|
Structure of metallofullerenes
1 March 2003
One interesting property of fullerenes is that they can contain
atoms of elements within them. In recent years, the dimetallofullerenes Sc2C84 with two atoms of scandium have
received the attention of researchers. According to theoretical calculations, which have been confirmed by nuclear
magnetic resonance studies, Sc2C84 molecules have three
isomers, in one of which scandium atoms are situated nonsymmetrically around the centre of the molecule. Until
recently, no experimental data on the structure of nonsymmetric isomers were available. Now, using an original
technique, K. Suenaga and his colleagues, all in Japan, have
for the first time investigated the structure of individual
Sc2C84 molecules and, in particular, studied an isomer
with a non-symmetric arrangement of scandium atoms. The
researchers placed carbon nanotubes in a gaseous fullerene
medium at high temperature, as a result of which metallofullerene molecules filled the tubes. The metallofullerenes within
the tubes were in a steady state and therefore convenient for
study with a high resolution transmission electron microscope.
Moreover, carbon nanotubes are highly transparent to
electrons and do not distort the image. The new method made
it possible to observe individual scandium atoms within
fullerene molecules.
Source: Phys. Rev. Lett. 90 055506 (2003)
Molecular switch
1 March 2003
A team of researchers from Switzerland and France directly
measured the energy needed for an organic molecule to make
an intramolecular conformational transition from one stable
position to another. Under high vacuum conditions, one part
of an organic molecule was rotated about the carbon C-C
bond with respect to the other part in a contactless fashion
using the tip of an atomic force microscope. The energy
required to `switch' the molecule was found to be
47x10-21 J, four orders of magnitude less than when
triggers based on computer chip field transistors are used.
Source: Phys. Rev. Lett. 90 066107 (2003)
Nanowire laser
1 March 2003
C. Lieber and his colleagues at Harvard University have for the
first time demonstrated an electrically pumped nanowire
laser. Unlike electrically pumped semiconductor lasers, the
new laser consists of a long cadmium-sulphide single crystal
80-200 nm in diameter. Such structures are called nanowires.
Laser radiation is generated when the current flowing through
the nanowire exceeds 200 mA. The new laser may have
practical applications even though its lasing mechanism is
not yet well understood.
Source: Science 299 531 (2003)
Testing Lorentz invariance
1 March 2003
Experimental tests of Lorentz invariance (see, for example,
Physics Uspekhi 45 220 (2002)) have
placed limits on the quantities characterizing the possible
anisotropy of the speed of light and on the way the speed of
light depends on the observer's velocity. However, there are
parameters involved in some Lorentz violating extensions of
the Standard Model of elementary particles for which no
clear-cut limits could be provided by these tests, V.A. Kostelecky and N. Mewes showed in 2002. J.A. Lipa and his
colleagues at Stanford University now have conducted a
new experiment and obtained limits on some of these
parameters. The experiment involved two microwave cav-
ities made of niobium, which were cooled to 1.5K. One of the
cavities was aligned along the Earth's radius and the other in
the east-west direction. The authors examined the beating of
the electromagnetic waves in the cavities for a number of
periods of the Earth's diurnal rotation. No Lorentz violation
was observed. It was found that 4 linear combinations of
unknown theoretical parameters did not exceed 10-13 and
that 4 other combinations did not exceed 4x10-13. A similar
but even more precise space-based experiment is currently
being planned.
Source: Phys. Rev. Lett. 90 060403 (2003)
The number of baryons in the Universe
1 March 2003
A team of astronomers from the USA and Italy have used the
UV detector onboard the FUSE satellite and the space-based
XMM-Newton and Chandra X-ray telescopes to detect
clouds of baryonic gas in the Local group of galaxies (a
system which includes our Galaxy, the Andromeda Nebula,
and dozens of dwarf galaxies). According to Big Bang
nucleosynthesis theory, baryons account for about 4% of
the density of the Universe. However, the observable stars,
gas, and dust thus far have provided only one-third of this
amount. The newly discovered clouds may contain the
missing two-thirds, their total mass in the Local group being
approximately 1012 solar masses. This (combined with the
mass of dark matter) is enough for the Local group to be a
gravitationally bound system. Earlier, the high temperature
and low density of the baryon clouds prevented their
detection. F. Nicastro and his colleagues detected the clouds
by taking advantage of the fact that ultraviolet radiation from
galactic cores is absorbed by oxygen ions present in a gas. By
using the Doppler effect, the radial velocities of the clouds
were found not to exceed 100 km/s, suggesting that the clouds
belong to the Local group rather than being peripheral
objects of our Galaxy.
Source: Nature 421 719 (2003)
|
The Extracts from the Internet is a section of Uspekhi Fizicheskih Nauk (Physics Uspekhi) the monthly rewiew journal of the current state of the most topical problems in physics and in associated fields. The presented News is devoted to the fundamental discoveries of physics and astrophysics. Permanent editor is Yu.N. Eroshenko. It is compiled from a multitude of Internet sources.
|