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Two-dimensional ferroelectrics

 a,  a,  a,  b,  b,  b
a Shubnikov Institute of Crystallography, Russian Academy of Sciences, Leninskii prosp. 59, Moscow, 119333, Russian Federaion
b Department of Physics and Astronomy, Behlen Laboratory of Physics, Center for Materials Research and Analysis, University of Nebraska-Linkoln, Linkoln, NE, USA

The investigation of the finite-size effect in ferroelectric crystals and films has been limited by the experimental conditions. The smallest demonstrated ferroelectric crystals had a diameter of ~200 Å and the thinnest ferroelectric films were ~200 Å thick, macroscopic sizes on an atomic scale. Langmuir-Blodgett deposition of films one monolayer at a time has produced high quality ferroelectric films as thin as 10 Å, made from polyvinylidene fluoride and its copolymers. These ultrathin films permitted the ultimate investigation of finite-size effects on the atomic thickness scale. Langmuir-Blodgett films also revealed the fundamental two-dimensional character of ferroelectricity in these materials by demonstrating that there is no so-called critical thickness; films as thin as two monolayers (1 nm) are ferroelectric, with a transition temperature near that of the bulk material. The films exhibit all the main properties of ferroelectricity with a first-order ferroelectric-paraelectric phase transition: polarization hysteresis (switching); the jump in spontaneous polarization at the phase transition temperature; thermal hysteresis in the polarization; the increase in the transition temperature with applied field; double hysteresis above the phase transition temperature; and the existence of the ferroelectric critical point. The films also exhibit a new phase transition associated with the two-dimensional layers.

Fulltext is available at IOP
PACS: 75.70.−i, 77.80.−e (all)
DOI: 10.1070/PU2000v043n03ABEH000639
URL: https://ufn.ru/en/articles/2000/3/b/
Citation: Blinov L M, Fridkin V M, Palto S P, Bune A V, Dowben P A, Ducharme S "Two-dimensional ferroelectrics" Phys. Usp. 43 243–257 (2000)
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Оригинал: Блинов Л М, Фридкин В М, Палто С П, Буне А В, Даубен П А, Дюшарм С «Двумерные сегнетоэлектрики» УФН 170 247–262 (2000); DOI: 10.3367/UFNr.0170.200003b.0247

References (97) ↓ Cited by (159) Similar articles (20)

  1. Dürr W et al. Phys. Rev. Lett. 62 206 (1989)
  2. Farle M, Baberschke K Phys. Rev. Lett. 58 511 (1987)
  3. Mermin N D, Wagner H Phys. Rev. Lett. 17 1133 (1966)
  4. Dowben P A, McIlroy D N, Li D, in Handbook on the Physics and Chemistry of Rare Earths Vol. 24 (Eds J K A Gschneidner, L Eyring, Amsterdam: Elsevier, 1997) Ch. 159
  5. Ishikawa K, Yoshikawa K, Okada N Phys. Rev. B 37 5852 (1988)
  6. Tanaka M, Makino Y Ferroelectrics Lett. 24 13 (1998)
  7. Kimura K, Ohigashi H Jpn. J. Appl. Phys. 25 383 (1986)
  8. Scott J F Phase Transitions 30 107 (1991)
  9. Tilley D R, in Ferroelectric Thin Films: Synthesis and Basic Properties (Eds C Paz de Araujo, J F Scott, G F Taylor, Amsterdam: Gordon and Breach, 1996) p. 11
  10. Scott J F Physica B 150 160 (1988)
  11. Onsager L Phys. Rev. 65 117 (1944)
  12. Valasek J Phys. Rev. 15 537 (1920)
  13. Devonshire A F Adv. Phys. 3 85 (1954)
  14. Lines M E, Glass A M Principles and Applications of Ferroelectrics and Related Materials (Oxford: Clarendon, 1977)
  15. Fridkin V M Ferroelectric Semiconductors (New York: Consultants Bureau, 1980)
  16. Valasek J Phys. Rev. 17 475 (1921)
  17. Blinc R, Zeks B Soft Modes in Ferroelectrics and Antiferroelectrics (Amsterdam: North-Holland, 1974)
  18. Xu Y Ferroelectric Materials and Their Applications (Amsterdam: North-Holland, 1991)
  19. Strukov B A, Levanyuk A P Ferroelectric Phenomena in Crystals (Berlin: Springer-Verlag, 1998)
  20. Ginzburg V L Zh. Eksp. Teor. Fiz. 15 739 (1945) [J. Phys. USSR 10 107 (1946)]
  21. Ginzburg V L Zh. Eksp. Teor. Fiz. 19 36 (1949)
  22. Landau L D, Lifshitz E M Statistical Physics Part I (Oxford: Pergamon, 1980)
  23. Landau L D Zh. Eksp. Teor. Fiz. 7 627 (1937); Phys. Z. Sowjetunion 11 545 (1937)
  24. Landau L D Phys. Z. Sowjetunion 11 545 (1937)
  25. Devonshire A F Philos. Mag. 40 1040 (1949)
  26. Devonshire A F Philos. Mag. 42 1065 (1951)
  27. Gerzanich E I, Fridkin V M Pis’ma Zh. Eksp. Teor. Fiz. 8 553 (1968) [JETP Lett. 8 337 (1968)]
  28. Strukov B A, Amin M, Kopchik V A Phys. Status Solidi 27 741 (1968)
  29. Keve E T et al. Commun. Solid State Phys. 8 1517 (1970)
  30. Bahr C, Heppke G Phys. Rev. A 39 5459 (1989)
  31. Cottam M G, Tilley D R, Zeks B J. Phys. C 17 1793 (1984)
  32. Tilley D R Phase Transitions in Thin Films in Ferroelectric Ceramics (Basel: Birkhäuser, 1993)
  33. Duiker H M "Static and dynamic properties of ferroelectric thin film memories" PhD Thesis (University of Colorado, 1989)
  34. Qu B D et al. Ferroelectrics 152 219 (1994)
  35. Scott J F et al. Phys. Rev. B 35 4144 (1987)
  36. Wang C L, Zhong W L, Zhang P L J. Phys.: Condens. Matter 3 4743 (1992)
  37. Li S et al. Phys. Lett. A 212 341 (1996)
  38. Li S et al. Philos. Mag. B 76 47 (1997)
  39. DeGennes P G Solid State Commun. 1 132 (1963)
  40. Furukawa T Ferroelectrics 57 63 (1984)
  41. Furukawa T Phase Transitions 18 143 (1989)
  42. Lovinger A J Science 220 1115 (1983)
  43. Lovinger A J, in Developments in Crystalline Polymers Vol. 1 (Ed. D C Basset, London: Elsevier Applied Science, 1982)
  44. Wang T T, Herbert J M, Glass A M The Applications of Ferroelectric Polymers (New York: Chapman and Hall, 1988)
  45. Nalwa H S Ferroelectric Polymers (New York: Marcel Dekker, 1995)
  46. Sessler G M (Ed.) Electrets (Berlin: Springer-Verlag, 1980)
  47. Furukawa T, Date M, Fukada E Ferroelectrics 57 63 (1980)
  48. Yagi T, Tatemoto M, Sako J Polymer J. 12 209 (1980)
  49. Lovinger A J Macromolecules 16 1529 (1983)
  50. Verkhovskaya K A, Danz R, Fridkin V M Fiz. Tverd. Tela 29 2198 (1987) [Sov. J. Solid State 29 1268 (1987)]
  51. Berry M H, Gookin D N, in Nonlinear Optical Properties of Organic Materials (Proc. SPIE, Vol. 971, Ed. G Khanarian, Bellingham, Wash.: SPIE, 1988) p. 154
  52. Bergman J G, McFee J H, Crane G R Appl. Phys. Lett. 18 203 (1971)
  53. Verkhovskaya K A et al. Ferroelectrics 134 7 (1992)
  54. Litt M H, Hsu C, Basu P J. Appl. Phys. 48 2208 (1977)
  55. Esayan S, Scheinbeim J I, Newman B A Appl. Phys. Lett. 67 623 (1995)
  56. Hachiya S J. Soc. Inform. Disp. 1 295 (1993)
  57. Fernandez M V, Suzuki A, Chiba A Macromolecules 20 1806 (1987)
  58. Tashiro K, Takano K, Kobayashi M Ferroelectrics 57 297 (1984)
  59. Palto S et al. Ferroelectrics Lett. 19 65 (1995)
  60. Bune A et al. Appl. Phys. Lett. 67 3975 (1995)
  61. Blinov L M Usp. Fiz. Nauk 155 443 (1988) [Sov. Phys. Usp. 31 623 (1988)]
  62. Roberts G G Langmuir-Blodgett Films (New York: Plenum, 1990)
  63. Petty M C Langmuir-Blodgett Films: An Introduction (Cambridge: Cambridge University Press, 1996)
  64. Ducharme S et al. Ferroelectrics 202 29 (1997)
  65. Advincula R C et al., in Organic Thin Films: Structure and Applications (ACS Symposium Series, Vol. 695, Ed. C W Frank, Washington, DC: American Chemical Society, 1998) p. 192
  66. Sorokin A V "Langmuir-Blodgett deposition of ferroelectric polymer films" PhD Thesis (Moscow: Institute of Crystallography, 1997)
  67. Palto S et al. Europhys. Lett. 34 465 (1996)
  68. Bune A et al. Nature (London) 391 874 (1998)
  69. Choi J et al. Phys. Lett. A 249 505 (1999)
  70. Borca C N et al. Appl. Phys. Lett. 74 347 (1999)
  71. Choi J et al. Phys. Rev. B 61 5760 (2000)
  72. Ducharme S et al. Phys. Rev. B 57 25 (1998)
  73. Legrand J F Ferroelectrics 91 303 (1989)
  74. Blinov L M et al. Thin Solid Films 284-285 474 (1996)
  75. Sorokin A V et al. Mol. Mater. 6 61 (1996)
  76. Bune A V et al. J. Appl. Phys. 85 7869 (1999)
  77. Merz W J Phys. Rev. 91 513 (1953)
  78. Okada K, Sugie H Phys. Lett. A 37 337 (1971)
  79. Gladkiî V V, Sidnenko E V Fiz. Tverd. Tela 13 3092 (1971) [Sov. J. Solid State 13 2592 (1971)]
  80. Kawai H Jpn. J. Appl. Phys. 8 975 (1969)
  81. Tashiro K et al. Macromol. 13 691 (1980)
  82. Fukada E Phase Transitions 18 135 (1989)
  83. Furukawa T, Seo N Jpn. J. Appl. Phys. 24 675 (1990)
  84. Nye P Physical Properties of Crystals (London: Oxford Press, 1967)
  85. Fowler R H, Nordheim L Proc. R. Soc. London. Ser. A 119 173 (1928)
  86. Isono Y, Nakano H J. Appl. Phys. 75 4557 (1994)
  87. Wang C L et al. Phys. Lett. A 254 297 (1999)
  88. Furukawa T et al. Jpn. J. Appl. Phys. 24 L661 (1985)
  89. Allenspach R, Bishof A Phys. Rev. Lett. 69 3385 (1992)
  90. Ducharme S et al. Phys. Rev. Lett. 84 175 (2000)
  91. Tagantsev A K Integr. Ferroelectrics 16 237 (1997)
  92. Tagantsev A K Ferroelectrics 184 79 (1996)
  93. Kevan S D, Stoffel N G Phys. Rev. Lett. 53 702 (1984)
  94. Kevan S D Phys. Rev. B 32 2344 (1985)
  95. Choi J et al. Phys. Rev. Lett. 80 1328 (1998)
  96. Choi J et al. Phys. Rev. B 59 1819 (1998)
  97. Kohler R et al. J. Korean Phys. Soc. 32 1744 (1998)

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