This paper reviews major research into the use of graphene and other multilayer materials in 2D printing technologies for fabricating modern electronics and photonics devices. The paper discusses methods for obtaining suspensions and properties of printed layers, provides examples and parameters of specific printed devices and outlines major trends in the field. Special emphasis is placed on the conceptual change in graphene suspension fabrication from using organic liquids to using water-based solution for stratifying graphite and fabricating liquid ink. The paper also considers the trend towards the use of increasingly graphene-rich ink, an approach whereby highly conductive printed layers can be obtained. The expansion of the range of used materials is also discussed.