Issues

 / 

2019

 / 

June

  

Methodological notes


Quantum effects in a system of Boltzmann hard spheres


Institute for High Pressure Physics, Russian Academy of Sciences, Kaluzhskoe shosse 14, Troitsk, Moscow, 108840, Russian Federation

Quantum contribution to the energy of the `Boltzmann' gas consisting of hard spheres proves to be virtually constant up to very high temperatures where the thermal de Broglie wavelength only makes a small fraction of the solid sphere diameter. Consequently, the heat capacity of the system virtually does not differ from a classical value of (3/2)kB everywhere except the lowest temperature region, where heat capacity as a function of temperature has the 'Debye' form but with a very low Debye temperature of the order of several degrees. The line of equilibrium between quantum crystal and liquid for the 'Boltzmann' system of hard spheres coincides with the classical one with the exception of a very-low-temperature region. High-temperature quantum effects are revealed in the system under consideration in a kind of `bare' form, while in the case of more realistic systems or models they can be masked by a complex behavior of other components of the total energy.

Fulltext pdf (585 KB)
Fulltext is also available at DOI: 10.3367/UFNe.2018.07.038399
Keywords: quantum hard sphere system, thermal wave length, Boltzmann gas
PACS: 64.70.D−, 67.10.Fj (all)
DOI: 10.3367/UFNe.2018.07.038399
URL: https://ufn.ru/en/articles/2019/6/e/
000484015200005
2-s2.0-85072915602
2019PhyU...62..617S
Citation: Stishov S M "Quantum effects in a system of Boltzmann hard spheres" Phys. Usp. 62 617–622 (2019)
BibTexBibNote ® (generic)BibNote ® (RIS)MedlineRefWorks

Received: 24th, April 2018, revised: 30th, July 2018, 30th, July 2018

Оригинал: Стишов С М «Квантовые эффекты в системе "больцмановских" твёрдых сфер» УФН 189 659–664 (2019); DOI: 10.3367/UFNr.2018.07.038399

References (29) ↓ Cited by (4) Similar articles (20)

  1. Runge K J, Chester G V Phys. Rev. B 38 135 (1988)
  2. Barker J A, Henderson D J. Chem. Phys. 47 2856 (1967)
  3. Hansen J-P, Levesque D, Schiff D Phys. Rev. A 3 776 (1971)
  4. Kalos M H, Levesque D, Verlet L Phys. Rev. A 9 2178 (1974)
  5. Peierls R E Quantum Theory Of Solids (Oxford: Clarendon Press, 1955); Per. na russk. yaz., Paierls R Kvantovaya Teoriya Tverdykh Tel (M.: IL, 1956)
  6. Levitt L S J. Chem. Educ. 39 520 (1962)
  7. Shankar R Principles Of Quantum Mechanics (Boston, MA: Springer, 1994)
  8. Borghi R Eur. J. Phys. 38 025404 (2017)
  9. Sesé L M J. Chem. Phys. 136 244504 (2012)
  10. Bhaduri R K, van Dijk W, Srivastava M K Eur. J. Phys. 27 1323 (2006)
  11. Ceperley D M, Simmons R O, Blasdell R C Phys. Rev. Lett. 77 115 (1996)
  12. Stishov S M Pis’ma ZhETF 31 272 (1980); Stishov S M JETP Lett. 31 249 (1980)
  13. Stishov S M Physica A 478 205 (2017)
  14. Stishov S M Pis’ma ZhETF 107 574 (2018); Stishov S M JETP Lett. 107 549 (2018)
  15. Wood W W, Jacobson J D J. Chem. Phys. 27 1207 (1957)
  16. Alder B J, Wainwright T E J. Chem. Phys. 27 1208 (1957)
  17. Landau L Zh. Eksp. Teor. Fiz. 7 19 (1937); Landau L D Phys. Z. Sowjetunion 11 26 (1937)
  18. Hill T L Statistical Mechanics. Principles And Selected Applications (New York: McGraw-Hill, 1956); Per. na russk. yaz., Khill T Statisticheskaya Mekhanika. Printsipy i Izbrannye Prilozheniya (M.: IL, 1960)
  19. Stishov S M Usp. Fiz. Nauk 114 3 (1974); Stishov S M Sov. Phys. Usp. 18 625 (1975)
  20. Hoover W G, Gray S G, Johnson K W J. Chem. Phys. 55 1128 (1971)
  21. London F Superfluids Vol. 2 (New York: Wiley, 1954)
  22. Landau L D, Lifshchits E M Statisticheskaya Fizika Vol. 1 (M.: Fizmatlit, 1995); Per. na angl. yaz., Landau L D, Lifshitz E M Statistical Physics Vol. 1 (New York: Pergamon Press, 1980)
  23. Jancovici B Phys. Rev 295 (1969)
  24. Gibson W G Mol. Phys. 30 13 (1975)
  25. Sesé L M J. Chem. Phys. 139 044502 (2013)
  26. Domb C, Dugdale J S Progress In Low Temperature Physics Vol. 2 (Amsterdam: North-Holland, 1957) p. 338
  27. Kirzhnits D A Zh. Eksp. Teor. Fiz. 38 503 (1960); Kirzhnits D A Sov. Phys. JETP 11 365 (1960)
  28. Jones M D, Ceperley D M Phys. Rev. Lett. 76 4572 (1996)
  29. Wigner E Phys. Rev. 46 1002 (1934)

© 1918–2024 Uspekhi Fizicheskikh Nauk
Email: ufn@ufn.ru Editorial office contacts About the journal Terms and conditions