Features of the thermodynamics of superionic conductors

This article reviews the theoretical and experimental studies on a number of the thermodynamic aspects of superionic conduction, the intensive study of which began in the past decade. We discuss the relation of superionic conductivity to the disordering of one of the sublattices of the crystal, disordering phase transitions caused by the interaction of point defects, and the mechanism of polymorphic transitions associated with partial disordering. We analyze the effect of jumpwise variation of the ionic conductivity induced by an external electric field, the thermodynamics of domain states in superionic conductors, and the effect of pressure on the phase transitions and the ionic conductivity.

PACS: 66.30.Dn
DOI: 10.1070/PU1982v025n04ABEH004539
URL: https://ufn.ru/en/articles/1982/4/d/
Citation: Gurevich Yu Ya, Kharkats Yu I "Features of the thermodynamics of superionic conductors" Sov. Phys. Usp. 25 257–276 (1982)

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PT Journal Article
TI Features of the thermodynamics of superionic conductors
AU Gurevich Yu Ya
FAU Gurevich YY
AU Kharkats Yu I
FAU Kharkats YI
DP 10 Apr, 1982
TA Phys. Usp.
VI 25
IP 4
PG 257-276
RX 10.1070/PU1982v025n04ABEH004539
URL https://ufn.ru/en/articles/1982/4/d/
SO Phys. Usp. 1982 Apr 10;25(4):257-276

Оригинал: Гуревич Ю Я, Харкац Ю И «Особенности термодинамики суперионных проводников» УФН 136 693–728 (1982); DOI: 10.3367/UFNr.0136.198204e.0693