Issues

 / 

1974

 / 

January

  

Methodological notes


Effects of the internal field in the spectra of molecular crystals and the theory of excitons


Institute of Spectroscopy, Russian Academy of Sciences, ul. Fizicheskaya 5, Troitsk, Moscow, 108840, Russian Federation

It is shown that a very large set of optical properties of molecular crystals (pure crystals, crystals containing impurities, and crystalline solutions) in the region of the lowest singlet electronic (or vibrational) excited states, where the mutual interaction of the molecules does not violate their neutrality, can be treated without bringing in exciton concepts, but by generalizing to anisotropic media the methods of molecular optics that had been developed before Frenkel's ideas on the exciton had appeared. This treatment is based on using the method of the acting field, which goes back to Lorentz, and also on the results of Born and Ewald \emph{et al.}, which permit one to calculate the electric field acting on some particular molecule in the crystal, and in particular, with account taken of the higher multipoles of the polarizability of the molecules. It is shown that this approach permits one to calculate the dielectric constant of the crystal with account taken of spatial dispersion, to treat the polarization and splitting of light-absorption bands in crystals, and polarization of impurity absorption bands, as well as an entire series of other problems that were previously studied in less general form only within the framework of the Frenkel exciton theory. The limits of applicability of the presented approach are also discussed.

Fulltext pdf (764 KB)
Fulltext is also available at DOI: 10.1070/PU1974v017n01ABEH004319
PACS: 71.35.Aa, 78.20.Ci, 77.22.Ch (all)
DOI: 10.1070/PU1974v017n01ABEH004319
URL: https://ufn.ru/en/articles/1974/1/f/
Citation: Agranovich V M "Effects of the internal field in the spectra of molecular crystals and the theory of excitons" Sov. Phys. Usp. 17 103–117 (1974)
BibTexBibNote ® (generic)BibNote ® (RIS)MedlineRefWorks

Оригинал: Агранович В М «Эффекты внутреннего поля в спектрах молекулярных кристаллов и теория экситонов» УФН 112 143–171 (1974); DOI: 10.3367/UFNr.0112.197401e.0143

Cited by (38) Similar articles (20) ↓

  1. D.A. Kirzhnits “Are the Kramers-Kronig relations for the dielectric permittivity of a material always valid?Sov. Phys. Usp. 19 530–537 (1976)
  2. V.G. Veselago “Formulating Fermat’s principle for light traveling in negative refraction materialsPhys. Usp. 45 1097–1099 (2002)
  3. K.Yu. Bliokh, Yu.P. Bliokh “What are the left-handed media and what is interesting about them?Phys. Usp. 47 393–400 (2004)
  4. V.L. Ginzburg “The laws of conservation of energy and momentum in emission of electromagnetic waves (photons) in a medium and the energy-momentum tensor in macroscopic electrodynamicsSov. Phys. Usp. 16 434–439 (1973)
  5. V.V. Shevchenko “Forward and backward waves: three definitions and their interrelation and applicabilityPhys. Usp. 50 287–292 (2007)
  6. E.H. Lock “The properties of isofrequency dependences and the laws of geometrical opticsPhys. Usp. 51 375–393 (2008)
  7. A.P. Vinogradov, A.V. Dorofeenko, S. Zouhdi “On the problem of the effective parameters of metamaterialsPhys. Usp. 51 485–492 (2008)
  8. V.L. Ginzburg “Line width in the spectrum of scattered lightSov. Phys. Usp. 15 114–120 (1972)
  9. V.L. Ginzburg, V.A. Ugarov “Remarks on forces and the energy-momentum tensor in macroscopic electrodynamicsSov. Phys. Usp. 19 94–101 (1976)
  10. A.M. Ignatov, A.A. Rukhadze “Ambiguity in the definition of the magnetic permeability of material mediaSov. Phys. Usp. 24 795–797 (1981)
  11. A.M. Dykhne, G.L. Yudin “Stimulated effects upon ’jarring’ of an electron in an external electromagnetic fieldSov. Phys. Usp. 20 80–86 (1977)
  12. A.A. Andronov, Yu.A. Ryzhov “An infinity of the classical theory of fluctuations in a nondegenerate electron gasSov. Phys. Usp. 21 873–878 (1978)
  13. B.M. Bolotovskii, V.A. Davydov, V.E. Rok “The emission of electromagnetic waves in the case of a smooth variation of parameters of a radiating systemSov. Phys. Usp. 25 167–175 (1982)
  14. V.L. Lyuboshits, M.I. Podgoretskii “The Archimedes force acting on individual molecules of matter in an external fieldSov. Phys. Usp. 34 (11) 997–1007 (1991)
  15. V.N. Tsytovich “Collective effects of plasma particles in bremsstrahlungPhys. Usp. 38 87–108 (1995)
  16. V.F. Khirnyi, A.A. Kozlovskii “Nonlinear effects and domain instability in oxide ceramicsPhys. Usp. 46 657–663 (2003)
  17. A.I. Musienko, L.I. Manevich “Classical mechanical analogs of relativistic effectsPhys. Usp. 47 797–820 (2004)
  18. L.A. Maksimov, T.V. Khabarova “Properties of acoustic polarization vectors in crystals and the phonon Hall effectPhys. Usp. 53 481–485 (2010)
  19. M.V. Kuzelev, A.A. Rukhadze “Nonrelativistic quantum theory of stimulated Cherenkov radiation and Compton scattering in a plasmaPhys. Usp. 54 375–380 (2011)
  20. M.Ya. Agre “Multipole expansions in magnetostaticsPhys. Usp. 54 167–180 (2011)

The list is formed automatically.

© 1918–2024 Uspekhi Fizicheskikh Nauk
Email: ufn@ufn.ru Editorial office contacts About the journal Terms and conditions