NMR in Van Vleck magnetics and intermolecular interactions in molecular crystals and Chevrel phases

S.R. Gabuda^a, S.G. Kozlova^a, A.G. Lundin^b
^aA.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, prosp. akad. Lavrenteva 3, Novosibirsk, 630090, Russian Federation
^bSiberian State Technological University, prosp. Mira 82, Krasnoyarsk, 660049, Russian Federation

Aspects of orbital paramagnetism and intermolecular interactions are discussed in relation to compounds containing octahedral MF₆ molecules (where M ia a transition metal) and Chevrel phase cuboctahedron systems M₆X₉. The 100th anniversary of the birth of Professor S A Altshuler, a pioneer in the use of NMR for studying Van Vleck magnetism, is a motivation for this review.

Text can be downloaded in Russian. English translation is available on IOP Science.

PACS: 31.15.E−, 75.20.−g, 82.56.−b (all)
DOI: 10.3367/UFNe.0181.201105d.0521
URL: https://ufn.ru/en/articles/2011/5/d/
Citation: Gabuda S R, Kozlova S G, Lundin A G "NMR in Van Vleck magnetics and intermolecular interactions in molecular crystals and Chevrel phases" Phys. Usp. 54 499–517 (2011)

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Received: 31st, May 2010, revised: 20th, February 2011, accepted: 11th, February 2011

Оригинал: Габуда С П, Козлова С Г, Лундин А Г «Ядерный магнитный резонанс в ван-флековских магнетиках и межмолекулярные взаимодействия в молекулярных кристаллах и фазах Шеврёля» УФН 181 521–541 (2011); DOI: 10.3367/UFNr.0181.201105d.0521