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’Jarring’ of a quantum system and the corresponding stimulated transitionsA systematic theory of sudden perturbations is derived for quantum systems whose states are described both by wave functions (a pure ensemble) and by a quantum density operator (a mixed ensemble). A perturbation series is written in powers of the parameter ωτωτ, which is small when the perturbation is ``sudden''; ℏωℏω is the typical eigenvalue of the unperturbed system; and ττ is the characteristic collision time. When the perturbation V(t)V(t), taken at different times, commutes with itself, the theory yields a compact analytic expression for the probabilities for stimulated transitions for any value of V(t)/ℏV(t)/ℏ. The results of many cross-section calculations for atomic collision processes are discussed from a common standpoint: the processes are treated as ``jarring'' processes which stimulate transitions in the quantum system. If a momentum δpδp is rapidly transferred to the system in a collision, regardless of the physical nature of the ``jarring'', the probabilities for the stimulated transitions are governed by the parameter N∼δp⋅δR/ℏN∼δp⋅δR/ℏ where δRδR is a measure of the uncertainty in the coordinates which is due to the relatively slow motions in the unperturbed system.
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