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NMR in Van Vleck magnetics and intermolecular interactions in molecular crystals and Chevrel phasesa A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, prosp. akad. Lavrenteva 3, Novosibirsk, 630090, Russian Federation b Siberian State Technological University, prosp. Mira 82, Krasnoyarsk, 660049, Russian Federation Aspects of orbital paramagnetism and intermolecular interactions are discussed in relation to compounds containing octahedral MF6 molecules (where M ia a transition metal) and Chevrel phase cuboctahedron systems M6X9. The 100th anniversary of the birth of Professor S A Altshuler, a pioneer in the use of NMR for studying Van Vleck magnetism, is a motivation for this review.
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