhin A S J. Exp. Theor. Fiz. 121 521 (2015)
  117. Khomkin A L, Shumikhin A S Contrib. Plasma Phys. 56 228 (2016)
  118. Khomkin A L, Shumikhin A S High Temp. High Press. 46 367 (2017)
  119. Khomkin A L, Shumikhin A S High Temp. High Press. 49 143 (2020)
  120. Gathers G R Rep. Prog. Phys. 49 341 (1986)
  121. Seydel U, Fischer U J. Phys. F 8 1397 (1978)
  122. Martynyuk M M Zhurn. Fizicheskoi Khimii 57 810 (1983)
  123. Hixson R S, Winkler M A Int. J. Thermophys. 13 477 (1992)
  124. Pottlacher G, Kaschnitz E, Jager H J. Phys. Condens. Matter 3 5783 (1991)
  125. Keldysh L V Usp. Fiz. Nauk 100 514 (1970); Keldysh L V Sov. Phys. Usp. 13 292 (1970)
  126. Thomas G A, Rice T M, Hencel J C Phys. Rev. Lett. 33 219 (1974)
  127. Ross M Phys. Rev. B 58 669 (1998)
  128. Iosilevskiy I L J. Phys. Conf. Ser. 653 012077 (2015)
  129. Gryaznov V K, Iosilevskiy I L J. Phys. A 42 214007 (2009)
  130. Mulenko I A, Khomkin A L, Shumikhin A S Teplofizika Vysokikh Temperatur 42 835 (2004); Mulenko I A, Khomkin A L, Shumikhin A S High Temp. 42 842 (2004)
  131. Khomkin A L, Shumikhin A S Vestn. OIVT 2 (1) 19 (2019)
  132. Filippov A V, Starostin A N, Gryaznov V K Zh. Eksp. Teor. Fiz. 153 514 (2018); Filippov A V, Starostin A N, Gryaznov V K J. Exp. Theor. Phys. 126 430 (2018)
  133. Khomkin A L, Shumikhin A S Zh. Eksp. Teor. Fiz. 151 1169 (2017); Khomkin A L, Shumikhin A S J. Exp. Theor. Fiz. 124 1001 (2017)
  134. Khomkin A L Teplofizika Vysokikh Temperatur 16 37 (1978)
  135. Khomkin A L, Shumikhin A S Teplofizika Vysokikh Temperatur 50 329 (2012); Khomkin A L, Shumikhin A S High Temp. 50 307 (2012)
  136. Radtsig A A, Smirnov B M Spravochnik Po Atomnoi i Molekulyarnoi Fizike (M.: Atomizdat, 1980); Per. na angl. yaz., Radzig A A, Smirnov B M Reference Data On Atoms, Molecules, And Ions (Springer Series in Chemical Physics) Vol. 31 (Berlin: Springer-Verlag, 1985)
  137. Khomkin A L, Shumikhin A S Fizika Plazmy 44 832 (2018); Khomkin A L, Shumikhin A S Plasma Phys. Rep. 44 958 (2018)
  138. Hirschfelder J O, Curtiss C F, Bird R B (Eds) Molecular Theory Of Gases And Liquids (New York: Wiley, 1954)
  139. Khomkin A L, Shumikhin A S Zh. Eksp. Teor. Fiz. 157 717 (2020); Khomkin A L, Shumikhin A S J. Exp. Theor. Phys. 130 602 (2020)
  140. Kloss A et al Phys. Rev. E 54 5851 (1996)
  141. Onufriev S V Teplofizika Vysokikh Temperatur 49 213 (2011); Onufriev S V High Temp. 49 205 (2011)
  142. Leitner M, Schröer W, Pottlacher G Int. J. Thermophys. 39 124 (2018)
  143. Boboridis K, Pottlacher G, Jäger H Int. J. Thermophys. 20 1289 (1999)
© 1918–2024 Uspekhi Fizicheskikh Nauk
Email: ufn@ufn.ru Editorial office contacts About the journal Terms and conditions