RSS feeds
РусскийEnglish
Issue 12, 2025
Volume year page
Issues Authors PACS Subscription For authors

Issues

 / 

1981

 / 

April

←  →

Reviews of topical problems


Structure and properties of fine metallic particles

, , ,

This review considers the present status of theoretical and experimental investigations of fine metallic particles (FMP) with characteristic dimension from 100 to 1 nm. An analysis is made of the influence of the size of FMP on the structure, on the phonon spectra, the heat capacity, the Debye temperature, the behavior of the FMP in an electromagnetic field, the relaxation of the electronic spins, the magnetic susceptibility, and the optical properties. Changes in the structure and in the phonon spectrum are due chiefly to disintegration of the surface layers of atoms and to the large curvature of the surface of the FMP. The electronic states of FMP are treated with allowance for the pronounced discreteness of the levels. A comparison is made of theoretical and experimental results on the effect of the parity of the number of electrons in the particles on the paramagnetic susceptibility and on the Knight shift. Relaxation of electron spins in FMP of alkali metals is discussed with allowance for the effect of the surface and of impurities, and also of a possible contribution from the pronounced discreteness of phonon and electron states. Investigations of optical properties and of plasma oscillations indicate an important role of surface states in relation to electronic transitions in FMP.

Fulltext pdf (1.1 MB)
Fulltext is also available at DOI: 10.1070/PU1981v024n04ABEH004800
PACS: 73.90.+f, 75.60.Jp, 71.55.Dp
DOI: 10.1070/PU1981v024n04ABEH004800
URL: https://ufn.ru/en/articles/1981/4/c/
Citation: Morokhov I D, Petinov V I, Trusov L I, Petrunin V F "Structure and properties of fine metallic particles" Sov. Phys. Usp. 24 295–317 (1981)
BibTexBibNote ® (generic)BibNote ® (RIS)MedlineRefWorks

Оригинал: Морохов И Д, Петинов В И, Трусов Л И, Петрунин В Ф «Структура и свойства малых металлических частиц» УФН 133 653–692 (1981); DOI: 10.3367/UFNr.0133.198104c.0653

Cited by (145) ↓ Similar articles (20)

  1. Sergeeva D Yu, Bekrenev I V, Tishchenko A A Jetp Lett. 121 (8) 595 (2025)
  2. Karami M H, Abdouss M et al Inorganic Chemistry Communications 161 112032 (2024)
  3. Katwal R Nano-Structures & Nano-Objects 35 101001 (2023)
  4. Ditenberg I A, Smirnov I V et al Materials Science And Engineering: A 874 145041 (2023)
  5. Sergeeva D Yu, Tishchenko A A Phys. Rev. B 108 (15) (2023)
  6. Ditenberg I A, Smirnov I V et al Materials 16 (6) 2430 (2023)
  7. Suliz K, Miller A et al Powder Technology 404 117491 (2022)
  8. Dong Ya, Sun W et al Opt. Mater. Express 12 (5) 1838 (2022)
  9. Ditenberg I A, Smirnov I V et al Materials Science And Engineering: A 843 143159 (2022)
  10. Wagner Ju, Josse C et al Results In Materials 13 100259 (2022)
  11. Sadovnichii D N, Milekhin Yu M et al Tech. Phys. 65 (7) 1076 (2020)
  12. Ditenberg I A, Smirnov I V et al Entropy 22 (2) 143 (2020)
  13. Kuznetsova I A, Romanov D N Russ Microelectron 49 (4) 244 (2020)
  14. Ditenberg I A, Smirnov I V et al Materials Characterization 168 110517 (2020)
  15. Pervikov A, Khrustalyov A et al Metals 9 (12) 1287 (2019)
  16. Pervikov A V, Lerner M I et al Inorg. Mater. Appl. Res. 10 (3) 699 (2019)
  17. Sergeeva D Yu, Tishchenko A A et al J. Inst. 13 (02) C02045 (2018)
  18. Mostovshchikov A V, Il’in A P et al Tech. Phys. 63 (8) 1223 (2018)
  19. Shestopalova L, Shestopalova L Science intensive technologies in mechanical engineering 2018 (7) 45 (2018)
  20. Mostovshchikov A V, Ilyin A P, Egorov I S Radiation Physics And Chemistry 153 156 (2018)
  21. Porvatkina O V, Tishchenko A A, Strikhanov M N Appl. Phys. A 123 (1) (2017)
  22. Aleksandrova G P, Sapozhnikov A N et al Russ J Gen Chem 87 (10) 2369 (2017)
  23. Voznyakovskii A P, Kudoyarova V Kh et al Phys. Solid State 59 (8) 1656 (2017)
  24. Anokhin M N, Tishchenko A A, Strikhanov M N Appl. Phys. A 123 (1) (2017)
  25. Mostovshchikov A V, Il’in A P et al Tech. Phys. Lett. 42 (4) 344 (2016)
  26. Shestopalova L P Russ. Metall. 2016 (13) 1241 (2016)
  27. Porvatkina O V, Tishchenko A A, Strikhanov M N J. Phys.: Conf. Ser. 643 012074 (2015)
  28. Sobacchi E, Vietri M Monthly Notices of the Royal Astronomical Society 450 (2) 2116 (2015)
  29. Petrunin V F Physics Procedia 72 536 (2015)
  30. Feldshtein E E, Dyachkova L N Composites Part B: Engineering 58 16 (2014)
  31. Petrunin V F Phys. Solid State 56 (1) 171 (2014)
  32. Korotun A V Phys. Metals Metallogr. 115 (5) 421 (2014)
  33. Lin E E WJM 04 (06) 170 (2014)
  34. Sorokin L M, Kalmykov A E et al Tech. Phys. Lett. 40 (4) 296 (2014)
  35. Popov V V, Stolbovskii A V et al Phys. Metals Metallogr. 114 (1) 68 (2013)
  36. Smirnov I A, Smirnov B I et al Phys. Solid State 55 (2) 454 (2013)
  37. Makarov G N Uspekhi Fizicheskikh Nauk 183 (7) 673 (2013) [Makarov G N Phys.-Usp. 56 (7) 643 (2013)]
  38. Kurlov A S, Gusev A I Springer Series In Materials Science Vol. Tungsten CarbidesNanocrystalline Tungsten Carbide184 Chapter 4 (2013) p. 109
  39. Buranbaev M Zh, Aliev B A et al Lecture Notes In Electrical Engineering Vol. Future Information Communication Technology and ApplicationsRadiation Modification of the Structure of Nanosized Metal Powders235 Chapter 52 (2013) p. 471
  40. Gafner S L, Redel L V, Gafner Yu Ya J. Exp. Theor. Phys. 114 (3) 428 (2012)
  41. Krylov A I, Konopelko L A et al Meas Tech 54 (10) 1191 (2012)
  42. Shirinyan A S, Bilogorodskyy Yu S Phys. Metals Metallogr. 113 (9) 823 (2012)
  43. Shikov A A, Zemlyanov M G et al Phys. Solid State 54 (12) 2345 (2012)
  44. Parshin P P, Zemlyanov M G et al J. Exp. Theor. Phys. 114 (3) 440 (2012)
  45. Batsanov S S, Batsanov A S Introduction to Structural Chemistry Chapter 1 (2012) p. 1
  46. Kumzerov Yu A, Kartenko N F et al Phys. Solid State 53 (5) 1099 (2011)
  47. Dobrovolsky V D, Ershova O G, Solonin Yu M Journal Of Alloys And Compounds 509 (3) 614 (2011)
  48. Gafner S L, Redel L V et al J Nanopart Res 13 (12) 6419 (2011)
  49. Sheshko T F, Serov Yu M Russ. J. Phys. Chem. 85 (1) 51 (2011)
  50. Shirinyan A S, Gusak A M Diffusion‐Controlled Solid State Reactions 1 (2010) p. 425
  51. Parshin P P, Zemlyanov M G et al J. Exp. Theor. Phys. 111 (6) 996 (2010)
  52. Shirinyan A S Phys. Solid State 52 (6) 1267 (2010)
  53. Lin É É Phys. Solid State 52 (1) 153 (2010)
  54. Panin V E, Egorushkin V E Phys. Metals Metallogr. 110 (5) 464 (2010)
  55. Dolgusheva E B, Trubitsin V Yu Phys. Solid State 52 (6) 1238 (2010)
  56. Gulina L B, Tolstobrov E V, Tolstoi V P Russ J Gen Chem 80 (6) 1149 (2010)
  57. Akopov F Kh, Chkhartishvili I V et al Phys. Metals Metallogr. 109 (4) 411 (2010)
  58. Ershova O G, Dobrovolsky V D et al Carbon Nanomaterials in Clean Energy Hydrogen Systems NATO Science For Peace And Security Series C: Environmental Security Chapter 60 (2009) p. 473
  59. Ershova O G, Dobrovolsky V D et al Journal Of Alloys And Compounds 464 (1-2) 212 (2008)
  60. Rekhviashvili S Sh Phys. Metals Metallogr. 105 (5) 421 (2008)
  61. Naumenko V Yu, Voronin I V, Gorbatov S A International Polymer Science And Technology 35 (4) 39 (2008)
  62. Frolov G I, Bachina O I et al Tech. Phys. 53 (8) 1059 (2008)
  63. Ryazanov M I, Strikhanov M N, Tishchenko A A Nuclear Instruments And Methods In Physics Research Section B: Beam Interactions With Materials And Atoms 266 (17) 3811 (2008)
  64. Karpenko S V, Savintsev A P, Temrokov A I Dokl. Phys. 53 (3) 128 (2008)
  65. Smirnov I A, Smirnov B I et al Phys. Solid State 49 (10) 1839 (2007)
  66. Smirnov I A, Smirnov B I et al Phys. Solid State 49 (10) 1835 (2007)
  67. Chernavskii P A, Peskov N V et al Russ. J. Phys. Chem. B 1 (4) 394 (2007)
  68. Berezkina S V, Kuznetsova I A, Yushkanov A A Phys. Solid State 49 (1) 6 (2007)
  69. Karpenko S V Russ Phys J 50 (11) (2007)
  70. Makarov G N Uspekhi Fizicheskikh Nauk 176 (2) 121 (2006)
  71. Karpenko S V, Savintsev A P, Temrokov A I Phys. Metals Metallogr. 101 (4) 320 (2006)
  72. Ryazanov M I, Tishchenko A A J. Exp. Theor. Phys. 103 (4) 539 (2006)
  73. Zemlyanov M G, Panova G Kh et al Phys. Solid State 48 (1) 139 (2006)
  74. Kochnev I N Physica B: Condensed Matter 373 (2) 217 (2006)
  75. Dobrovol’skii V D, Radchenko O G et al Powder Metall Met Ceram 45 (7-8) 381 (2006)
  76. Karpenko S V, Kyarov A Kh, Temrokov A I Phys. Solid State 48 (3) 570 (2006)
  77. Karpenko S V, Savintsev A P, Temrokov A I Dokl. Phys. 51 (12) 658 (2006)
  78. Moiseev I O, Yushkanov A A, Yalamov Yu I Opt. Spectrosc. 101 (5) 797 (2006)
  79. Nakin A V, Khmelevskaya V S Crystallogr. Rep. 51 (2) 322 (2006)
  80. Berezkina S V, Kuznetsova I A, Yushkanov A A Tech. Phys. 51 (5) 533 (2006)
  81. Chernavskii P A Kinet Catal 46 (5) 634 (2005)
  82. Poluboyarov V A, Lapin A E et al Inorg Mater 41 (2) 110 (2005)
  83. Poluboyarov V A, Lapin A E et al Kinet Catal 46 (4) 565 (2005)
  84. Akopyan I Kh Phys. Solid State 47 (7) 1372 (2005)
  85. Karpenko S V, Temrokov A I Tech. Phys. 49 (11) 1509 (2004)
  86. Berezkina S V, Kuznetsova I A, Yushkanov A A Tech. Phys. 49 (12) 1605 (2004)
  87. Moiseev I O, Yushkanov A A, Yalamov Yu I Tech. Phys. 49 (1) 87 (2004)
  88. Zavitaev É V, Yushkanov A A, Yalamov Yu I Tech. Phys. 48 (3) 290 (2003)
  89. Parfen’eva L S, Smirnov I A et al Phys. Solid State 45 (2) 381 (2003)
  90. Chuistov K V, Shpak A P et al Usp. Fiz. Met. 4 (4) 235 (2003)
  91. Kuznetsova I A, Yushkanov A A Opt. Spectrosc. 94 (4) 613 (2003)
  92. Yurkov G Yu, Kozinkin A V et al Inorganic Materials 37 (10) 997 (2001)
  93. Zavitaev É V, Yushkanov A A, Yalamov Yu I Tech. Phys. 46 (11) 1460 (2001)
  94. Petrunin V F MRS Proc. 676 (2001)
  95. Ivanov V G, Safronov M N, Gavrilyuk O V Combustion, Explosion, And Shock Waves 37 (2) 173 (2001)
  96. Andrievski R A, Glezer A M Scripta Materialia 44 (8-9) 1621 (2001)
  97. Emaletdinov A K Crystallogr. Rep. 45 (2) 264 (2000)
  98. Lin É É Phys. Solid State 42 (10) 1946 (2000)
  99. Petrunin V F Nanostructured Materials 12 (5-8) 1153 (1999)
  100. Zaulichnyi Y V Powder Metall Met Ceram 38 (7-8) 387 (1999)
  101. Fomichev S V, Zaretsky D F J. Phys. B: At. Mol. Opt. Phys. 32 (21) 5083 (1999)
  102. Il’in A P, Yablunovskii G V et al Combust Explos Shock Waves 35 (6) 656 (1999)
  103. Kamilov I K, Murtazaev A K, Aliev Kh K Uspekhi Fizicheskikh Nauk 169 (7) 773 (1999)
  104. Tyumentsev V A, Belenkov E A et al Carbon 36 (7-8) 845 (1998)
  105. Ye X, Lin D et al J. Phys. D: Appl. Phys. 31 (20) 2739 (1998)
  106. Roitsin A B, Klimov A A, Artamonov L V J. Exp. Theor. Phys. 87 (1) 123 (1998)
  107. Gusev A I Uspekhi Fizicheskikh Nauk 168 (1) 55 (1998)
  108. Roitsin A B, Artamonov L V, Klimov A A Phys. Solid State 39 (9) 1512 (1997)
  109. Roitsin A B, Klimov A A, Artamonov L V Computer Modelling of Electronic and Atomic Processes in Solids Chapter 12 (1997) p. 115
  110. Pomogailo A D Russ. Chem. Rev. 66 (8) 679 (1997)
  111. Kalamazov R U, Lem I N Met Sci Heat Treat 38 (3) 115 (1996)
  112. Bates S E, Buhro W E et al J. Mater. Res. 10 (10) 2599 (1995)
  113. Shevchenko V V, Savost’yanov V S, Ponomarev A N Russ Chem Bull 44 (9) 1695 (1995)
  114. Roitsin A B Physica Status Solidi (b) 178 (2) 275 (1993)
  115. Lyushinskii A V Welding International 7 (12) 985 (1993)
  116. Gryaznov V G, Trusov L I Progress In Materials Science 37 (4) 289 (1993)
  117. Stein A, Ozin G A Proceedings from the Ninth International Zeolite Conference (1993) p. 93
  118. Pokutnyi S I, Efremov N A Physica Status Solidi (b) 172 (2) 573 (1992)
  119. Berkovits R, Altshuler B L Phys. Rev. B 46 (19) 12526 (1992)
  120. Gamarnik M Ya Physica Status Solidi (b) 164 (1) 107 (1991)
  121. Apell S P, Giraldo J, Lundqvist S Phase Transitions 24-26 (2) 577 (1990)
  122. Slanina Z Res. Chem. Intermed. 14 (1) 47 (1990)
  123. Khvorov M M, Shvitai V A, Shvets T M Powder Metall Met Ceram 29 (11) 927 (1990)
  124. Gamarnik M Ya, Sidorin Yu Yu Physica Status Solidi (b) 156 (1) (1989)
  125. Bobovich Ya S J Appl Spectrosc 49 (3) 869 (1988)
  126. Gusev V A, Moroz E M, Levitskii E A React Kinet Catal Lett 37 (2) 343 (1988)
  127. Derjaguin B V, Churaev N V, Rabinovich Ya I Advances In Colloid And Interface Science 28 197 (1987)
  128. Derjaguin B V, Churaev N V, Muller V M Surface Forces Chapter 4 (1987) p. 85
  129. Aktsipetrov O A, Baranova I M et al Physics Letters A 117 (5) 239 (1986)
  130. Balerna A, Mobilio S Phys. Rev. B 34 (4) 2293 (1986)
  131. Halperin W P Rev. Mod. Phys. 58 (3) 533 (1986)
  132. Parmigiani F, Scagliotti M et al Thin Solid Films 125 (3-4) 229 (1985)
  133. Rubtsov N A, Dulin M N et al J Russ Laser Res 5 (1) 165 (1984)
  134. Kiparisov S S, Nuzhdin A A, Strelova S V Powder Metall Met Ceram 23 (7) 546 (1984)
  135. Shevchenko S A, Levlyuk L P, Pavlov S M Powder Metall Met Ceram 23 (6) 425 (1984)
  136. Petrunin V F, Pogonin V A et al Powder Metall Met Ceram 23 (2) 108 (1984)
  137. Mobilio S, Burattini E et al Springer Proceedings In Physics Vol. EXAFS and Near Edge Structure IIINoble Metal Small Cluster EXAFS2 Chapter 56 (1984) p. 222
  138. Zubov V I Soviet Physics Journal 27 (3) 235 (1984)
  139. Tománek D, Mukherjee S, Bennemann K H Phys. Rev. B 28 (2) 665 (1983)
  140. Hintermann A, Manninen M Phys. Rev. B 27 (12) 7262 (1983)
  141. Novikov V I, Trusov L I et al Powder Metall Met Ceram 22 (7) 547 (1983)
  142. Koverda V P, Skokov V N, Skripov V P Phys. Stat. Sol. (a) 74 (1) 343 (1982)
  143. Mal’shukov A G Solid State Communications 44 (8) 1257 (1982)
  144. Panin V E, Egorushkin V E et al Soviet Physics Journal 25 (12) 1073 (1982)
  145. Parmigiani F Physics Letters A 92 (8) 419 (1982)
© 1918–2025 Uspekhi Fizicheskikh Nauk
Email: ufn@ufn.ru Editorial office contacts About the journal Terms and conditions