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Diffusion phase transitions in alloys


Physical-Technical Institute of the Ural Branch of the Russian Academy of Sciences, Kirova str. 132, Izhevsk, 426001, Russian Federation

This paper presents a critical analysis of research on thermodynamics, kinetics and morphology of diffusion phase transitions in alloys. It is shown that the key thermodynamic stimulus for diffusion phase transitions is the chemical potential difference due to a change in the sign of the chemical interaction between the component atoms. It is explained how the sign of the chemical interaction energy can be obtained from experimental measurements. Examples are given to illustrate the kinetics and morphology of the ordering-separation phase transition in Ni- and Co-based alloys. It is shown how introducing the concept of the ordering-separation phase transition affects our thinking in this area.

Fulltext pdf (1020 KB)
Fulltext is also available at DOI: 10.3367/UFNe.0184.201407b.0723
PACS: 61.46.−w, 64.75.−g (all)
DOI: 10.3367/UFNe.0184.201407b.0723
URL: https://ufn.ru/en/articles/2014/7/b/
000343769200002
2-s2.0-84907899901
2014PhyU...57..670U
Citation: Ustinovshchikov Yu I "Diffusion phase transitions in alloys" Phys. Usp. 57 670–683 (2014)
BibTexBibNote ® (generic)BibNote ® (RIS) MedlineRefWorks
PT Journal Article
TI Diffusion phase transitions in alloys
AU Ustinovshchikov Yu I
FAU Ustinovshchikov YI
DP 10 Jul, 2014
TA Phys. Usp.
VI 57
IP 7
PG 670-683
RX 10.3367/UFNe.0184.201407b.0723
URL https://ufn.ru/en/articles/2014/7/b/
SO Phys. Usp. 2014 Jul 10;57(7):670-683

Received: 18th, October 2013, revised: 2nd, December 2013, 17th, December 2013

Оригинал: Устиновщиков Ю И «Диффузионные фазовые превращения в сплавах» УФН 184 723–737 (2014); DOI: 10.3367/UFNr.0184.201407b.0723

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