RSS feeds
РусскийEnglish
Issue 4, 2024
Volume year page
Issues Authors PACS Subscription For authors

Issues

 / 

1999

 / 

February

←  →

Reviews of topical problems


Statistical physics of the solvated electron


Department of Quantum-Chemical Systems, Institute of Mathematical Problems of Biology, Russian Academy of Sciences, Pushchino, Moscow Region, Russian Federation

Statistical models of an electron solvated in a classical liquid are reviewed. The analogy between the behaviour of a quantum particle and a polymer chain results in that statistical physics methods can be applied to the solvated electron problem. We have derived basic relations for thermodynamic and structural characteristics of the solvated electron. The free energy of the solvated electron and the effective electron-solvent potential as well as the electron-solvent correlation function are studied in detail. The calculated results are compared with experimental data and a quantum molecular dynamics simulation for simple, polar, and Coulomb liquids. We also outline many-particle quantum effects, such as electron-electron interactions and dielectron (bipolaron) formation. The potentialities and restrictions of the statistical method are also discussed.

Fulltext pdf (366 KB)
Fulltext is also available at DOI: 10.1070/pu1999v042n02ABEH000520
PACS: 05.90.+m, 71.38.+i, 71.23.An (all)
DOI: 10.1070/pu1999v042n02ABEH000520
URL: https://ufn.ru/en/articles/1999/2/b/
000079341200002
Citation: Chuev G N "Statistical physics of the solvated electron" Phys. Usp. 42 149 (1999)
BibTexBibNote ® (generic)BibNote ® (RIS)MedlineRefWorks

Оригинал: Чуев Г Н «Статистическая физика сольватированного электрона» УФН 169 155–170 (1999); DOI: 10.3367/UFNr.0169.199902b.0155

References (128) ↓ Cited by (5) Similar articles (20)

  1. Jortner J, Kestner N R (Eds) Electrons in Fluids (Berlin: Springer-Verlag, 1973)
  2. Kevan L, Webster B C (Eds) Electron - Solvent and Anion - Solvent Interactions (Amsterdam: Elsevier, 1976)
  3. Kevan L, Feng D F Chem. Rev. 80 1 (1980)
  4. Itskovitch E M, Kuznetsov A M, Ulstrup J, in The Chemical Physics of Solvation (Eds R R Dogonadze et al., Amsterdam: Elsevier, 1988)
  5. Ferradini C, Jay-Gerin J-P (Eds) Excess Electrons in Dielectric Media (Boca Raton: CRC Press, 1991)
  6. Pikaev A K The Solvated Electron in Radiation Chemistry (Jerusalem: World Univ., 1970)
  7. Hart E J, Anbar M The Hydrated Electron (New York: Wiley-Interscience, 1970) [Translated into Russian (Moscow: Atomizdat, 1973)]
  8. Tompson J C Electrons in Liquid Ammonia (Oxford: Clarendon Press, 1976) [Translated into Russian (Moscow: Mir, 1979)]
  9. Pikaev A K Sovremennaya Radiatsionnaya Khimiya: Radioliz Gazov i Zhidkosteî (Contemporary Radiation Chemistry: Radiolysis of Gases and Liquids, Moscow: Nauka, 1986)
  10. Pikaev A K Sovremennaya Radiatsionnaya Khimiya: Tverdoe Telo i Polimery. Prikladnye Aspekty (Contemporary Radiation Chemistry: Solids and Polymers, Moscow: Nauka, 1987)
  11. Khrapak A G, Yakubov I T Elektrony v Plotnykh Gazakh i Plazme (Electrons in Dense Gases and Plasma, Moscow: Nauka, 1981)
  12. The Study of Fast Processes and Transient Species by Electron Pulse Radiolysis (NATO Advanced Study Institute Series, Ser. C, Vol. 86; Eds J H Baxendale, F Busi, Dordrecht: D Reidel Publ. Co., 1982)
  13. Farhataziz R M A, Rodgers M A J (Eds) Radiation Chemistry: Principles and Applications (New York: VCH Publ., 1987)
  14. Careri G, Fasoli U, Gaeta F S Nuovo Cimento 15 774 (1960)
  15. Springett B E, Jortner J, Cohen M H J. Chem. Phys. 48 2720 (1968)
  16. Shikin V B, Monarkha Yu P Dvumernye Zaryazhennye Sistemy v Gelii (Two-Dimensional Charged Systems in Helium, Moscow: Nauka, 1989)
  17. Golden S, Tuttle T R, Jr. J. Chem. Soc. Faraday Trans. 2 78, 1581 (1982)
  18. Petrucci S J. Mol. Liquids 54 173 (1992)
  19. Schnitker J, Rossky P J J. Phys. Chem. 93 6965 (1989)
  20. Chandler D, Wolynes P G J. Chem. Phys. 74 4078 (1981)
  21. Berne B J, Gallicchio E Absorption Spectrum of an Excess Electron in Water, in http://www.mhpcc.edu/research/ss95/ssp03.html
  22. Parrinello M, Rahman A J. Chem. Phys. 80 860 (1984)
  23. Bartholomew J, Hall R, Berne B J Phys. Rev. B 32 548 (1985)
  24. Berne B J, Thirumalai D Ann. Rev. Phys. Chem. 37 401 (1986)
  25. Wallqvist A, Thirumalai D, Berne B J J. Chem. Phys. 85 1583 (1986)
  26. Sprik M, Impey R W, Klein M L J. Stat. Phys. 43 967 (1986)
  27. Schnitker J, Rossky P J J. Chem. Phys. 86 3471 (1987)
  28. Marchi M, Sprik M, Klein M L Faraday Discuss. Chem. Soc. 85 373 (1988)
  29. Barnett R N et al. J. Chem. Phys. 89 382 (1989)
  30. Zhu J, Cukier R I J. Chem. Phys. 98 5679 (1993)
  31. Coker F, Berne B J, Thirumalai D J. Chem. Phys. 86 5689 (1994)
  32. Chandler D Studies in Statistical Mechanics VIII (Eds E W Montroll, J L Lebowitz, Amsterdam: North-Holland, 1982)
  33. Chandler D, Singh Y, Richardson D M J. Chem. Phys. 81 1975 (1984)
  34. Nichols III A L et al. J. Chem. Phys. 81 5109 (1984)
  35. Nichols III A L, Chandler D J. Chem. Phys. 84 398 (1986)
  36. Nichols III A L, Chandler D J. Chem. Phys. 87 6671 (1987)
  37. Laria D, Chandler D J. Chem. Phys. 87 4088 (1987)
  38. Hsu D, Chandler D J. Chem. Phys. 93 5075 (1990)
  39. Laria D, Wu D, Chandler D J. Chem. Phys. 95 4444 (1991)
  40. Chandler D, Leung K Ann. Rev. Phys. Chem. 45 1500 (1994)
  41. Leung K, Chandler D Phys. Rev. E 49 2851 (1994)
  42. Sethia A, Singh Y Phys. Rev. B 42 6090 (1990)
  43. Sethia A, Singh Y Phys. Rev. B 46 9958 (1992)
  44. Malescio G, Parrinello M Phys. Rev. A 35 897 (1987)
  45. Malescio G Phys. Rev. A 36 5847 (1987)
  46. Malescio G Mol. Phys. 69 895 (1990)
  47. Malescio G Nuovo Cimento D 13 1031 (1991)
  48. Shaw M R, Thirumalai D J. Chem. Phys. 93 3450 (1990)
  49. Zhu J, Cukier R I J. Chem. Phys. 99 1288 (1993)
  50. Zhu J, Cukier R I J. Chem. Phys. 99 5384 (1993)
  51. Miura S, Hirata F J. Phys. Chem. 98 9649 (1994)
  52. Chuev G N Zh. Eksp. Teor. Fiz. 105 626 (1994) [JETP 78 334 (1994)]
  53. Chuev G N Perspectives in Polarons (Eds G N Chuev, V D Lakhno, Singapore: World Scientific, 1997)
  54. Chuev G N Zh. Fiz. Khim. 69 1375 (1995)
  55. Chuev G N Izv. Ross. Akad. Nauk Ser. Fiz. 59 (8) 95 (1995)
  56. Chuev G N Physica D 83 68 (1995)
  57. Chuev G N Izv. Ross. Akad. Nauk Ser. Fiz. 60 (9) 2 (1996)
  58. Chuev G N Izv. Ross. Akad. Nauk Ser. Fiz. 61 (9) 1770 (1997)
  59. Wiegel F W Introduction to Path-Integral Methods in Physics and Polymer Science (Singapore: World Scientific, 1986)
  60. Grosberg A Yu, Khokhlov A R Statisticheskaya Fizika Makromolekul (Statistical Physics of Macromolecules, Moscow: Nauka, 1989) [Translated into English (New York: AIP Press, 1994)]
  61. Lifshits I M, Grosberg A Yu, Khokhlov A R Usp. Fiz. Nauk 127 353 (1979) [Sov. Phys. Usp. 22 123 (1979)]
  62. Isihara A Statistical Physics (New York: Academic Press, 1971) [Translated into Russian (Moscow: Mir, 1973)]
  63. Hansen J P, McDonald I R Theory of Simple Liquids (London: Academic Press, 1986)
  64. Kovalenko N P, Fisher I Z Usp. Fiz. Nauk 108 209 (1972) [Sov. Phys. Usp. 15 592 (1973)]
  65. Rowlinson J S, Widom B Molecular Theory of Capillarity (Oxford: Clarendon Press, 1982)
  66. Yukhnovskiî I R, Golovko M F Statisticheskya Teoriya Klassicheskikh Ravnovesnykh Sistem (Statistical Theory of Classical Equilibrium Systems, Kiev: Naukova Dumka, 1980)
  67. Mayer J E J. Chem. Phys. 18 1426 (1950)
  68. Anderson P W Phys. Rev. 109 1492 (1958)
  69. Mott N F, Davis E A Electronic Processes in Non-Crystalline Materials (Oxford: Oxford University Press, 1979) [Translated into Russian (Moscow: Mir, 1982)]
  70. Ziman J M Models of Disorder (Cambridge: Cambridge University Press, 1979) [Translated into Russian (Moscow: Mir, 1982)]
  71. Schnitker J, Rossky P J J. Chem. Phys. 86 3462 (1987)
  72. Bachelet G B, Ceperley D M, Chiocchetti M G B Phys. Rev. Lett. 62 2088 (1989)
  73. Del Buono G S, Rossky P J, Murphrey T H J. Phys. Chem. 96 7761 (1992)
  74. Gaathon A, Jortner J, in Electrons in Fluids (Eds J Jortner, N R Kestner, Berlin: Springer-Verlag, 1973)
  75. Tachiya M, Tabata Y, Oshima K J. Phys. Chem. 77 263 (1973)
  76. Funabashi K, Maruyama Y J. Chem. Phys. 55 4494 (1971)
  77. Bartczak W M, Hilczer M, Kroh J J. Phys. Chem. 91 3894 (1987)
  78. Hilczer M, Bartczak W M J. Phys. Chem. 91 3834 (1987)
  79. Hilczer M, Bartczak W M J. Phys. Chem. 97 508 (1993)
  80. Feynman R P Statistical Mechanics (Reading, Mass.: Addison-Wesley, 1972) [Translated into Russian (Moscow: Mir, 1975)]
  81. Atrazhev V M, Yakubov I T Zh. Eksp. Teor. Fiz. 108 604 (1995) [JETP 81 326 (1995)]
  82. Friedberg R, Luttinger J M Phys. Rev. B 12 4460 (1975)
  83. Luttinger J M Phys. Rev. B 13 2596 (1976)
  84. Huang S-S, Freeman G R J. Chem. Phys. 68 1355 (1978)
  85. Reininger R et al. Phys. Rev. B 28 4426 (1983)
  86. Dmitrenko V V et al. Zh. Tekh. Fiz. 53 2343 (1983) [Sov. Phys. Tech. Phys. 28 1440 (1983)]
  87. Roellig L O, Kelly T M Phys. Rev. Lett. 15 746 (1965)
  88. Canter K F, Roellig L O Phys. Rev. Lett. 25 328 (1970)
  89. Tuomisaari M, RytsöläK, Hautojärvi P Phys. Lett. A 112 279 (1985)
  90. Chen J, Miller B N J. Chem. Phys. 100 3013 (1994)
  91. Khrapak A G, Yakubov I T Usp. Fiz. Nauk 129 45 (1979) [Sov. Phys. Usp. 22 703 (1979)]
  92. Miller B N, Reese T Phys. Rev. A 39 4735 (1989)
  93. Hernandez J P Rev. Mod. Phys. 63 675 (1991)
  94. Cao J, Berne B J J. Chem. Phys. 102 432 (1995)
  95. Gallicchio E, Berne B J J. Chem. Phys. 101 9909 (1994)
  96. Chen J, Miller B N Phys. Rev. B 49 15615 (1994)
  97. Reese T, Miller B N Phys. Rev. E 47 2581 (1993)
  98. Iguchi K J. Chem. Phys. 48 1735 (1968)
  99. Jou F Y, Freeman G R J. Phys. Chem. 81 909 (1977)
  100. Golden S, Tuttle T R, Lwenje S M J. Phys. Chem. 91 1360 (1987)
  101. Kreitus I V J. Phys. Chem. 89 1987 (1985)
  102. Rips I, Tachiya M J. Chem. Phys. 107 3924 (1997)
  103. Graf P, Nitzan A, Diercksen G H F J. Phys. Chem. 100 18916 (1996)
  104. Lakhno V D, Vasil’ev O V Chem. Phys. 153 147 (1991)
  105. Lakhno V D, Vasil’ev O V Chem. Phys. Lett. 177 147 (1991)
  106. Vasil’ev O V, Lakhno V D Zh. Fiz. Khim. 65 2104 (1991)
  107. Lakhno V D, Vasil’ev O V Phys. Lett. A 152 300 (1991)
  108. Vasil’ev O V "Localized electron states in a medium with movable ions", Thesis for Candidate of Physicomathematical Sciences (Moscow, 1991)
  109. Pekar S I Issledovaniya po Èlektronnoiî Teorii Kristallov (Research on Electron Theory in Crystals, Moscow: Gostekhizdat, 1951) [Translated into English (Washington, U.S.: AEC, 1963)]
  110. Chandler D, Schweizer K S, Wolynes P G Phys. Rev. Lett. 49 1100 (1982)
  111. Hoye J S, Olaussen K J. Chem. Phys. 77 2583 (1982)
  112. Schweizer K S, Chandler D J. Chem. Phys. 78 4118 (1983)
  113. Logan D E, Winn M D J. Phys. C 21 5773 (1988)
  114. Stratt R M Ann. Rev. Phys. Chem. 41 175 (1990)
  115. Leegwater J A, Mukamel S Phys. Rev. A 49 146 (1994)
  116. Schvaneveldt S J, Loring R F J. Chem. Phys. 101 4133 (1994)
  117. Feng D-F, Feuki K, Kevan L J. Chem. Phys. 58 3281 (1973)
  118. Kaukonen H-P, Barnett R N, Landman U J. Chem. Phys. 97 1365 (1992)
  119. Martyna G J, Deng Z, Klein M L J. Chem. Phys. 98 555 (1993)
  120. Nicoloso N, Freyland W J. Phys. Chem. 87 1997 (1987)
  121. Nakamura Y J. Phys. IV (Suppl.) 1 C5-61 (1991)
  122. Deng Z, Martyna G J, Klein M L Phys. Rev. Lett. 71 267 (1993)
  123. Alavi A, Frenkel D J. Chem. Phys. 97 9249 (1992)
  124. Lifshits I M, Gredeskul S A, Pastur L A Vvedenie v Teoriyu Neuporyadochennykh Sistem (Introduction to the Theory of Disordered Systems, Moscow: Nauka, 1982) [Translated into English (New York: Wiley, 1988)]
  125. Krivoglaz M A Usp. Fiz. Nauk 111 617 (1973) [Phys. Usp. 16(6) 856 (1974)]
  126. Coe J V et al. J. Chem. Phys. 92 3980 (1990)
  127. Lakhno V D, Chuev G N Usp. Fiz. Nauk 165 285 (1995) [Phys. Usp. 38 273 (1995)]
  128. Barnett R N et al. Acc. Chem. Res. 22 350 (1990)
© 1918–2024 Uspekhi Fizicheskikh Nauk
Email: ufn@ufn.ru Editorial office contacts About the journal Terms and conditions