Short-range order and diffuse scattering in nonstoichiometric compounds
A.I. Gusev
Institute of Solid State Chemistry, Urals Branch of the Russian Academy of Sciences, Ekaterinburg, Russian Federation
Diffraction studies of nonstoichiometric compounds have revealed a diverse range of diffuse scattering effects due to the short-range
order induced by atom and vacancy substitution or by atomic displacements. In this paper, diffuse neutron and X-ray scattering data
and electron diffraction data on short-range order in nonstoichiometric compounds are discussed. It is shown that the redistribution of
non-metallic atoms and structural vacancies in disordered nonstoichiometric carbides, nitrides, and oxides produces diffuse intensity
maxima in diffraction patterns, as does the redistribution of mutually substitutable metallic atoms in the solid solutions of nonstoichiometric
compounds before long-range order sets in. A discussion is given of whether the cluster model of transition state is adequate for
describing diffuse scattering intensity profile in a nonstoichiometric compound with substitutional short-range order. Flat extended
diffuse scattering regions observed in the diffraction patterns of ordered phases and not passing through reciprocal lattice sites are
discussed and shown to be due to the appearance of atomic displacement waves in the material.
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