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Instruments and methods of investigation


Desorption processes in the measurement of weak currents

,
Institute of Molecular and Crystal Physics, Ufa Research Center, Russian Academy of Sciences, prosp. Oktyabrya 151, Ufa, 450075, Russian Federation

It was previously shown that the experimental measurement of the lifetime of gas-phase negative ions formed in autoionization states during resonant electron capture by molecules is inherently fraught with inaccuracy due to adsorption of ions on the walls of the ionization chamber, with some of them surviving there and staying stabilized as 'eternal' till they eventually desorb back into the vacuum and merge with the total ion flow; this leads to an upward distortion of lifetime measurements. This paper describes a technique for removing desorbed ions from the total flow using an ion filter that lets only gas-phase ions pass into the detection system but detains the desorbed ions due to the differences among their kinetic energies.

Fulltext pdf (889 KB)
Fulltext is also available at DOI: 10.3367/UFNe.2019.07.038615
Keywords: resonant electron capture, lifetime of negative ions, temperature dependence, ion adsorption, mass spectrometry
PACS: 34.35.+a, 37.20.+j (all)
DOI: 10.3367/UFNe.2019.07.038615
URL: https://ufn.ru/en/articles/2020/5/c/
000555764100003
2-s2.0-85090225560
2020PhyU...63..487L
Citation: Lukin V G, Khvostenko O G "Desorption processes in the measurement of weak currents" Phys. Usp. 63 487–499 (2020)
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Received: 11th, April 2019, revised: 19th, June 2019, 11th, July 2019

Оригинал: Лукин В Г, Хвостенко О Г «Процессы десорбции при измерении слабых токов» УФН 190 525–538 (2020); DOI: 10.3367/UFNr.2019.07.038615

References (89) ↓ Cited by (5) Similar articles (7)

  1. Feshbach H Ann. Physics 5 357 (1958)
  2. Fano U Phys. Rev. 124 1866 (1961)
  3. Demkov Yu N Zh. Eksp. Teor. Fiz. 49 885 (1965); Demkov Yu N Sov. Phys. JETP 22 615 (1965)
  4. O’Malley T F Phys. Rev. 150 14 (1966)
  5. Bardsley J N, Mandl F Rep. Prog. Phys. 31 471 (1968)
  6. Herzenberg A J. Chem. Phys. 51 4942 (1969)
  7. Taylor H S, Thomas L D Phys. Rev. Lett. 28 1091 (1972)
  8. Schulz G J Rev. Mod. Phys. 45 423 (1973)
  9. Khvostenko V I, Tolstikov G A Uspekhi Khimii 45 251 (1976); Khvostenko V I, Tolstikov G A Russ. Chem. Rev. 45 127 (1976)
  10. Christophorou L G Advances In Electronics And Electron Physics Vol. 46 (Ed. L Marton) (New York: Academic Press, 1978) p. 55
  11. Smirnov B M Otritsatel’nye Iony (M.: Atomizdat, 1978); Per. na angl. yaz., Smirnov B M Negative Ions (New York: McGraw-Hill, 1982)
  12. Illenberger E, Smirnov B M Usp. Fiz. Nauk 168 731 (1998); Illenberger E, Smirnov B M Phys. Usp. 41 651 (1998)
  13. Simons J Annu. Rev. Phys. Chem. 62 107 (2011)
  14. Fabrikant I I Phys. Rev. A 94 052707 (2016)
  15. Zawadzki M et al Phys. Rev. Lett. 121 143402 (2018)
  16. Buchel’nikova N S Usp. Fiz. Nauk 65 351 (1958)
  17. Aleksandrov N L, Napartovich A P Usp. Fiz. Nauk 163 (3) 1 (1993); Aleksandrov N L, Napartovich A P Phys. Usp. 36 107 (1993)
  18. Checchetto V et al Biophys. Chem. 182 51 (2013)
  19. Brooks J S Chem. Soc. Rev. 39 2667 (2010)
  20. Koh W et al ChemPhysChem. 17 1095 (2016)
  21. Khvostenko V I, Vorob’yov A S, Khvostenko O G J. Phys. B 23 1975 (1990)
  22. Khvostenko O G et al J. Electron Spectrosc. Relat. Phenom. 199 1 (2015)
  23. Blau L M, Novick R, Weinflash D Phys. Rev. Lett. 24 2168 (1970)
  24. Khvostenko O G, Tuimedov G M Rapid Commun. Mass Spectrom. 20 3699 (2006)
  25. Khvostenko O G et al Chem. Phys. Lett. 711 81 (2018)
  26. Edelson D, Grifiths J E, McAffe K B (Jr) J. Chem. Phys. 37 917 (1962)
  27. Liu Y, Suess L, Dunning F B J. Chem. Phys. 122 214313 (2005)
  28. Rajput J, Lammich L, Andersen L H J. Phys. Rev. Lett. 100 153001 (2008)
  29. Menk S Dissertation (Germany, 2013)
  30. Harland P W, Thynne J C J Inorg. Nucl. Chem. Lett. 7 29 (1971)
  31. Stock M G Dyn. Mass Spectrom. 4 197 (1976)
  32. Odom P W, Smith D L, Futrell J H J. Phys. B 8 1349 (1975)
  33. Compton R N et al J. Chem. Phys. 45 4634 (1966)
  34. Lukin V G, Tuimedov G M Prib. Tekh. Eksp. (5) 77 (2013); Lukin V G, Tuimedov G M Instrum. Exp. Tech. 56 565 (2013)
  35. Harland P W, Thynne J C J J. Phys. Chem. 75 3517 (1971)
  36. Klots C F J. Chem. Phys. 46 1197 (1967)
  37. Vorob’ev A S i dr Zh. Tekh. Fiz. 79 (9) 11 (2009); Vorob’ev A S et al Tech. Phys. 54 1255 (2009)
  38. Lukin V G, Khvostenko O G, Tuimedov G M Int. J. Mass Spectrom. 399-400 17 (2016)
  39. Lukin V G, Khvostenko O G, Tuimedov G M Pis’ma ZhTF 42 (4) 96 (2016); Lukin V G, Khvostenko O G, Tuimedov G M Tech. Phys. Lett. 42 215 (2016)
  40. Lukin V G, Khvostenko O G, Tuimedov G M Zh. Tekh. Fiz. 87 982 (2017); Lukin V G, Khvostenko O G, Tuimedov G M Tech. Phys. 62 998 (2017)
  41. Lukin V G, Khvostenko O G Usp. Fiz. Nauk 187 981 (2017); Lukin V G, Khvostenko O G Phys. Usp. 60 911 (2017)
  42. Lukin V G, Tuimedov G M Prib. Tekh. Eksp. (1) 51 (2019); Lukin V G, Tuimedov G M Instrum. Exp. Tech. 62 47 (2019)
  43. Kaminsky M Atomic And Ionic Impact Phenomena On Metal Surfaces (Berlin: Springer-Verlag, 1965); Per. na russk. yaz., Kaminskii M Atomnye i Ionnye Stolknoveniya na Poverkhnosti Metalla (M.: Mir, 1967)
  44. Smirnov B M Fizika Atoma i Iona (M.: Energoatomizdat, 1986); Per. na angl. yaz., Smirnov B M Physics Of Atoms And Ions (New York: Springer, 2003)
  45. Masel R I Principles Of Adsorption And Reaction On Solid Surfaces (New York: Wiley, 1996)
  46. MacDonald R J, O’Connor D J Aust. J. Phys. 37 389 (1984)
  47. Cooper B H et al Nucl. Instrum. Meth. Phys. Res. B 64 49 (1992)
  48. Kammerer J, Carle R, Kammerer D R J. Agric. Food Chem. 59 22 (2011)
  49. Gupta S et al AIP Adv. 8 065225 (2018)
  50. Minissale M, Congiu E, Dulieu F Astron. Astrophys. 585 A146 (2016)
  51. Filatov V N, Sysoev A A, Morozov O V Prib. Tekh. Eksp. (1) 77 (1981)
  52. Roberts T D, Burch B D Rev. Sci. Insrum. 35 1067 (1964); Roberts T D, Burch B S Pribory Nauchnykh Issledovanii (8) 140 (1964)
  53. Cherepnin N V Vakuumnye Svoistva Materialov dlya Elektronnykh Priborov (M.: Sovetskoe radio, 1966)
  54. Edelson D, Griffiths J E, McAfee K B (Jr.) J. Chem. Phys. 37 917 (1962)
  55. Hadjiantjniou A, Christophorou L G, Carter J G J. Chem. Soc. Faraday Trans. 2 69 1691 (1973)
  56. Khvostenko V I Mass-spektrometriya Otritsatel’nykh Ionov v Organicheskoi Khimii (M.: Nauka, 1981)
  57. Khvostenko V I i dr Izv. AN SSSR Ser. Khim. (3) 681 (1973)
  58. Lukin V G, Vorob’ev A S, Lomakin G S Prib. Tekh. Eksp. (4) 121 (2009); Lukin V G, Vorob’ev A S, Lomakin G S Instrum. Exp. Tech. 52 560 (2009)
  59. Tal’roze V L, Frankevich E L ZhFKh 34 2709 (1960)
  60. Giese C F "Ion-neutral reactions" Advances In Chemical Physics: Molecular Beams Vol. 10 (Ed. J Rose) (New York: John Wiley and Sons, 1966) p. 247; Per. na russk. yaz., Gize K "Reaktsii neitronov s neitral’nymi chastitsami" Issledovaniya s Molekulyarnymi Puchkami (Pod red. A M Brodskogo, V B Leonasa) (M.: Mir, 1969) p. 281
  61. Tyutikov A M Usp. Fiz. Nauk 100 467 (1970); Tyutikov A M Sov. Phys. Usp. 13 204 (1970)
  62. Cravath A M Phys. Rev. 33 605 (1929)
  63. Loeb L B Phys. Rev. 48 684 (1935)
  64. Massey H S W, Burhop E H S Electronic And Ionic Impact Phenomena (Oxford: Clarendon Press, 1952); Per. na russk. yaz., Messi G, Barkhop E Elektronnye i Ionnye Stolknoveniya (M.: IL, 1958)
  65. Ageev V N, Kutsenko E N Zh. Tekh. Fiz. 39 1275 (1969)
  66. Tekhnicheskoe Opisanie i Instruktsiya Po Ekspluatatsii Mass-spektrometra MI-1201V (Sumy: Proizvodstvennoe ob’’edinenie "Elektron", 1983)
  67. Christophorou L G Atomic And Molecular Radiation Physics (London: Willey-Interscience, 1971)
  68. De Boer J H The Dynamical Character Of Adsorption (Oxford: Clarendon P, 1968); Per. na russk. yaz., De-Bur Ya Dinamicheskii Kharakter Adsorbtsii (M.: IL, 1962)
  69. Hickam W M, Berg D Advances In Mass Spectrometry (Ed. J D Waldron) (New York: Pergamon Press, 1959); Per. na russk. yaz., Khikkam V, Berg D Uspekhi Mass-spektrometrii (Pod red. Dzh D Uoldrona) (M.: IL, 1963)
  70. Vol’kenshtein F F Fizikokhimiya Poverkhnosti Poluprovodnikov (M.: Nauka, 1973)
  71. Adamson A W Physical Chemistry Of Surfaces (New York: Academic Press, 1973); Per. na russk. yaz., Adamson A Fizicheskaya Khimiya Poverkhnostei (M.: Mir, 1979)
  72. Becker J A Phys. Rev. 28 341 (1926)
  73. De Boer I H Electron Emission And Adsorption Phenomena (Cambridge: The Univ. Press, 1935); Per. na russk. yaz., De-Bur Zh G Elektronnaya Emissiya i Yavleniya Adsorbtsii (M.-L.: GROTL, 1936)
  74. Brunauer S et al J. Am. Chem. Soc. 62 1723 (1940)
  75. Gregg S J, Sing K S W Adsorption, Surface Area And Porosity ((London: Academic Press, 1982); Per. na russk. yaz., Greg S, Sing K Adsorbtsiya. Udel’naya Poverkhnost’. Poristost’ (M.: Mir, 1984)
  76. Avgul’ N N, Kiselev A V, Poshkus D P Adsorbtsiya Gazov i Parov na Odnorodnykh Poverkhnostyakh (M.: Khimiya, 1975)
  77. Karnaukhov A P Adsorbtsiya i poristost’. Trudy 4-oi Vsesoyuz. konf. po teoreticheskim voprosam adsorbtsii, Leningrad, 29 yanvarya - 2 fevralya 1974 g. (Otv. red. M M Dubinin, V V Serpinskii) (M.: Nauka, 1976)
  78. Ehrlich G Molecular Processes in Adsorption on Metals. Trans. 8th Natl. Vacuum Symp. 1961 (Oxford: Pergamon Press, 1962) p. 1961
  79. Redhead P A, Hobson J P, Kornelson E V The Physical Basis Of Ultrahigh Vacuum (London: Chapman and Hall, 1968)
  80. Cherepnin V N Sorbtsionnye Yavleniya v Vakuumnoi Tekhnike (M.: Sovetskoe radio, 1973)
  81. Inghram G M, Hayden R J, Hess D C Mass Spectrometry in Physic Research. Proc.s of the NBS Semicentennial Symp. on Mass Spectroscopy in Physics Research, September 6-8, 1951 (National Bureau of Standards Circular) Vol. 522 (Washington, DC: National Bureau of Standards, 1953) p. 257
  82. Dukel’skii V M, Zandberg E Ya Zh. Eksp. Teor. Fiz. 19 73 (1949)
  83. Berry H W Phys. Rev. 74 848 (1948)
  84. Stier P M, Barnett C F, Evans G E Phys. Rev. 96 973 (1954)
  85. Akishin A I Usp. Fiz. Nauk 66 331 (1958); Akishin A I Sov. Phys. Usp. 1 113 (1958)
  86. Zalkind V M, Sushko I S, Tarasenko V P Prib. Tekh. Eksp. (5) 110 (1982)
  87. Gusev V B, Polenov B V, Khazanov B I Yadernoe Priborostroenie. Trudy Soyuznogo Nauchno-issledovatel’skogo Instituta Priborostroeniya Vyp. 8 (M.: Atomizdat, 1968)
  88. Balashova N A, Merkulova N S Izuchenie spetsificheskoi adsorbtsii ionov i polozheniya tochki nulevogo zaryada metodom mechennykh atomov. Tr. 4-go soveshchaniya po elektrokhimii (M.: AN SSSR, otd. khim. nauk, 1950)
  89. Vol’kenshtein F F, Kogan Sh M Izv. AN SSSR. Otd. Khim. Nauk 9 1536 (1959)
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