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Inductive-resonant mechanism of nonradiative transitions in ions and molecules in condensed phase

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S I Vavilov State Optical Institute, Birzhevaya liniya 12, St. Petersburg, 199034, Russian Federation

The inductive-resonant mechanism of nonradiative transitions between electronic levels in lanthanide and transition metal ions and complex molecules in the condensed phase is systematically described. A quantum-mechanical justification is presented, and theoretical expectations conforming to the mechanisms and quantitative rate constants of nonradiative transitions are compared with experiment.

Fulltext is available at IOP
PACS: 33.90.+h, 34.30.+h (all)
DOI: 10.1070/PU1996v039n03ABEH000137
URL: https://ufn.ru/en/articles/1996/3/c/
Citation: Ermolaev V L, Sveshnikova E B, Bodunov E N "Inductive-resonant mechanism of nonradiative transitions in ions and molecules in condensed phase" Phys. Usp. 39 261–282 (1996)
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Оригинал: Ермолаев В Л, Свешникова Е Б, Бодунов Е Н «Индуктивно-резонансный механизм безызлучательных переходов в ионах и молекулах в конденсированной фазе» УФН 166 279–302 (1996); DOI: 10.3367/UFNr.0166.199603c.0279

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