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Issue 11, 2026
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1962

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June

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Reviews of topical problems


Structural investigations in crystals by the method of nuclear magnetic resonance

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1. Introduction 947
2. Theory of Line Width and Line Shape of Nuclear Magnetic Resonance Lines in Crystals 948
a) Two-spin Systems 948
b) Three- and Four-spin Systems 950
c) Integral Characteristics of the Spectrum (Moments). Van Vleck's Theory 951
d) Effect of Small Thermal Vibrations on the Observed Value of the Second Moment 954
e) Changes in the Nuclear Magnetic Resonance Spectrum Occurring in the Case of Intense Molecular Motion 954
f) Double Resonances in Crystals 956
3. Experimental Methods 956
a) Radiofrequency Spectrograph for the Quantitative Study of Nuclear Magnetic Resonance in Solids 956
b) Measurement of Second Moments. Instrumental Corrections 958
4. Structural Investigations of Crystals Carried out by the Method of Nuclear Magnetic Resonance 960
a) Verification of the Theory and Some Methodological Problems 960
b) Nuclear Magnetic Resonance in Crystalline Hydrates 961
c) Investigation of Hydrogen Bonding in Crystals 963
d) Selection of One of Several Models 965
e) Investigation of Incompletely Ordered (Statistical) Structures 966
References 967

Fulltext pdf (2.7 MB)
Fulltext is also available at DOI: 10.1070/PU1962v004n06ABEH003395
PACS: 61.50.Ah, 76.60.−k, 61.66.−f, 61.50.Lt (all)
DOI: 10.1070/PU1962v004n06ABEH003395
URL: https://ufn.ru/en/articles/1962/6/g/
Citation: Aleksandrov N M, Skripov F I "Structural investigations in crystals by the method of nuclear magnetic resonance" Sov. Phys. Usp. 4 947–974 (1962)
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Оригинал: Александров Н М, Скрипов Ф И «Структурные исследования в кристаллах методом ядерного магнитного резонанса» УФН 75 585–628 (1961); DOI: 10.3367/UFNr.0075.196112a.0585

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