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Inductive-resonant mechanism of nonradiative transitions in ions and molecules in condensed phase

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S I Vavilov State Optical Institute, Birzhevaya liniya 12, St. Petersburg, 199034, Russian Federation

The inductive-resonant mechanism of nonradiative transitions between electronic levels in lanthanide and transition metal ions and complex molecules in the condensed phase is systematically described. A quantum-mechanical justification is presented, and theoretical expectations conforming to the mechanisms and quantitative rate constants of nonradiative transitions are compared with experiment.

Text can be downloaded in Russian. English translation is available on IOP Science.
PACS: 33.90.+h, 34.30.+h (all)
DOI: 10.1070/PU1996v039n03ABEH000137
URL: https://ufn.ru/en/articles/1996/3/c/
Citation: Ermolaev V L, Sveshnikova E B, Bodunov E N "Inductive-resonant mechanism of nonradiative transitions in ions and molecules in condensed phase" Phys. Usp. 39 261–282 (1996)
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Оригинал: Ермолаев В Л, Свешникова Е Б, Бодунов Е Н «Индуктивно-резонансный механизм безызлучательных переходов в ионах и молекулах в конденсированной фазе» УФН 166 279–302 (1996); DOI: 10.3367/UFNr.0166.199603c.0279

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