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Electron-vibrational interactions in polyatomic molecules

We review the literature on electron-vibrational interactions in polyatomic molecules. The analysis is based on an adiabatic theory that employs a single universal small parameter of the molecules, viz., the Born--Oppenheimer parameter. The principal results of the theory of electron-vibrational spectra are summarized. Special attention is paid to to the results that follow from a general analysis that is not based on concrete model. The theory is compared with experimental data for a wide range of chemical compounds (hydrocarbons with various structures, heterocyclic compounds, dyes). Possible mechanisms of broadening the electronvibrational line in liquid and solid solutions are discussed. Experimental data that demonstrate the role of various broadening mechanisms in concrete cases are cited. It is demonstrated by means of a number of examples (induced optical activity, dimers, excimers) that the adiabatic theory is significant in the analysis of the influence of intermolecular interactions on the spectral characteristics of the molecules. The theoretical analysis is illustrated with experimental data. The role of the adiabatic theory in the description of nonradiative transitions in polyatomic molecules is briefly considered. Particular attention is paid to a discussion of the role of chemical processes that accompany nonradiative transitions. Some additional problems faced by theory and experiment are indicated in the conclusion.

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Fulltext is also available at DOI: 10.1070/PU1975v018n06ABEH001963
PACS: 32.20.P
DOI: 10.1070/PU1975v018n06ABEH001963
URL: https://ufn.ru/en/articles/1975/6/a/
Citation: Frank-Kamenetskii M D, Lukashin A V "Electron-vibrational interactions in polyatomic molecules" Sov. Phys. Usp. 18 391–409 (1975)
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Оригинал: Франк-Каменецкий М Д, Лукашин А В «Электронно-колебательные взаимодействия в многоатомных молекулах» УФН 116 193–229 (1975); DOI: 10.3367/UFNr.0116.197506a.0193

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  53. Mertz E L, Tikhomirov V A, Krishtalik L I J. Phys. Chem. A 101 3433 (1997)
  54. Gulis I M J Appl Spectrosc 63 31 (1996)
  55. Mertz E L Chemical Physics Letters 262 27 (1996)
  56. Lanzani G, Nisoli M et al Chemical Physics Letters 251 339 (1996)
  57. Medvedev E S, Osherov V I Springer Series In Chemical Physics Vol. Radiationless Transitions in Polyatomic MoleculesIntroduction57 Chapter 1 (1995) p. 1
  58. Baczyński A, Radomska D J Fluoresc 5 91 (1995)
  59. Jalviste E, Treshchalov A Chemical Physics 172 325 (1993)
  60. Zusman L D Russ. Chem. Rev. 61 15 (1992)
  61. Bozio R, Feis A et al NATO ASI Series Vol. Lower-Dimensional Systems and Molecular ElectronicsStructural Properties of Molecular Charge-Transfer Conductors and Semiconductors from Infrared and Raman Spectroscopy248 Chapter 2 (1990) p. 23
  62. Zakaraya M G, Maisuradze G G J Appl Spectrosc 53 1301 (1990)
  63. Gulis I M, Komyak A I et al J Appl Spectrosc 50 257 (1989)
  64. Yin L, Goscinski O Chemical Physics 137 67 (1989)
  65. Korovina V M, Bakhshiev N G J Appl Spectrosc 50 211 (1989)
  66. Zakaraya M G, Ulstrup Je Chemical Physics 135 49 (1989)
  67. Kircheva P P, Pfeiffer M et al J Raman Spectroscopy 20 183 (1989)
  68. Zakaraya M G, Ulstrup Je Optics Communications 68 107 (1988)
  69. Maier G V, Galeeva A I J Appl Spectrosc 45 844 (1986)
  70. Boitsov V M, Yuzhakov V I J Appl Spectrosc 45 1200 (1986)
  71. Mit’kina N N, Puko R A et al J Appl Spectrosc 44 156 (1986)
  72. Chigiryov A R Journal Of Molecular Spectroscopy 115 419 (1986)
  73. Nagamov N A, Bolotin A B Theor Exp Chem 21 349 (1985)
  74. Rashev S Spectroscopy Letters 18 179 (1985)
  75. Ishchenko A A, Derevyanko N A et al Theor Exp Chem 20 415 (1985)
  76. Zen’kevich � I, Shul’ga A M et al J Appl Spectrosc 42 139 (1985)
  77. Ivanov A I, Ponomarev O A Theor Exp Chem 19 578 (1984)
  78. Priyutov M V, Kovner M A et al J Struct Chem 24 653 (1984)
  79. Nagamov N A, Bolotin A B et al Theor Exp Chem 20 156 (1984)
  80. Bakhshiev N G, Glebovskii D N, Bedrina M E J Appl Spectrosc 38 204 (1983)
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  85. Peuker K, Enderlein R et al Physica Status Solidi (b) 109 599 (1982)
  86. Helman A B Chemical Physics 65 271 (1982)
  87. Lukashin A V, Frank‐Kamenetskii M D J Raman Spectroscopy 12 234 (1982)
  88. Klochkov V P J Appl Spectrosc 34 251 (1981)
  89. Rashev S S J Appl Spectrosc 35 997 (1981)
  90. Langhoff P W, Langhoff S R et al Chemical Physics 58 71 (1981)
  91. Lukashin A V, Frank-Kamenetskii M D Chemical Physics Letters 80 119 (1981)
  92. Danilova V I, Kopylova T N et al Soviet Physics Journal 23 872 (1980)
  93. Gustav K, Sühnel J Zeitschrift Fuer Chemie 20 283 (1980)
  94. Dygdała R S, Stefański K Chemical Physics 53 51 (1980)
  95. Huang T-H, Rieckhoff K E, Voigt E M Chemical Physics 36 423 (1979)
  96. Doktorov E V, Malkin I A, Man’ko V I Journal Of Molecular Spectroscopy 77 178 (1979)
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  98. Goscinski O, Palma A Int J Of Quantum Chemistry 15 197 (1979)
  99. Ohno K Chemical Physics 37 63 (1979)
  100. Lukashin A V Chemical Physics Letters 65 527 (1979)
  101. Lunichev V N J Struct Chem 20 14 (1979)
  102. Zhdanov G S, Osipov V P et al Polymer Science U.S.S.R. 21 208 (1979)
  103. Mikhailenko V I, Grosul V P, Red’kin Yu R J Appl Spectrosc 28 552 (1978)
  104. Alexandrov I V, Khairutdinov R F, Zamaraev K I Chemical Physics 32 123 (1978)
  105. Lukashin A V, Frank-Kamenetskii M D Chemical Physics 35 469 (1978)
  106. Klochkov V P J Appl Spectrosc 28 523 (1978)
  107. Duke C B Annals Of The New York Academy Of Sciences 313 166 (1978)
  108. Domcke W, Cederbaum L S Chemical Physics 25 189 (1977)
  109. Frank-Kamenetskii M D, Lukashin A V, Puretskii A A Chemical Physics Letters 45 583 (1977)
  110. Martin T P, Onari S Phys. Rev. B 15 1093 (1977)
  111. Doktorov E V, Malkin I A, Man’ko V I Journal Of Molecular Spectroscopy 64 302 (1977)
  112. Schirmer J, Cederbaum L S et al Chemical Physics 26 149 (1977)
  113. Lukashin A V, Frank-Kamenetskii M D Chemical Physics Letters 45 36 (1977)
  114. Doktorov E V, Malkin I A, Man’ko V I J. Phys. B: At. Mol. Phys. 9 507 (1976)
  115. Mirumyants S O, Demchuk Yu S J Appl Spectrosc 25 1535 (1976)

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