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Current state of the spin exchange theory in dilute solutions of paramagnetic particles


E.K. Zavoiskii Kazan Physicotechnical Institute, Kazan Scientific Centre of the Russian Academy of Sciences, Sibirskii trakt 10/7, Kazan, 420029, Russian Federation

The kinetic equations for single-particle spin density matrices with Heisenberg exchange interaction in bimolecular collisions of particles and dipole-dipole spin-spin interaction between particles are presented. The results of calculations of the effective spin exchange radius for a number of model situations are summarized. The characteristic manifestations of spin exchange and dipole-dipole spin-spin interaction in the form of electron paramagnetic resonance (EPR) spectra are described. A modern approach to determining the rate of the bimolecular spin exchange process from the analysis of EPR spectra is presented. Set forth a new interpretation of the effect of exchange narrowing of ESR spectra.

Text is available here.

Keywords: spin probes, the exchange and the dipole-dipole interaction, the rate constant for spin exchange, decoherence of spins, transferring spin coherence, the shape of the EPR spectra, mixed form of spectral lines (absorption+dispersion), the exchange narrowing of the spectra
DOI: 10.3367/UFNe.2018.08.038421
Citation: Salikhov K M "Current state of the spin exchange theory in dilute solutions of paramagnetic particles" Phys. Usp., accepted

Received: 28th, June 2018, revised: 17th, August 2018, 31st, August 2018

Оригинал: Салихов К М «Состояние теории спинового обмена в разбавленных растворах парамагнитных частиц» УФН, принята к публикации; DOI: 10.3367/UFNr.2018.08.038421

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