RSS feeds
РусскийEnglish
Issue 9, 2026
Volume year page
Issues Authors PACS Subscription For authors

Issues

 / 

2000

 / 

January

←  →

Reviews of topical problems


Order-disorder transformations and phase equilibria in strongly nonstoichiometric compounds


Institute of Solid State Chemistry, Urals Branch of the Russian Academy of Sciences, ul. Pervomayskaya 91, Ekaterinburg, 620219, Russian Federation

Data on order-disorder phase transformations in strongly nonstoichiometric carbides and nitrides MXy (X=C, N) of Group IV and V transition metals at temperatures below 1300-1400 K are reviewed. The order-parameter functional method as applied to atomic and vacancy ordering in strongly nonstoichiometric MXy compounds and to phase equilibrium calculations for M-X systems is discussed. Phase diagram calculations for the Ti-C, Zr-C, Hf-C, V-C, Nb-C, Ta-C, Ti-N, and Ti-B-C systems (with the inclusion of the ordering of nonstoichiometric carbides and nitrides) and those for pseudobinary carbide M(1)C-M(2)C systems are presented. Heat capacity, electrical resistivity and magnetic susceptibility changes at reversible order-disorder phase transformations in nonstoichiometric carbides are considered.

Fulltext pdf (1.2 MB)
Fulltext is also available at DOI: 10.1070/PU2000v043n01ABEH000647
PACS: 61.72.Ji, 64.60.Cn, 81.30.Dz (all)
DOI: 10.1070/PU2000v043n01ABEH000647
URL: https://ufn.ru/en/articles/2000/1/a/
000086055100001
Citation: Gusev A I "Order-disorder transformations and phase equilibria in strongly nonstoichiometric compounds" Phys. Usp. 43 1–37 (2000)
BibTexBibNote ® (generic)BibNote ® (RIS)MedlineRefWorks

Оригинал: Гусев А И «Превращение беспорядок–порядок и фазовые равновесия в сильно нестехиометрических соединениях» УФН 170 3–40 (2000); DOI: 10.3367/UFNr.0170.200001a.0003

References (219) Cited by (129) ↓ Similar articles (20)

  1. Ortega Y, Monge M A, Savoini B Journal Of Alloys And Compounds 1050 185539 (2026)
  2. Wang J, Yue D et al Journal Of Materials Research And Technology 34 1571 (2025)
  3. Frolov A, Bulava A et al J Am Ceram Soc. 108 (8) (2025)
  4. Tang X, Ma K et al Acta Materialia 301 121574 (2025)
  5. Peng J, Wang Ju et al MSI Eureka 104 10.13983.2.0 (2025)
  6. Stotts J C, Salehin R et al International Journal Of Hydrogen Energy 50 512 (2024)
  7. Tang X, Watkins B R et al Computational Materials Science 235 112803 (2024)
  8. Stotts J C, Tang X et al J. Phys.: Condens. Matter 36 (50) 505703 (2024)
  9. Samuels M H, Kramer A R, Richardson Ch J K Review of Scientific Instruments 95 (4) (2024)
  10. Zheng H, Yuan Ju et al Computational Materials Science 244 113177 (2024)
  11. Lin Ya, Chong X et al Ceramics International 49 (13) 22518 (2023)
  12. Luo N, Hou Zh et al Crystal Growth & Design 23 (8) 5486 (2023)
  13. Stotts J C, Thompson G B, Weinberger Ch R Results In Engineering 18 101106 (2023)
  14. Kostenko M G, Gusev A I, Lukoyanov A V Acta Materialia 223 117449 (2022)
  15. Salehin R, Thompson G B, Weinberger Ch R Materials & Design 214 110399 (2022)
  16. Khidirov I, Parpiev A S et al Russ. J. Inorg. Chem. 67 (4) 479 (2022)
  17. Zhang Zh, Zhang Yu Van der Waals Heterostructures 1 (2022) p. 1
  18. Davey T, Chen Y Int J Ceramic Engine & Sci 4 (3) 134 (2022)
  19. (PROCEEDINGS OF THE INTERNATIONAL CONFERENCE ??aPHYSICAL MESOMECHANICS. MATERIALS WITH MULTILEVEL HIERARCHICAL STRUCTURE AND INTELLIGENT MANUFACTURING TECHNOLOGY??v) Vol. PROCEEDINGS OF THE INTERNATIONAL CONFERENCE ??aPHYSICAL MESOMECHANICS. MATERIALS WITH MULTILEVEL HIERARCHICAL STRUCTURE AND INTELLIGENT MANUFACTURING TECHNOLOGY??vStructure and properties of non-stoichiometric titanium carbide powder after mechanical treatmentT. Yu.SablinaI. N.SevostyanovaE. V.AbdulmenovaS. N.Kulkov2509 (2022) p. 020163
  20. Zhang H, Hu T et al Journal Of Materials Science & Technology 38 205 (2020)
  21. Robin Ch Y H, Yoon T L Ceramics International 46 (1) 1124 (2020)
  22. Tanasescu S Structure Processing Properties Relationships in Stoichiometric and Nonstoichiometric Oxides Chapter 1 (2020)
  23. Weinberger Ch R, Thompson G B J Am Ceram Soc 103 (12) 7202 (2020)
  24. Zhou Yu, Heitmann T W et al J Am Ceram Soc 103 (4) 2891 (2020)
  25. Huang L, Pan Ya et al Calphad 71 102199 (2020)
  26. Backman L, Gild J et al Acta Materialia 197 81 (2020)
  27. Tang X, Salehin R et al Phys. Rev. Materials 4 (9) (2020)
  28. Kostenko M G, Gusev A I, Lukoyanov A V Phys. Chem. Chem. Phys. 22 (41) 24116 (2020)
  29. Rempel S V, Gusev A I Phys. Chem. Chem. Phys. 22 (26) 14918 (2020)
  30. Dubey P, Kaurav N Structure Processing Properties Relationships in Stoichiometric and Nonstoichiometric Oxides Chapter 6 (2020)
  31. Shabalin I L Ultra-High Temperature Materials II Chapter 5 (2019) p. 423
  32. Vorotilo S, Sidnov K et al Journal Of Alloys And Compounds 778 480 (2019)
  33. Shabalin I L Ultra-High Temperature Materials II Chapter 3 (2019) p. 145
  34. Kostenko M G, Lukoyanov A V, Valeeva A A Mendeleev Communications 29 (6) 707 (2019)
  35. Shabalin I L Ultra-High Temperature Materials II Chapter 2 (2019) p. 9
  36. Osorio A G, Souza D et al Journal Of Materials Processing Technology 266 46 (2019)
  37. Madaoui N, Adnane-Amara L, Taibi K Mater. Res. Express 6 (6) 066523 (2019)
  38. Shabalin I L Ultra-High Temperature Materials II Chapter 4 (2019) p. 249
  39. Furuta T, Shiina K et al J.Japan Inst.Metals 83 (3) 97 (2019)
  40. Weinberger Ch R, Thompson G B Acta Crystallogr B Struct Sci Cryst Eng Mater 75 (5) 870 (2019)
  41. Shi F, Liu L et al Materials Chemistry And Physics 225 256 (2019)
  42. Zhao X, Togaru M et al Journal Of The European Ceramic Society 39 (16) 5167 (2019)
  43. Ou P, Li Zh Materials 11 (11) 2321 (2018)
  44. Riedl H, Glechner T et al Scripta Materialia 149 150 (2018)
  45. Smith Ch J, Weinberger Ch R, Thompson G B Journal Of The European Ceramic Society 38 (15) 4850 (2018)
  46. Wei B, Chen L et al Journal Of The European Ceramic Society 38 (2) 411 (2018)
  47. Weinberger Ch R, Thompson G B J Am Ceram Soc 101 (10) 4401 (2018)
  48. Weinberger Ch R, Yu H et al Advances In Applied Ceramics 117 (sup1) s26 (2018)
  49. Schulz B C, DiPietro S et al Journal Of The European Ceramic Society 37 (15) 4532 (2017)
  50. Weinberger Ch R, Yu X-X et al Computational Materials Science 138 333 (2017)
  51. Zhang J -L, Hong G -Y Modern Inorganic Synthetic Chemistry (2017) p. 329
  52. Cuppari M, Santos S Metals 6 (10) 250 (2016)
  53. Khvan A, Kuznetsov V MSI Eureka 66 10.12824.1.0 (2016)
  54. Li X, Hu W J. Mater. Res. 31 (1) 137 (2016)
  55. Xie C, Liu N et al Journal Of The European Ceramic Society 36 (15) 3593 (2016)
  56. Kurlov A S, Gusev A I et al Superlattices And Microstructures 90 148 (2016)
  57. Yu H, Guziewski M et al Modelling Simul. Mater. Sci. Eng. 24 (5) 055004 (2016)
  58. Pan Ya, Zhou P et al Calphad 53 1 (2016)
  59. Xie C, Oganov A R et al Phys. Chem. Chem. Phys. 18 (17) 12299 (2016)
  60. Yu X-X, Weinberger Ch R, Thompson G B Computational Materials Science 112 318 (2016)
  61. Kolosov V N, Shevyrev A A Phys. Metals Metallogr. 117 (1) 22 (2016)
  62. Gusev A I J. Exp. Theor. Phys. 120 (1) 91 (2015)
  63. Yu X-X, Thompson G B, Weinberger Ch R Journal Of The European Ceramic Society 35 (1) 95 (2015)
  64. Gusev A I ’pс’?’?kh’? ф’?’?’?ch’?с’?’?kh ’?’?у’? 184 (9) 905 (2014) [Gusev A I Phys.-Usp. 57 (9) 839 (2014)]
  65. Gusev A I, Bel’kov A M et al Phys. Solid State 56 (10) 2092 (2014)
  66. Hu W, Tian Y, Liu Zh Nanotechnology chapter 31 (2014) p. 667
  67. Yu X-X, Weinberger Ch R, Thompson G B Acta Materialia 80 341 (2014)
  68. Shabalin I L Ultra-High Temperature Materials I Chapter 2 (2014) p. 7
  69. Seplyarsky B S, Tarasov A G et al Combust Explos Shock Waves 50 (3) 300 (2014)
  70. Volodin V N, Teleushev Yu Zh, Zhakanbaev E A Phys. Metals Metallogr. 114 (5) 395 (2013)
  71. Zhou P, Peng Y et al International Journal Of Refractory Metals And Hard Materials 41 408 (2013)
  72. Hu W, Tian Y, Liu Zh MAX Phases and Ultra-High Temperature Ceramics for Extreme Environments chapter 16 (2013) p. 478
  73. Gusev A I Journal Of Solid State Chemistry 199 181 (2013)
  74. Seplyarskii B S, Tarasov A G, Kochetkov R A Int. J Self-Propag. High-Temp. Synth. 22 (1) 65 (2013)
  75. Gusev A I J. Exp. Theor. Phys. 117 (2) 293 (2013)
  76. Kurlov A S, Gusev A I Springer Series In Materials Science Vol. Tungsten CarbidesOrdering of Tungsten Carbides184 Chapter 3 (2013) p. 57
  77. Dobatkina T, Bochvar N MSI Eureka 52 10.13983.1.1 (2013)
  78. Khidirov I, Parpiev A S Crystallogr. Rep. 58 (3) 450 (2013)
  79. Khidirov I, Parpiev A S At Energy 114 (2) 128 (2013)
  80. Zhao D, Chang K et al Journal Of The Mechanical Behavior Of Biomedical Materials 28 171 (2013)
  81. Hu W, Xiang J et al J. Mater. Res. 27 (9) 1230 (2012)
  82. Lukas H MSI Eureka 49 10.13982.1.9 (2012)
  83. Gusev A I, Valeeva A A Jetp Lett. 96 (6) 364 (2012)
  84. Pedrosa P, Alves E et al Corrosion Science 56 49 (2012)
  85. Xiang J Y, Liu S C et al Journal Of The European Ceramic Society 31 (8) 1491 (2011)
  86. Xiang J, Hu W et al Materials Chemistry And Physics 130 (1-2) 352 (2011)
  87. Gusev A I, Davydov D A, Valeeva A A Journal Of Alloys And Compounds 509 (5) 1364 (2011)
  88. Khidirov I, Parpiev A S Crystallogr. Rep. 56 (3) 470 (2011)
  89. Khidirov I Russ. J. Inorg. Chem. 56 (2) 298 (2011)
  90. Zhang J, Hong G Modern Inorganic Synthetic Chemistry (2011) p. 321
  91. Lukas H L Landolt-Börnstein - Group IV Physical Chemistry Vol. Refractory metal systemsCarbon ??I Tantalum ??I Titanium11E2 Chapter 41 (2010) p. 619
  92. Dobatkina T, Bochvar N Landolt-Börnstein - Group IV Physical Chemistry Vol. Refractory metal systemsCarbon ??I Tantalum ??I Zirconium11E3 Chapter 3 (2010) p. 18
  93. Rempel A A, Valeeva A A Mendeleev Communications 20 (2) 101 (2010)
  94. Kurlov A S, Gusev A I Phys. Solid State 52 (2) 370 (2010)
  95. Gusev A I Phys. Solid State 52 (9) 1935 (2010)
  96. Gusev A I Jetp Lett. 91 (3) 119 (2010)
  97. Rogl P, Korniyenko K, Velikanova T MSI Eureka 40 10.11532.2.3 (2009)
  98. Adjaoud O, Steinle-Neumann G et al Phys. Rev. B 80 (13) (2009)
  99. Winkler Björn, Juarez-Arellano E A et al Journal Of Alloys And Compounds 478 (1-2) 392 (2009)
  100. Rogl P, Korniyenko K, Velikanova T Landolt-Börnstein - Group IV Physical Chemistry Vol. Refractory metal systemsBoron ??I Carbon ??I Niobium11E1 Chapter 20 (2009) p. 474
  101. Kurlov A S, Gusev A I Phys. Solid State 51 (10) 2051 (2009)
  102. Khidirov I, Mirzaev B B et al Carbon Nanomaterials in Clean Energy Hydrogen Systems NATO Science For Peace And Security Series C: Environmental Security Chapter 83 (2009) p. 663
  103. Gusev A I J. Exp. Theor. Phys. 109 (3) 417 (2009)
  104. Markström Andreas, Andersson D, Frisk K Calphad 32 (4) 615 (2008)
  105. Gusev A I Phys. Solid State 50 (12) 2256 (2008)
  106. Gusev A I Jetp Lett. 87 (5) 248 (2008)
  107. Kurlov A S, Gusev A I J. Exp. Theor. Phys. 105 (4) 710 (2007)
  108. Gusev A I Jetp Lett. 86 (2) 108 (2007)
  109. Gusev A I, Nazarova S Z Uspekhi Fizicheskikh Nauk 175 (7) 681 (2005)
  110. DANON C A, SERVANT C ISIJ Int. 45 (6) 903 (2005)
  111. Vaz F, Ferreira J et al Surface And Coatings Technology 191 (2-3) 317 (2005)
  112. Lipatnikov V N, Rempel A A Jetp Lett. 81 (7) 326 (2005)
  113. Maksimov G A, Krasil’nik Z F et al Phys. Solid State 47 (1) 22 (2005)
  114. Onufrienok V V Inorg Mater 41 (6) 650 (2005)
  115. Servant C, Danon C A Calphad 28 (4) 337 (2004)
  116. Rempel S V, Gusev A I Phys. Solid State 44 (1) 68 (2002)
  117. Gusev A I, Rempel A A, Magerl A J Springer Series In Materials Science Vol. Disorder and Order in Strongly Nonstoichiometric CompoundsEquilibrium Phase Diagrams47 Chapter 10 (2001) p. 371
  118. Gusev A I, Rempel A A, Magerl A J Springer Series In Materials Science Vol. Disorder and Order in Strongly Nonstoichiometric CompoundsEffects of Ordering on the Properties of Strongly Nonstoichiometric Compounds47 Chapter 11 (2001) p. 453
  119. Nazarova S Z, Gusev A I Journal Of Structural Chemistry 42 (3) 470 (2001)
  120. Ivanovskii A L, Medvedeva N I, Okatov S V Inorganic Materials 37 (5) 459 (2001)
  121. Gusev A I Jetp Lett. 74 (2) 91 (2001)
  122. Medvedeva N I, Ivanovskii A L Phys. Solid State 43 (3) 469 (2001)
  123. Valeeva A A, Rempel’ A A, Gusev A I Inorganic Materials 37 (6) 603 (2001)
  124. Rempel’ S V, Gusev A I Inorganic Materials 37 (10) 1024 (2001)
  125. Cherkashenko V M, Nazarova S Z et al Journal Of Structural Chemistry 42 (6) 1002 (2001)
  126. Gusev A I ChemInform 31 (41) (2000)
  127. Gusev A I, Rempel’ S V Doklady Physical Chemistry 375 (4-6) 249 (2000)
  128. Valeeva A A, Rempel’ A A, Gusev A I Jetp Lett. 71 (11) 460 (2000)
  129. Ivanovskii A L, Sofronov A A Theor Exp Chem 36 (4) 187 (2000)
© 1918–2026 Uspekhi Fizicheskikh Nauk
Email: ufn@ufn.ru Editorial office contacts About the journal Terms and conditions