Issues

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2021

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November

  

In memory of Vladimir Evgen'evich Fortov. Reviews of topical problems


Detonation wave of condensation

 ,
Joint Institute for High Temperatures, Russian Academy of Sciences, ul. Izhorskaya 13/19, Moscow, 127412, Russian Federation

In a number of recent studies by the authors, a new physical phenomenon has been discovered and investigated in detail — the formation of a detonation wave during the condensation of highly supersaturated carbon vapor. The essence of the phenomenon is that an initiating shock wave propagating through an exothermic carbon compound (for example, carbon suboxide $C_3O_2$ or acetylene $C_2H_2$), as a result of its rapid dissociation, yields a highly supersaturated carbon vapor; the energy released during its condensation forms and maintains a detonation wave. This review describes in detail the results of experimental studies and their analysis based on the detailed kinetics and thermodynamics of the processes occurring and the one-dimensional Zeldovich—Neumann—Döring (ZND) theory of detonation. The potential to practically use the discovered phenomenon is discussed.

Fulltext pdf (1.2 MB)
Fulltext is also available at DOI: 10.3367/UFNe.2021.02.038936
Keywords: detonation, shock wave, chemical condensation, carbon suboxide, acetylene, carbon, supersaturated vapor, nanoparticles, kinetics, thermodynamics
PACS: 47.40.Rs, 64.70.fm, 82.60.−s (all)
DOI: 10.3367/UFNe.2021.02.038936
URL: https://ufn.ru/en/articles/2021/11/b/
000765556800001
2-s2.0-85125708046
2021PhyU...64.1073E
Citation: Eremin A V, Fortov V E "Detonation wave of condensation" Phys. Usp. 64 1073–1093 (2021)
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Received: 26th, November 2020, revised: 16th, January 2021, 21st, February 2021

Оригинал: Ерёмин А В, Фортов В Е «Детонационная волна конденсации» УФН 191 1131–1152 (2021); DOI: 10.3367/UFNr.2021.02.038936

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