High-energy ball milling of nonstoichiometric compounds

A.I. Gusev
Institute of Solid State Chemistry, Urals Branch of the Russian Academy of Sciences, ul. Pervomayskaya 91, Ekaterinburg, 620219, Russian Federation

The preparation of nanocrystalline powders of nonstoichiometric compounds such as carbides and oxides by high-energy milling is considered. The modern state of milling models for nonstoichiometric compounds is described. The influence of nonstoichiometry on the particle size of the produced nanopowders is discussed. The model dependences of the size of nanopowder particles on the duration of milling and the composition of nonstoichiometric compounds are compared with the literature experimental results on the milling of nonstoichiometric carbides and oxides. Diffraction methods for the certification of nanopowders according to the size of the nanoparticles, the magnitude of microstrains, and the uniformity of the microstructure are considered in detail. The importance of taking into account the anisotropy of microstrains in milled nanopowders is shown.

Keywords: high-energy ball milling, nanopowders, nonstoichiometry, carbides, oxides, nanoparticle size, anisotropy of microstrains, X-ray and neutron diffraction
PACS: 61.46.−w, 61.66.Fn, 61.82.Rx, 81.07.Wx (all)
DOI: 10.3367/UFNe.2019.06.038581
URL: https://ufn.ru/en/articles/2020/4/c/
Web of Science

000555762600003
Scopus

2-s2.0-85091001545
ADS NASA

2020PhyU...63..342G
Citation: Gusev A I "High-energy ball milling of nonstoichiometric compounds" Phys. Usp. 63 342–364 (2020)

BibTexBibNote ® (generic)BibNote ® (RIS)MedlineRefWorks

Received: 25th, March 2019, revised: 13th, June 2019, accepted: 18th, June 2019

Оригинал: Гусев А И «Высокоэнергетический размол нестехиометрических соединений» УФН 190 371–395 (2020); DOI: 10.3367/UFNr.2019.06.038581

References (150) Cited by (9) Similar articles (20) ↓

A.I. Gusev “Nonstoichiometry and superstructures” 57 839–876 (2014)
R.A. Andrievski, A.M. Glezer “Strength of nanostructures” 52 315 (2009)
R.A. Andrievski “High-melting point compounds: new approaches and new results” 60 276–289 (2017)
R.A. Andrievski “Nanostructures under extremes” 57 945–958 (2014)
V.A. Gritsenko “Atomic structure of the amorphous nonstoichiometric silicon oxides and nitrides” 51 699–708 (2008)
A.D. Pogrebnjak, A.P. Shpak et al “Structures and properties of hard and superhard nanocomposite coatings” 52 29–54 (2009)
A.I. Gusev “Order-disorder transformations and phase equilibria in strongly nonstoichiometric compounds” 43 1–37 (2000)
K.V. Larionov, P.B. Sorokin “Investigation of atomically thin films: state of the art” 64 28–47 (2021)
G.N. Makarov “Laser applications in nanotechnology: nanofabrication using laser ablation and laser nanolithography” 56 643–682 (2013)
R.S. Berry, B.M. Smirnov “Phase transitions in various kinds of clusters” 52 137–164 (2009)
A.I. Golovashkin “High-temperature superconducting ceramics (review of experimental results)” 30 659–670 (1987)
V.A. Milichko, A.S. Shalin et al “Solar photovoltaics: current state and trends” 59 727–772 (2016)
M.V. Avdeev, V.L. Aksenov “Small-angle neutron scattering in structure research of magnetic fluids” 53 971–993 (2010)
V.P. Krainov, B.M. Smirnov, M.B. Smirnov “Femtosecond excitation of cluster beams” 50 907–931 (2007)
G.L. Belen’kii, E.Yu. Salaev, R.A. Suleimanov “Deformation effects in layer crystals” 31 434–455 (1988)
A.G. Syromyatnikov, S.V. Kolesnikov et al “Formation and properties of metallic atomic chains and wires” 64 671–701 (2021)
A.D. Pogrebnyak, M.A. Lisovenko et al “Protective coatings with nanoscale multilayer architecture: current state and main trends” 64 253–279 (2021)
G.E. Abrosimova, D.V. Matveev, A.S. Aronin “Nanocrystal formation in homogeneous and heterogeneous amorphous phases” 65 227–244 (2022)
D.V. Kazantsev, E.V. Kuznetsov et al “Apertureless near-field optical microscopy” 60 259–275 (2017)
E.A. Ekimov, M.V. Kondrin “Vacancy-impurity centers in diamond: perspectives of synthesis and applications” 60 539–558 (2017)

The list is formed automatically.