Issues

 / 

1974

 / 

March

  

Reviews of topical problems


Probabilities of optical transitions in electronic vibration-rotation spectra of diatomic molecules

This review presents systematized data on absolute probabilities of electronic transitions in diatomic molecules published between the beginning of 1961 and the end of 1973, and relative transition probabilites published between the beginning of 1966 and the end of 1973. The paper reviews theoretical relationships lying at the basis of experimental methods for determining absolute transition probabilities. Individual methods are not reviewed in detail, since the details can be found in the cited literature. The following material is tabulated: absolute probabilities of electronic transitions, the dependence of the dipole moments of electronic transitions on internuclear distances, and the Franck-Condon factors (Tables I, II, and IV, respectively), using all publications known to the authors. In addition to the complete systematization of probability data, the authors attempt to provide a critical analysis of published results with a view to selecting the most reliable. The recommended values of the squares of the matrix elements of the dipole moments of electronic transitions are listed in Table III. The last chapter compares calculations of the Franck-Condon factors obtained for different molecular potentials.

Fulltext pdf (974 KB)
Fulltext is also available at DOI: 10.1070/PU1974v017n03ABEH004141
PACS: 33.70.Ca, 33.20.Vq, 33.15.Dj (all)
DOI: 10.1070/PU1974v017n03ABEH004141
URL: https://ufn.ru/en/articles/1974/3/g/
Citation: Kuznetsova L A, Kuz’menko N E, Kuzyakov Yu Ya, Plastinin Yu A "Probabilities of optical transitions in electronic vibration-rotation spectra of diatomic molecules" Sov. Phys. Usp. 17 405–423 (1974)
BibTexBibNote ® (generic)BibNote ® (RIS)MedlineRefWorks

Оригинал: Кузнецова Л А, Кузьменко Н Е, Кузяков Ю Я, Пластинин Ю А «Вероятности оптических переходов электронно-колебательно-вращательных спектров двухатомных молекул» УФН 113 285–325 (1974); DOI: 10.3367/UFNr.0113.197406c.0285

Cited by (60) ↓ Similar articles (20)

  1. Bobrovnikov S M, Gorlov E V, Zharkov V I Atmos Ocean Opt 35 (4) 329 (2022)
  2. Bobrovnikov S M, Gorlov E V, Zharkov V I Atmos Ocean Opt 34 (4) 302 (2021)
  3. Gitlin M S, Bogatov N A et al Plasma Sources Sci. Technol. 28 (4) 045011 (2019)
  4. Huebner W F, Barfield W D Astrophysics And Space Science Library Vol. OpacityRadiative Cross Sections402 Chapter 5 (2014) p. 123
  5. Huebner W F, Barfield W D Astrophysics And Space Science Library Vol. OpacityUncertainties in Models, Methods, and Calculations402 Chapter 12 (2014) p. 421
  6. Huebner W F, Barfield W D Astrophysics And Space Science Library Vol. OpacityComparisons with Experiments402 Chapter 13 (2014) p. 425
  7. Huebner W F, Barfield W D Astrophysics And Space Science Library Vol. OpacityAtomic and Molecular Structure402 Chapter 3 (2014) p. 29
  8. Bityurin V A, Grigorenko A V et al High Temp 52 (1) 1 (2014)
  9. Huebner W F, Barfield W D Astrophysics And Space Science Library Vol. OpacityBound–Bound (Line) Transitions402 Chapter 7 (2014) p. 287
  10. Huebner W F, Barfield W D Astrophysics And Space Science Library Vol. OpacityLimits, Approximations, Scaling, and Interpolations402 Chapter 11 (2014) p. 411
  11. Huebner W F, Barfield W D Astrophysics And Space Science Library Vol. OpacityEquation of State (EOS)402 Chapter 4 (2014) p. 81
  12. Huebner W F, Barfield W D Astrophysics And Space Science Library Vol. OpacityElectron Conduction and Electron Opacity402 Chapter 9 (2014) p. 383
  13. Huebner W F, Barfield W D Astrophysics And Space Science Library Vol. OpacityCollision-Induced Absorption (CIA)402 Chapter 8 (2014) p. 369
  14. Huebner W F, Barfield W D Astrophysics And Space Science Library Vol. OpacitySpecial Cases402 Chapter 14 (2014) p. 443
  15. Huebner W F, Barfield W D Astrophysics And Space Science Library Vol. OpacityContinuum Transitions402 Chapter 6 (2014) p. 263
  16. Huebner W F, Barfield W D Astrophysics And Space Science Library Vol. OpacityEquations of State and Opacities for Mixtures402 Chapter 10 (2014) p. 405
  17. Dikalyuk A S, Surzhikov S T High Temp 52 (1) 35 (2014)
  18. Huebner W F, Barfield W D Astrophysics And Space Science Library Vol. OpacityDefinitions402 Chapter 2 (2014) p. 9
  19. Dikalyuk A S, Surzhikov S T Fluid Dyn 48 (1) 123 (2013)
  20. Dikalyuk A, Kozlov P et al 44th AIAA Thermophysics Conference, (2013)
  21. Belevtsev A A, Kukushkin A M et al High Temperature 42 (3) 342 (2004)
  22. Fukuchi T, Wong A Y, Wuerker R F Radio Science 25 (6) 1299 (1990)
  23. Dubovskii V V, Labuda A A, Nikiforenko N N J Appl Spectrosc 50 (3) 247 (1989)
  24. Yamaguchi S, Tsuji M, Nishimura Yu The Journal of Chemical Physics 88 (5) 3111 (1988)
  25. Kuznetsova L A Spectroscopy Letters 20 (9) 665 (1987)
  26. Yamaguchi S, Tsuji M et al The Journal of Chemical Physics 86 (9) 4952 (1987)
  27. Huber M C E, Sandeman R J Rep. Prog. Phys. 49 (4) 397 (1986)
  28. Kuznetsova L A, Kuz’menko N E, Kuzyakov Yu Ya Acta Physica Hungarica 55 (1-4) 395 (1984)
  29. Vagin Yu P, Punkevich B S et al Radiophys Quantum Electron 26 (5) 410 (1983)
  30. Metal Vapours in Flames (1982) p. 959
  31. Dumont M N, Remy F Spectroscopy Letters 15 (9) 699 (1982)
  32. Chakraborty B P Int J Of Quantum Chemistry 22 (1) 73 (1982)
  33. Singh P D, de Almeida A A Journal Of Quantitative Spectroscopy And Radiative Transfer 27 (4) 471 (1982)
  34. Hitachi A, A K T J. Phys. Soc. Jpn. 51 (10) 3325 (1982)
  35. Ibragimova L B Journal Of Engineering Physics 40 (3) 250 (1981)
  36. Gallas Ja A C Phys. Rev. A 21 (6) 1829 (1980)
  37. Kuz’menko N E, Kuznetsova L A et al Journal Of Quantitative Spectroscopy And Radiative Transfer 24 (3) 219 (1980)
  38. Hefferlin R, Kuhlman H Journal Of Quantitative Spectroscopy And Radiative Transfer 24 (5) 379 (1980)
  39. Kuz’menko N E, Kuznetsova L A et al Journal Of Quantitative Spectroscopy And Radiative Transfer 24 (1) 29 (1980)
  40. Golubovskii Yu B, Telezhko V M J Appl Spectrosc 32 (2) 111 (1980)
  41. Nikiforenko N N, Labuda A A, Bosyakov M N J Appl Spectrosc 32 (2) 116 (1980)
  42. Golubovskii Yu B, Florko A V J Appl Spectrosc 33 (1) 710 (1980)
  43. Erman P, Larsson M Phys. Scr. 20 (5-6) 582 (1979)
  44. Chakraborty B P, Grieneisen H P et al The Journal of Chemical Physics 70 (6) 3023 (1979)
  45. Smirnov A D, Kuz’menko N E, Kuzyakov Yu Ya J Appl Spectrosc 30 (1) 64 (1979)
  46. Mohamed K A, King G C J. Phys. B: At. Mol. Phys. 12 (17) 2809 (1979)
  47. Erman P Phys. Scr. 20 (5-6) 575 (1979)
  48. Kondranin T V, Kuz’minskii I N Fluid Dyn 13 (5) 693 (1979)
  49. Ibragimova L B J Appl Spectrosc 28 (4) 417 (1978)
  50. Smirnov A D, Kuz’menko N E, Kuzyakov Yu Ya J Appl Spectrosc 28 (5) 631 (1978)
  51. Hefferlin R Journal Of Quantitative Spectroscopy And Radiative Transfer 19 (3) 335 (1978)
  52. Nikolaev V M, Plastinin Yu A J Appl Spectrosc 26 (5) 678 (1977)
  53. Ochkin V N, Savinov S Yu, Sobolev N N J Appl Spectrosc 26 (5) 647 (1977)
  54. Hsu D K, Smith W H Spectroscopy Letters 10 (4) 181 (1977)
  55. Mohamed K A, King G C, Read F H Journal Of Electron Spectroscopy And Related Phenomena 12 (3) 229 (1977)
  56. Berg J O, Robinson G W Israel Journal Of Chemistry 16 (4) 235 (1977)
  57. Imhof R E, Read F H Rep. Prog. Phys. 40 (1) 1 (1977)
  58. Doktorov E V, Malkin I A, Man’ko V I Journal Of Quantitative Spectroscopy And Radiative Transfer 16 (12) 1021 (1976)
  59. Bourimov V N, Letokhov V S, Ryabov E A Journal Of Photochemistry 5 (1) 49 (1976)
  60. Erman P Beam-Foil Spectroscopy Chapter 20 (1976) p. 199

© 1918–2025 Uspekhi Fizicheskikh Nauk
Email: ufn@ufn.ru Editorial office contacts About the journal Terms and conditions